SECTION 1: IDENTIFICATION

1.1. Product Identifier

Product Form: Mixture

Product Name: UTC - Water Blown B Component (Polyurethane resin blend with Amine Catalyst)

1.2. Intended Use of the Product

Use of the substance/mixture: Component of a two-part polyurethane system.

1.3. Name, Address, and Telephone of the Responsible Party

Company

URETHANE TECHNOLOGY CO

59-77 TEMPLE AVENUE

NEWBURGH NY 12550

(845) 561-5500

1.4. Emergency Telephone Number

Emergency Number : Chemtrec: (800) 424-9300 or (703) 527-3887

2.1. Classification of the Substance or Mixture

Classification (GHS-US)

Skin Irrit. 2

Eye Dam. 1

H315

H318

2.2. Label Elements

GHS-US Labeling

Hazard Pictograms (GHS-US)

Signal Word (GHS-US)

Danger

Hazard Statements (GHS-US)

H315 - Causes skin irritation

H318 - Causes serious eye damage

Precautionary Statements (GHS-US)

P264 - Wash hands, forearms, and exposed areas thoroughly after handling

P280 - Wear eye protection, face protection, protective clothing, protective gloves

P302+P352 - IF ON SKIN: Wash with plenty of soap and water

P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing

P310 - Immediately call a POISON CENTER or doctor/physician

P321 - Specific treatment (see Section 4)

P332+P313 - If skin irritation occurs: Get medical advice/attention

P362 - Take off contaminated clothing and wash before reuse

2.3. Other Hazards

Other Hazards Not Contributing to the Classification:

Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions.

2.4. Unknown Acute Toxicity (GHS-US)

No data available

3.1. Substance

Not applicable

3.2. Mixture

Name

Product identifier

%

Classification (GHS-US)

Glycerol poly(oxyethylene) poly(oxypropylene) ether

(CAS No) 9082-00-2

50 - 80

Not classified

Water

(CAS No) 7732-18-5

10 - 40

Not classified

2-(Dimethylamino)ethanol

(CAS No) 108-01-0

< 5

Flam. Liq. 3, H226

Acute Tox. 4 (Oral), H302

Acute Tox. 4 (Dermal), H312

Acute Tox. 3

(Inhalation:vapour), H331

Skin Corr. 1B, H314

Eye Dam. 1, H318

STOT SE 3, H335

Aquatic Acute 3, H402

Full text of H-phrases: see section 16

4.1. Description of First Aid Measures

First-aid Measures General

Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).

First-aid Measures After Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists.

First-aid Measures After Skin Contact

Rinse immediately with plenty of water. Obtain medical attention if irritation develops or persists.

First-aid Measures After Eye Contact:

Rinse cautiously with water for at least 60 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention.

First-aid Measures After Ingestion

Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physician.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/Injuries

Causes serious eye damage. Causes skin irritation.

Symptoms/Injuries After Inhalation

May cause respiratory irritation.

Symptoms/Injuries After Skin Contact

Causes skin irritation.

Symptoms/Injuries After Eye Contact

Causes serious eye damage.

Symptoms/Injuries After Ingestion

Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms

None expected under normal conditions of use.

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

If you feel unwell, seek medical advice (show the label where possible).

5.1. Extinguishing Media

Suitable Extinguishing Media

Use extinguishing media appropriate for surrounding fire.

Unsuitable Extinguishing Media

Do not use a heavy water stream. Use of heavy stream of water may spread fire. Application of water stream to hot product may cause frothing and increase fire intensity.

5.2. Special Hazards Arising From the Substance or Mixture

Fire Hazard

Not considered flammable but may burn at high temperatures.

Explosion Hazard

Product is not explosive.

Reactivity

Hazardous reactions will not occur under normal conditions.

5.3. Advice for Firefighters

Precautionary Measures Fire

Exercise caution when fighting any chemical fire.

Firefighting Instructions

Use water spray or fog for cooling exposed containers.

Protection During Firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

Other information

Refer to Section 9 for flammability properties.

6.1. Personal Precautions, Protective Equipment and Emergency Procedures

General Measures

Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray).

6.1.1. For Non-emergency Personnel

Protective Equipment

Use appropriate personal protection equipment (PPE).

Emergency Procedures

Evacuate unnecessary personnel.

6.1.2. For Emergency Responders

Protective Equipment

Equip cleanup crew with proper protection.

Emergency Procedures

Stop leak if safe to do so. Eliminate ignition sources. Ventilate area.

6.2. Environmental Precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and Material for Containment and Cleaning Up

For Containment

Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.

Methods for Cleaning Up

Clear up spills immediately and dispose of waste safely. Prepare a decontamination solution of 0.2%0.5% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium hydroxide). Allow deactivated material to stand for at least 30 minutes before shoveling into drums. Do not tighten the bungs. Mixing with wet earth is also effective, but slower. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill.

6.4. Reference to Other Sections

See Heading 8. Exposure controls and personal protection.

7.1. Precautions for Safe Handling

Hygiene Measures

Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2. Conditions for Safe Storage, Including Any Incompatibilities

Technical Measures

Comply with applicable regulations.

Storage Conditions

Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials.

Incompatible Products

Strong acids. Strong bases. Strong oxidizers.

7.3. Specific End Use(s)

Component of a two-part polyurethane system.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control Parameters

No Occupational Exposure Limits (OELs) have been established for this product or its chemical components.

8.2. Exposure Controls

Appropriate Engineering Controls

Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed.

Personal Protective Equipment

Protective goggles. Gloves. Protective clothing. Face shield.

Open

Materials for Protective Clothing

Chemically resistant materials and fabrics.

Hand Protection

Wear chemically resistant protective gloves.

Eye Protection

Chemical goggles or safety glasses. Face shield.

Skin and Body Protection

Wear suitable protective clothing.

Respiratory Protection

Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits.

Environmental Exposure Controls

Do not allow the product to be released into the environment.

Consumer Exposure Controls

Do not eat, drink or smoke during use.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on Basic Physical and Chemical Properties

Physical State

Liquid

Odor

Amine like, or organic odor

Odor Threshold

No data available

pH

No data available

Relative Evaporation Rate (butylacetate=1)

No data available

Melting Point

No data available

Freezing Point

No data available

Boiling Point

No data available

Flash Point

> 110 °C (> 230 °F)

Auto-ignition Temperature

No data available

Decomposition Temperature

No data available

Flammability (solid, gas)

No data available

Vapor Pressure

No data available

Relative Vapor Density at 20 °C

No data available

Relative Density

No data available

Specific Gravity

No data available

Solubility

No data available

Partition coefficient: n-octanol/water

No data available

Viscosity

No data available

9.2. Other Information

No additional information available

10.1 Reactivity

Hazardous reactions will not occur under normal conditions.

10.2 Chemical Stability

Stable under recommended handling and storage conditions (see section 7).

10.3 Possibility of Hazardous Reactions

Hazardous polymerization will not occur.

10.4 Conditions to Avoid

Direct sunlight. Extremely high or low temperatures. Ignition sources. Incompatible materials.

10.5 Incompatible Materials

Strong acids. Strong bases. Strong oxidizers.

10.6 Hazardous Decomposition Products

Carbon oxides (CO, CO₂). Nitrogen oxides. Hydrogen cyanide.

11.1. Information On Toxicological Effects

Acute Toxicity

Not classified

Glycerol poly(oxyethylene) poly(oxypropylene) ether (9082-00-2)

LD50 Oral Rat

> 10 g/kg

2-(Dimethylamino)ethanol (108-01-0)

LD50 Oral Rat

1803 mg/kg

LD50 Dermal Rabbit

1220 mg/kg

LC50 Inhalation Rat (ppm)

1641 ppm/4h

Skin Corrosion/Irritation

Causes skin irritation.

Serious Eye Damage/Irritation

Causes serious eye damage.

Respiratory or Skin Sensitization

Not classified

Germ Cell Mutagenicity

Not classified

Carcinogenicity

Not classified

Reproductive Toxicity

Not classified

Specific Target Organ Toxicity (Single Exposure)

Not classified

Specific Target Organ Toxicity (Repeated Exposure)

Not classified

Aspiration Hazard

Not classified

Symptoms/Injuries After Inhalation

May cause respiratory irritation.

Symptoms/Injuries After Skin Contact

Causes skin irritation.

Symptoms/Injuries After Eye Contact

Causes serious eye damage.

Symptoms/Injuries After Ingestion

Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms

None expected under normal conditions of use.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity

2-(Dimethylamino)ethanol (108-01-0)

LC50 Fish 1

81 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

EC50 Daphnia 1

98.77 mg/l (Exposure time: 48 h - Species: Daphnia magna)

EC50 Other Aquatic Organisms 1

35 mg/l (Exposure time: 72 h - Species: Desmodesmus subspicatus)

12.2. Persistence and Degradability

No additional information available

12.3. Bioaccumulative Potential

2-(Dimethylamino)ethanol (108-01-0)

Log Pow

-0.55 (at 23 °C)

12.4. Mobility in Soil

No additional information available

12.5. Other Adverse Effects

Other Information

Avoid release to the environment.

13.1. Waste treatment methods

Waste Disposal Recommendations

Dispose of waste material in accordance with all local, regional, national, and international regulations.

Ecology – Waste Materials

Avoid release to the environment.

14.1 In Accordance with DOT

Not regulated for transport

14.2 In Accordance with IMDG

Not regulated for transport

14.3 In Accordance with IATA

Not regulated for transport

SECTION 15: REGULATORY INFORMATION

15.1 US Federal Regulations

UTC - Water Blown B Component (Polyurethane resin blend with Amine Catalyst)

SARA Section 311/312 Hazard Classes

Immediate (acute) health hazard

Glycerol poly(oxyethylene) poly(oxypropylene) ether (9082-00-2)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

2-(Dimethylamino)ethanol (108-01-0)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

Water (7732-18-5)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2 US State Regulations

Glycerol poly(oxyethylene) poly(oxypropylene) ether (9082-00-2)

U.S. - Texas - Effects Screening Levels - Long Term

U.S. - Texas - Effects Screening Levels - Short Term

2-(Dimethylamino)ethanol (108-01-0)

U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1

U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2

U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity

U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1

U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 RTK - U.S. - Massachusetts - Right To Know List

U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour

U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual

RTK - U.S. - New Jersey - Right to Know Hazardous Substance List

U.S. - New Jersey - Special Health Hazards Substances List

RTK - U.S. - Pennsylvania - RTK (Right to Know) List

U.S. - Texas - Effects Screening Levels - Long Term

U.S. - Texas - Effects Screening Levels - Short Term

Revision date

11/09/2015

Other Information

This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200

GHS Full Text Phrases

Acute Tox. 3 (Inhalation:vapour)

Acute toxicity (inhalation:vapour) Category 3

Acute Tox. 4 (Dermal)

Acute toxicity (dermal) Category 4

Acute Tox. 4 (Oral)

Acute toxicity (oral) Category 4

Aquatic Acute 3

Hazardous to the aquatic environment - Acute Hazard Category 3

Eye Dam. 1

Serious eye damage/eye irritation Category 1

Flam. Liq. 3

Flammable liquids Category 3

Skin Corr. 1B

Skin corrosion/irritation Category 1B

Skin Irrit. 2

Skin corrosion/irritation Category 2

STOT SE 3

Specific target organ toxicity (single exposure) Category 3

H226

Flammable liquid and vapor

H302

Harmful if swallowed

H312

Harmful in contact with skin

H314

Causes severe skin burns and eye damage

H315

Causes skin irritation

H318

Causes serious eye damage

H331

Toxic if inhaled

H335

May cause respiratory irritation

H402

Harmful to aquatic life

NFPA Health Hazard

2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.

NFPA Fire Hazard

1 - Must be preheated before ignition can occur.

NFPA Reactivity

1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently.

HMIS III Rating

Health

2 Moderate Hazard

Flammability

1 Slight Hazard

Physical

1 Slight Hazard