Section 1. Identification

Product name

Product code

Other means of identification

Product type

Relevant identified uses of the substance or mixture and uses advised against

Manufacturer

Emergency telephone number of the company

SP™3105 Carton Stencil Ink Aerosol White

S03105

Not available.

Aerosol.

Not applicable.

Sprayon Products, Cleveland, OH 44115

(216) 566-2917

Product Information Telephone Number

(800)247-3266

Regulatory Information Telephone Number

(216)566-2902

Transportation Emergency Telephone Number

(800)424-9300

Section 2. Hazards identification

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

FLAMMABLE AEROSOLS - Category 1

GASES UNDER PRESSURE - Compressed gas

SKIN CORROSION/IRRITATION - Category 2

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 33.6%

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

Causes serious eye irritation.

Causes skin irritation.

Suspected of causing cancer.

May be fatal if swallowed and enters airways.

May cause respiratory irritation.

May cause drowsiness and dizziness.

May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED

EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Hazards not otherwise classified

None known.

Section 3. Composition/information on ingredients

Substance/mixture

Mixture

Other means of identification

Not available.

CAS number/other identifiers

Ingredient name

% by weight

CAS number

Acetone

41.3

67-64-1

Propane

12.8

74-98-6

Butane

12.3

106-97-8

p-Chlorobenzotrifluoride

11.5

98-56-6

Titanium Dioxide

5.8

13463-67-7

Lt. Aliphatic Hydrocarbon Solvent

5.3

64742-89-8

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

Causes skin irritation.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Adverse symptoms may include the following: irritation, redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

No specific treatment.

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Extinguishing media

Suitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media

None known.

Specific hazards arising from the chemical

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Hazardous thermal decomposition products

Decomposition products may include the following materials: carbon dioxide, carbon monoxide, halogenated compounds, carbonyl halides, metal oxide/oxides

Special protective actions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

Control parameters

Occupational exposure limits

Ingredient name

Exposure limits

Acetone

ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours

Propane

NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.

Butane

NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes

Titanium Dioxide

ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance

Physical state

Liquid.

Color

Not available.

Odor

Not available.

Odor threshold

Not available.

pH

7

Melting point

Not available.

Boiling point

Not available.

Flash point

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Evaporation rate

5.6 (butyl acetate = 1)

Flammability (solid, gas)

Not available.

Lower and upper explosive (flammable) limits

Lower: 0.9%

Upper: 12.8%

Vapor pressure

13.5 kPa (101.325 mm Hg) [at 20°C]

Vapor density

1.55 [Air = 1]

Relative density

0.79

Solubility

Not available.

Partition coefficient: noctanol/water

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Kinematic (room temperature): <0.07 cm²/s (<7 cSt)

Kinematic (40°C (104°F)): <0.07 cm²/s (<7 cSt)

Aerosol product

Type of aerosol

Spray

Heat of combustion

0.00002993 kJ/g

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

The product is stable.

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible materials

No specific data.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name

Result

Species

Dose

Exposure

Acetone

LD50 Oral

Rat

5800 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

p-Chlorobenzotrifluoride

LD50 Oral

Rat

13 g/kg

-

Irritation/Corrosion

Product/ingredient name

Result

Species

Score

Exposure

Observation

Acetone

Eyes - Mild irritant

Human

-

186300 parts per million

-

Eyes - Mild irritant

Rabbit

-

10 microliters

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20 milligrams

-

Eyes - Severe irritant

Rabbit

-

20 milligrams

-

Skin - Mild irritant

Rabbit

-

24 hours 500 milligrams

-

Skin - Mild irritant

Rabbit

-

395 milligrams

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300

Micrograms

Intermittent

-

Sensitization

Not available.

Mutagenicity

Not available.

Carcinogenicity

Not available.

Product/ingredient name

OSHA

IARC

NTP

Titanium Dioxide

-

2B

-

Reproductive toxicity

Not available.

Teratogenicity

Not available.

Specific target organ toxicity (single exposure)

Name

Category

Route of exposure

Target organs

Acetone

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

p-Chlorobenzotrifluoride

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Lt. Aliphatic Hydrocarbon Solvent

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Specific target organ toxicity (repeated exposure)

Name

Category

Route of exposure

Target organs

Acetone

Category 2

Not determined

Not determined

Propane Butane

Category 2

Not determined

Not determined

p-Chlorobenzotrifluoride

Category 2

Not determined

Not determined

Lt. Aliphatic Hydrocarbon Solvent

Category 2

Not determined

Not determined

Aspiration hazard

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Information on the likely routes of exposure

Not available.

Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

Causes skin irritation.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

Skin contact

Adverse symptoms may include the following: irritation redness

Ingestion

Adverse symptoms may include the following: nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects

Not available.

Potential delayed effects

Not available.

Long term exposure

Potential immediate effects

Not available.

Potential delayed effects

Not available.

Potential chronic health effects

Not available.

General

May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates

Not available.

Section 12. Ecological information

Toxicity

Product/ingredient name

Result

Species

Exposure

Acetone

Acute EC50 20.565 mg/l Marine water

Algae - Ulva pertusa

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 10000 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Persistence and degradability

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

-

-

Readily

Bioaccumulative potential

Product/ingredient name

LogP_ow

BCF

Potential

Titanium Dioxide

-

352

low

Lt. Aliphatic Hydrocarbon Solvent

-

10 to 2500

high

Mobility in soil

Soil/water partition coefficient (K_OC)

Not available.

Other adverse effects

No known significant effects or critical hazards.

Disposal methods

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

Section 14. Transport information

Special precautions for user

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

Transport in bulk according to Annex II of MARPOL

73/78 and the IBC Code

Not available.

U.S. Federal regulations

State regulations

California Prop. 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

Hazardous Material Information System (U.S.A.)

Health

*

2

Flammability

3

Physical hazards

0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.