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SAFETY DATA SHEET

1. Identification

Product identifier Dykem® Brite-Mark® - Black

Other means of identification

Recommended use Solvent based marker

Recommended restrictions None known.

Manufacturer/Importer/Supplier/Distributor information

2. Hazard(s) identification

Physical hazards: Flammable liquids - Category 3

Health hazards: Specific target organ toxicity, single exposure - Category 3 narcotic effects

Environmental hazards: Not classified.

OSHA defined hazards: Not classified.

Label elements:

Open

Hazard(s) not otherwise classified (HNOC): None known.

Supplemental information: None.

3. Composition/information on ingredients

4. First-aid measures

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

Skin contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists.

Ingestion: Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Direct contact with eyes may cause temporary irritation.

Indication of immediate medical attention and special treatment needed: Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed.

General information: Take off all contaminated clothing immediately. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse.

5. Fire-fighting measures

Suitable extinguishing media: Water fog. Alcohol resistant foam. Dry chemical powder. Dry sand. Carbon dioxide (CO2).

Unsuitable extinguishing media: Water. Do not use water jet as an extinguisher, as this will spread the fire. Carbon dioxide (CO2).

Specific hazards arising from the chemical: Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions: In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.

Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards: Flammable liquid and vapor.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Methods and materials for containment and cleaning up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling: Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid prolonged exposure. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

Conditions for safe storage, including any incompatibilities: Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits.

Biological limit values: No biological exposure limits noted for the ingredient(s).

Exposure guidelines

Appropriate engineering controls: Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment

General hygiene considerations: Observe any medical surveillance requirements. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Odor: Sweet.

Odor threshold: Not available.

pH: Not available.

Melting point/freezing point: Not available.

Initial boiling point and boiling range: 251.96 °F (122.2 °C)

Flash point: 81.0 °F (27.2 °C) Tag Closed Cup

Evaporation rate: Not available.

Flammability (solid, gas): Not applicable.

Upper/lower flammability or explosive limits

Vapor pressure: Not available.

Vapor density: Not available.

Relative density: Not available.

Solubility(ies)

Partition coefficient (n-octanol/water): Not available.

Auto-ignition temperature: Not available.

Decomposition temperature: Not available.

Viscosity: Not available.

Other information

10. Stability and reactivity

Reactivity: The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability: Material is stable under normal conditions.

Possibility of hazardous reactions: Hazardous polymerization does not occur.

Conditions to avoid: Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials: Acids. Strong oxidizing agents. Chlorine. Isocyanates. Nitrates.

Hazardous decomposition products: Carbon oxides.

11. Toxicological information

Information on likely routes of exposure

Symptoms related to the physical, chemical and toxicological characteristics: May cause drowsiness and dizziness. Headache. Nausea, vomiting.

Information on toxicological effects

Acute toxicity: Not expected to be acutely toxic.

Skin corrosion/irritation: Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation: Direct contact with eyes may cause temporary irritation.

Respiratory or skin sensitization:

Germ cell mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Reproductive toxicity: This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - single exposure: May cause drowsiness and dizziness.

Specific target organ toxicity - repeated exposure: Not classified.

Aspiration hazard: Not an aspiration hazard.

Chronic effects: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

Further information: Symptoms may be delayed.

12. Ecological information

Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Persistence and degradability: No data is available on the degradability of any ingredients in the mixture.

Bioaccumulative potential

Mobility in soil: Not established.

Other adverse effects: None known.

13. Disposal considerations

Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations: Dispose in accordance with all applicable regulations.

Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging: Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information

DOT

IATA

IMDG

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable.

DOT

IATA; IMDG

Marine pollutant

General information: IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.

15. Regulatory information

US federal regulations: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Other federal regulations

US state regulations

International Inventories

16. Other information, including date of preparation or last revision

Issue date: 07-11-2019

Version #: 01

Disclaimer: ITW Pro Brands cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.