Section 1. Identification

Product name

KRYLON® PRO PROFESSIONAL All Surface Enamel Flat White

Product code

5810

Other means of identification

Not available.

Product type

Aerosol.

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

Manufacturer

Krylon Products Group

101 W. Prospect Avenue Cleveland, OH 44115

Emergency telephone number of the company

US / Canada: (216) 566-2917

Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Product Information Telephone Number

US / Canada: (800) 457-9566 Mexico: Not Available

Regulatory Information Telephone Number

US / Canada: (216) 566-2902 Mexico: Not Available

Transportation Emergency Telephone Number

US / Canada: (216) 566-2917

Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Section 2. Hazards identification

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

FLAMMABLE AEROSOLS - Category 1

GASES UNDER PRESSURE - Compressed gas

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

SKIN SENSITIZATION - Category 1

CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract

irritation) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -

Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1

ASPIRATION HAZARD - Category 1

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 30.4%

(oral), 32.1% (dermal), 32.1% (inhalation)

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

Causes serious eye irritation.

May cause respiratory irritation.

May cause drowsiness or dizziness.

Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure. (lungs)

Precautionary statements

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use.

Response

IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place. Keep container tightly closed.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Hazards not otherwise classified

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations.

Section 3. Composition/information on ingredients

Substance/mixture

Mixture

Other means of identification

Not available.

CAS number/other identifiers

Ingredient name

% by weight

CAS number

Propane

≥10 - ≤25

74-98-6

Talc

≥10 - ≤25

14807-96-6

Acetone

≥10 - ≤25

67-64-1

Lt. Aliphatic Hydrocarbon Solvent

≥10 - ≤25

64742-89-8

Butane

≤10

106-97-8

Titanium Dioxide

≤10

13463-67-7

n-Butyl Acetate

≤7.7

123-86-4

Xylene, mixed isomers

≤2.2

1330-20-7

Ethyl 3-Ethoxypropionate

≤3

763-69-9

Ethylbenzene

<1

100-41-4

Unsaturated Fatty Acids

<1

85711-46-2

Light Aliphatic Hydrocarbon

≤0.3

64742-47-8

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Skin contact

May cause an allergic skin reaction.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following:

pain or irritation

watering

redness

Inhalation

Adverse symptoms may include the following:

respiratory tract irritation

coughing

nausea or vomiting

headache

drowsiness/fatigue

dizziness/vertigo

unconsciousness

Skin contact

Adverse symptoms may include the following:

irritation

redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments

No specific treatment.

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media

None known.

Specific hazards arising from the chemical

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.

Hazardous thermal decomposition products

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

phosphorus oxides

metal oxide/oxides

Special protective actions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools.

Empty containers retain product residue and can be hazardous.

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits (OSHA United States)

Ingredient name

CAS #

Exposure limits

Propane

74-98-6

NIOSH REL (United States, 10/2020).

TWA: 1000 ppm 10 hours.

TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 5/2018).

TWA: 1000 ppm 8 hours.

TWA: 1800 mg/m³ 8 hours.

Talc

14807-96-6

NIOSH REL (United States, 10/2020). TWA: 2 mg/m³ 10 hours. Form: Respirable fraction

ACGIH TLV (United States, 1/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction

Acetone

67-64-1

ACGIH TLV (United States, 1/2021).

TWA: 250 ppm 8 hours.

STEL: 500 ppm 15 minutes.

NIOSH REL (United States, 10/2020).

TWA: 250 ppm 10 hours.

TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 5/2018).

TWA: 1000 ppm 8 hours.

TWA: 2400 mg/m³ 8 hours.

Lt. Aliphatic Hydrocarbon Solvent

64742-89-8

None.

Butane

106-97-8

NIOSH REL (United States, 10/2020).

TWA: 800 ppm 10 hours.

TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 1/2021).

Explosive potential.

STEL: 1000 ppm 15 minutes.

Titanium Dioxide

13463-67-7

ACGIH TLV (United States, 1/2021).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 15 mg/m³ 8 hours. Form: Total dust

n-Butyl Acetate

123-86-4

NIOSH REL (United States, 10/2020).

TWA: 150 ppm 10 hours.

TWA: 710 mg/m³ 10 hours.

STEL: 200 ppm 15 minutes.

STEL: 950 mg/m³ 15 minutes.

OSHA PEL (United States, 5/2018).

TWA: 150 ppm 8 hours.

TWA: 710 mg/m³ 8 hours.

ACGIH TLV (United States, 1/2021).

STEL: 150 ppm 15 minutes.

TWA: 50 ppm 8 hours.

Xylene, mixed isomers

1330-20-7

ACGIH TLV (United States, 1/2021).

TWA: 100 ppm 8 hours.

TWA: 434 mg/m³ 8 hours.

STEL: 150 ppm 15 minutes.

STEL: 651 mg/m³ 15 minutes.

OSHA PEL (United States, 5/2018).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Ethyl 3-Ethoxypropionate

763-69-9

None.

Ethylbenzene

100-41-4

ACGIH TLV (United States, 1/2021).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2020).

TWA: 100 ppm 10 hours.

TWA: 435 mg/m³ 10 hours.

STEL: 125 ppm 15 minutes.

STEL: 545 mg/m³ 15 minutes.

OSHA PEL (United States, 5/2018).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Unsaturated Fatty Acids

85711-46-2

None.

Light Aliphatic Hydrocarbon

64742-47-8

ACGIH TLV (United States, 1/2021).

Absorbed through skin.

TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours.

Occupational exposure limits (Canada)

Ingredient name

CAS #

Exposure limits

Normal propane

74-98-6

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 1000 ppm 8 hours.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 1000 ppm 8 hours.

TWAEV: 1800 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 1250 ppm 15 minutes.

TWA: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada, 6/2021). Oxygen Depletion [Asphyxiant]. Explosive potential.

CA Ontario Provincial (Canada, 6/2019). Oxygen Depletion [Asphyxiant]. Explosive potential.

talc (none asbestiform)

14807-96-6

CA British Columbia Provincial (Canada, 6/2021).

TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021).

TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust.

CA Alberta Provincial (Canada, 6/2018).

Ingredient name

CAS #

Exposure limits

Normal propane

74-98-6

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 1000 ppm 8 hours.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 1000 ppm 8 hours.

TWAEV: 1800 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 1250 ppm 15 minutes.

TWA: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada, 6/2021). Oxygen Depletion [Asphyxiant]. Explosive potential.

CA Ontario Provincial (Canada, 6/2019). Oxygen Depletion [Asphyxiant]. Explosive potential.

talc (none asbestiform)

14807-96-6

CA British Columbia Provincial (Canada, 6/2021).

TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021).

TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust.

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 2 mg/m³ 8 hours. Form: Respirable particulate

CA Ontario Provincial (Canada, 6/2019).

TWA: 2 mg/m³ 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

TWA: 2 mg/m³ 8 hours. Form: respirable fraction

acetone

67-64-1

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 1200 mg/m³ 8 hours.

15 min OEL: 1800 mg/m³ 15 minutes.

8 hrs OEL: 500 ppm 8 hours.

15 min OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021).

TWA: 250 ppm 8 hours.

STEL: 500 ppm 15 minutes.

CA Ontario Provincial (Canada, 6/2019).

TWA: 250 ppm 8 hours.

STEL: 500 ppm 15 minutes.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 500 ppm 8 hours.

TWAEV: 1190 mg/m³ 8 hours.

STEV: 1000 ppm 15 minutes.

STEV: 2380 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours.

Butane

106-97-8

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 1000 ppm 8 hours.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 800 ppm 8 hours.

TWAEV: 1900 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 1250 ppm 15 minutes.

TWA: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada, 6/2021). Explosive potential.

STEL: 1000 ppm 15 minutes.

CA Ontario Provincial (Canada, 6/2019).

Explosive potential.

STEL: 1000 ppm 15 minutes.

Titanium dioxide

13463-67-7

CA British Columbia Provincial (Canada, 6/2021).

TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 10 mg/m³ 8 hours. Form: Total dust.

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 10 mg/m³ 8 hours.

CA Ontario Provincial (Canada, 6/2019).

TWA: 10 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 20 mg/m³ 15 minutes.

TWA: 10 mg/m³ 8 hours.

n-butyl acetate

123-86-4

CA Alberta Provincial (Canada, 6/2018).

15 min OEL: 200 ppm 15 minutes.

15 min OEL: 950 mg/m³ 15 minutes.

8 hrs OEL: 150 ppm 8 hours.

8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 200 ppm 15 minutes.

TWA: 150 ppm 8 hours.

CA Ontario Provincial (Canada, 6/2019).

STEL: 150 ppm 15 minutes.

TWA: 50 ppm 8 hours.

CA British Columbia Provincial (Canada, 6/2021).

STEL: 150 ppm 15 minutes.

TWA: 50 ppm 8 hours.

CA Quebec Provincial (Canada, 6/2021).

STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours.

Xylene

1330-20-7

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 100 ppm 8 hours.

15 min OEL: 651 mg/m³ 15 minutes.

15 min OEL: 150 ppm 15 minutes.

8 hrs OEL: 434 mg/m³ 8 hours.

CA British Columbia Provincial (Canada, 6/2021).

TWA: 100 ppm 8 hours.

STEL: 150 ppm 15 minutes.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 100 ppm 8 hours.

TWAEV: 434 mg/m³ 8 hours.

STEV: 150 ppm 15 minutes.

STEV: 651 mg/m³ 15 minutes.

CA Ontario Provincial (Canada, 6/2019).

STEL: 150 ppm 15 minutes.

TWA: 100 ppm 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours.

Ethylbenzene

100-41-4

CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 100 ppm 8 hours.

8 hrs OEL: 434 mg/m³ 8 hours.

15 min OEL: 543 mg/m³ 15 minutes.

15 min OEL: 125 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021).

TWA: 20 ppm 8 hours.

CA Ontario Provincial (Canada, 6/2019).

TWA: 20 ppm 8 hours.

CA Quebec Provincial (Canada, 6/2021).

TWAEV: 20 ppm 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 125 ppm 15 minutes.

TWA: 100 ppm 8 hours.

Petroleum refining, hydrotreated light distillate

64742-47-8

CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin.

TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours.

CA Alberta Provincial (Canada, 6/2018).

Absorbed through skin.

8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours.

CA Ontario Provincial (Canada, 6/2019).

Absorbed through skin.

TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours.

CAS #

Exposure limits

Propane

74-98-6

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 1000 ppm 8 hours.

Acetone

67-64-1

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 500 ppm 8 hours.

STEL: 750 ppm 15 minutes.

Butane

106-97-8

NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours.

n-Butyl Acetate

123-86-4

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 150 ppm 8 hours.

STEL: 200 ppm 15 minutes.

Xylene, mixed isomers

1330-20-7

NOM-010-STPS-2014 (Mexico, 4/2016).

STEL: 150 ppm 15 minutes.

TWA: 100 ppm 8 hours.

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Skin protection

Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Section 9. Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance

Physical state

Liquid.

Color

Not available.

Odor

Not available.

Odor threshold

Not available.

pH

7

Melting point/freezing point

Not available.

Boiling point, initial boiling point, and boiling range

Not available.

Flash point

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Evaporation rate

5.6 (butyl acetate = 1)

Flammability

Not available.

Lower and upper explosion limit/flammability limit

Lower: 0.9%

Upper: 12.8%

Vapor pressure

101.3 kPa (760 mm Hg)

Relative vapor density

1.55 [Air = 1]

Relative density

0.85

Solubility

Not available.

Partition coefficient: noctanol/water

Not applicable.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Kinematic (40°C (104°F)): <20.5 mm²/s (<20.5 cSt)

Molecular weight

Not applicable.

Aerosol product

Type of aerosol

Spray

Heat of combustion

24.167 kJ/g

Section 10. Stability and reactivity

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

The product is stable.

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible materials

No specific data.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name

Result

Species

Dose

Exposure

Acetone

LD50 Oral

Rat

5800 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

n-Butyl Acetate

LD50 Dermal

Rabbit

>17600 mg/kg

-

LD50 Oral

Rat

10768 mg/kg

-

Xylene, mixed isomers

LC50 Inhalation Gas.

Rat

6700 ppm

4 hours

LD50 Oral

Rat

4300 mg/kg

-

Ethyl 3-Ethoxypropionate

LD50 Oral

Rat

3200 mg/kg

-

Ethylbenzene

LD50 Dermal

Rabbit

>5000 mg/kg

-

LD50 Oral

Rat

3500 mg/kg

-

Product/ingredient name

Result

Species

Score

Exposure

Observation

Talc

Skin - Mild irritant

Human

-

72 hours 300 ug I

-

Acetone

Eyes - Mild irritant

Human

-

186300 ppm

-

Eyes - Mild irritant

Rabbit

-

10 uL

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20

mg

-

Eyes - Severe irritant

Rabbit

-

20 mg

-

Skin - Mild irritant

Rabbit

-

24 hours 500

mg

-

Skin - Mild irritant

Rabbit

-

395 mg

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300 ug I

-

n-Butyl Acetate

Eyes - Moderate irritant

Rabbit

-

100 mg

-

Skin - Moderate irritant

Rabbit

-

24 hours 500

mg

-

Xylene, mixed isomers

Eyes - Mild irritant

Rabbit

-

87 mg

-

Eyes - Severe irritant

Rabbit

-

24 hours 5

mg

-

Skin - Mild irritant

Rat

-

8 hours 60 uL

-

Skin - Moderate irritant

Rabbit

-

24 hours 500

mg

-

Skin - Moderate irritant

Rabbit

-

100 %

-

Ethyl 3-Ethoxypropionate

Skin - Mild irritant

Rabbit

-

24 hours 500 mg

-

Ethylbenzene

Eyes - Severe irritant

Rabbit

-

500 mg

-

Skin - Mild irritant

Rabbit

-

24 hours 15

mg

-

Sensitization

Not available.

Mutagenicity

Not available.

Carcinogenicity

Not available.

Product/ingredient name

OSHA

IARC

NTP

Talc

-

3

-

Titanium Dioxide

-

2B

-

Xylene, mixed isomers

-

3

-

Ethylbenzene

-

2B

-

Reproductive toxicity

Not available.

Teratogenicity

Not available.

Name

Category

Route of exposure

Target organs

Propane

Category 3

-

Respiratory tract irritation

Category 3

Narcotic effects

Acetone

Category 3

-

Respiratory tract irritation

Category 3

Narcotic effects

Lt. Aliphatic Hydrocarbon Solvent

Category 3

-

Respiratory tract irritation

Category 3

Narcotic effects

Butane

Category 3

-

Respiratory tract irritation

Category 3

Narcotic effects

n-Butyl Acetate

Category 3

-

Narcotic effects

Xylene, mixed isomers

Category 3

-

Respiratory tract irritation

Ethylbenzene

Category 3

-

Respiratory tract irritation

Category 3

Narcotic effects

Name

Category

Route of exposure

Target organs

Propane

Category 2

-

-

Talc

Category 1

inhalation

lungs

Acetone

Category 2

-

-

Lt. Aliphatic Hydrocarbon Solvent

Category 2

-

-

Butane

Category 2

-

-

Xylene, mixed isomers

Category 2

-

-

Ethylbenzene

Category 2

-

-

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Xylene, mixed isomers

ASPIRATION HAZARD - Category 1

Ethylbenzene

ASPIRATION HAZARD - Category 1

Light Aliphatic Hydrocarbon

ASPIRATION HAZARD - Category 1

Information on the likely routes of exposure

Not available.

Potential acute health effects

Eye contact

: Causes serious eye irritation.

Inhalation

: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Skin contact

: May cause an allergic skin reaction.

Ingestion

: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: respiratory tract irritation

coughing

nausea or vomiting

headache

drowsiness/fatigue

dizziness/vertigo

unconsciousness

Skin contact

Adverse symptoms may include the following:

irritation

redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects

Not available.

Potential delayed effects

Not available.

Long term exposure

Potential immediate effects

Not available.

Potential delayed effects

Not available.

Potential chronic health effects

General

Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

Carcinogenicity

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Route

ATE value

Oral

66106.17 mg/kg

Dermal

33307.8 mg/kg

Inhalation (gases)

202874.76 ppm

Section 12. Ecological information

Toxicity

Product/ingredient name

Result

Species

Exposure

Acetone

Acute EC50 7200000 µg/l Fresh water

Algae - Selenastrum sp.

96 hours

Acute LC50 4.42589 ml/L Marine water

Crustaceans - Acartia tonsa Copepodid

48 hours

Acute LC50 7460000 µg/l Fresh water

Daphnia - Daphnia cucullata

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

n-Butyl Acetate

Acute LC50 32 mg/l Marine water

Crustaceans - Artemia salina

48 hours

Acute LC50 18000 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Xylene, mixed isomers

Acute LC50 8500 µg/l Marine water

Crustaceans - Palaemonetes pugio

48 hours

Acute LC50 13400 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Ethylbenzene

Acute EC50 4900 µg/l Marine water

Algae - Skeletonema costatum

72 hours

Acute EC50 7700 µg/l Marine water

Algae - Skeletonema costatum

96 hours

Acute EC50 6.53 mg/l Marine water

Crustaceans - Artemia sp. Nauplii

48 hours

Acute EC50 2.93 mg/l Fresh water

Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 4200 μg/l Fresh water

Fish - Oncorhynchus mykiss

96 hours

Light Aliphatic Hydrocarbon

Acute LC50 2200 μg/l Fresh water

Fish - Lepomis macrochirus

4 days

Persistence and degradability

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

-

-

Readily

n-Butyl Acetate

-

-

Readily

Xylene, mixed isomers

-

-

Readily

Ethylbenzene

-

-

Readily

Bioaccumulative potential

Product/ingredient name

LogP_ow

BCF

Potential

Lt. Aliphatic Hydrocarbon Solvent

-

10 to 2500

high

Xylene, mixed isomers

-

8.1 to 25.9

low

Mobility in soil

Soil/water partition coefficient (K_OC)

Not available.

Other adverse effects

No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

Section 14. Transport information

Mexico Classification

UN number

UN1950

UN1950

UN1950

UN1950

UN1950

UN proper shipping name

AEROSOLS

AEROSOLS

AEROSOLS

AEROSOLS, flammable

AEROSOLS

Transport hazard class(es)

2.1

2.1

2.1

2.1

2.1

Packing group

-

-

-

-

-

Environmental hazards

No.

No.

No.

No.

No.

Additional information

-

Product classified as per the following sections of the

Transportation of Dangerous Goods Regulations:

2.13-2.17 (Class 2).

-

-

-

Dependent upon container size, this product may ship under the Limited Quantity shipping exception.

Dependent upon container size, this product may ship under the Limited Quantity shipping exception.

Dependent upon container size, this product may ship under the Limited Quantity shipping exception.

Dependent upon container size, this product may ship under the Limited Quantity shipping exception.

Dependent upon container size, this product may ship under the Limited Quantity shipping exception.

Special precautions for user

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

Transport in bulk according to IMO instruments

Not available.

Proper shipping name

Not available.

Section 15. Regulatory information

SARA 313

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

California Prop. 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

International regulations

International lists

Australia inventory (AIIC): Not determined.

China inventory (IECSC): Not determined.

Japan inventory (CSCL): Not determined.

Japan inventory (ISHL): Not determined.

Korea inventory (KECI): Not determined.

New Zealand Inventory of Chemicals (NZIoC): Not determined.

Philippines inventory (PICCS): Not determined.

Taiwan Chemical Substances Inventory (TCSI): Not determined.

Thailand inventory: Not determined.

Turkey inventory: Not determined.

Vietnam inventory: Not determined.

Section 16. Other information

Hazardous Material Information System (U.S.A.)

Health

3

Flammability

4

Physical hazards

3

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

Procedure used to derive the classification

Classification

Justification

FLAMMABLE AEROSOLS - Category 1

On basis of test data

GASES UNDER PRESSURE - Compressed gas

Calculation method

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

Calculation method

SKIN SENSITIZATION - Category 1

Calculation method

CARCINOGENICITY - Category 2

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1

Calculation method

ASPIRATION HAZARD - Category 1

Calculation method

History

Date of printing

6/18/2022

Date of issue/Date of revision

6/18/2022

Date of previous issue

4/16/2022

Version

22

Key to abbreviations

ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations

Notice to reader

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.