Terminator5099

 

Safety Data Sheet

Issue Date: 01-Apr-2014

Revision Date: 14-Sep-2017

Version: 3

1. IDENTIFICATION

Product Identifier

Product Name

Buckeye Terminator

Other means of identification

SDS #

BE-5099

Product Code

5099

Registration Number(s)

EPA Reg. No. 6836-75-559

UN/ID No

UN1760

Recommended use of the chemical and restrictions on use

Recommended Use

EPA registered disinfectant.

Details of the supplier of the safety data sheet

Supplier Address

Buckeye International, Inc.

2700 Wagner Place

Maryland Heights, MO 63043 USA

Emergency Telephone Number

Company Phone Number

1-314-291-1900

Emergency Telephone (24 hr)

Transportation - INFOTRAC 1-352-323-3500 (International)

1-800-535-5053 (North America)

Medical - (International) 1-651-632-8956

(North America) 1-800-303-0441

2. HAZARDS IDENTIFICATION

Emergency Overview

This chemical is a product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-EPA registered chemicals. Please see Section 15 for additional EPA information.

Appearance

Clear green liquid

Physical State

Liquid

Odor

Mild Fragrance added

Classification

Skin corrosion/irritation

Category 1 Sub-category B

Serious eye damage/eye irritation

Category 1

Signal Word

Danger

Hazard statements

Causes severe skin burns and eye damage

Precautionary Statements - Prevention

Wear protective gloves/protective clothing/eye protection/face protection

Wash face, hands and any exposed skin thoroughly after handling

Do not breathe dust/fume/gas/mist/vapors/spray

Precautionary Statements - Response

If exposed or concerned: Get medical advice/attention

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

Precautionary Statements - Storage

Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name

CAS No.

Weight-%

Nonylphenol Ethoxylate

127087-87-0

1.5-3.5

Di-n-alkyl Dimethyl Ammonium Chloride

68424-95-3

2.0-3.5

Alkyl dimethyl benzyl ammonium chloride (C12-16)

68424-85-1

1.0-2.5

Ethyl Alcohol

64-17-5

0.5-1.0

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**

4. FIRST AID MEASURES

First Aid Measures

Eye Contact

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

Skin Contact

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. Immediately call a poison center or doctor/physician.

Inhalation

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Immediately call a poison center or doctor/physician.

Ingestion

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Have person sip a glass of water if able to swallow. Never give anything by mouth to an unconscious person. Immediately call a poison center or doctor/physician.

Most important symptoms and effects

Symptoms

Causes severe skin burns and eye damage. Mist or vapor inhalation can cause irritation to the nose, throat, and upper respiratory tract. Ingestion may cause nausea and headache.

Indication of any immediate medical attention and special treatment needed

Notes to Physician

Treat symptomatically. If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Dermatitis or other pre-existing skin conditions may be aggravated by overexposure to this product.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Dry chemical. Foam. Water.

Unsuitable Extinguishing Media

Not determined.

Specific Hazards Arising from the Chemical

Combustion products may be toxic.

Hazardous Combustion Products

Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

 

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions

Use personal protective equipment as required.

Environmental precautions

Environmental precautions

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment

Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up

Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8. Wash face, hands and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray.

Conditions for safe storage, including any incompatibilities

Storage Conditions

Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep container closed when not in use.

Packaging Materials

Rinse container before discarding.

Incompatible Materials

Chlorine bleach. Anionic detergents.

 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name

ACGIH TLV

OSHA PEL

NIOSH IDLH

Ethyl Alcohol

64-17-5

STEL: 1000 ppm

TWA: 1000 ppm

TWA: 1900 mg/m3

(vacated) TWA: 1000 ppm

(vacated) TWA: 1900 mg/m3

IDLH: 3300 ppm

TWA: 1000 ppm

TWA: 1900 mg/m3

Appropriate engineering controls

Engineering Controls

Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.

Individual protection measures, such as personal protective equipment

Eye/Face Protection

Splash goggles or safety glasses.

Skin and Body Protection

Rubber gloves. Normal work clothing (long sleeved shirts and long pants) is recommended. Wear water or chemical resistant footwear when scrubbing floors.

Respiratory Protection

Refer to 29 CFR 1910.134 for respiratory protection requirements.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state

Liquid

Appearance

Clear green liquid

Color

Clear green

Odor

Mild Fragrance added

Odor Threshold

Not determined

Property

Values

Remarks / Method

pH

11.8-12.2 (conc.)

9.7-10.7 (1:64 dilution)

 

Melting Point/Freezing Point

Not determined

 

Boiling Point/Boiling Range

100 °C / 212 °F

 

Flash Point

>93.3 °C / >200 °F

Tag Closed Cup

Evaporation Rate

1.0

(Water = 1)

Flammability (Solid, Gas)

Liquid-Not Applicable

 

Flammability Limits in Air

Upper Flammability Limits

Not Applicable

 

Lower Flammability Limit

Not Applicable

 

Vapor Pressure

Not determined

 

Vapor Density

Not determined

 

Relative Density

1.01

 

Water Solubility

Infinite

 

Solubility in other solvents

Not determined

 

Partition Coefficient

Not determined

 

Auto-ignition Temperature

Not determined

 

Decomposition Temperature

Not determined

 

Kinematic Viscosity

Not determined

 

Dynamic Viscosity

Not determined

 

Explosive Properties

Not determined

 

Oxidizing Properties

Not determined

 

10. STABILITY AND REACTIVITY

Reactivity

Not reactive under normal conditions.

Chemical Stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Hazardous Polymerization

Hazardous polymerization does not occur.

Conditions to Avoid

Keep separated from incompatible substances. Keep out of reach of children.

Incompatible Materials

Chlorine bleach. Anionic detergents.

Hazardous Decomposition Products

Thermal decomposition can lead to release of irritating and toxic gases and vapors.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact

Causes severe eye damage.

Skin Contact

Causes severe skin burns.

Inhalation

Avoid breathing vapors or mists.

Ingestion

Do not ingest.

Component Information

Chemical Name

Oral LD50

Dermal LD50

Inhalation LC50

Nonylphenol Ethoxylate

127087-87-0

= 1310 mg/kg (Rat)

-

-

Alkyl dimethyl benzyl ammonium chloride (C12-16)

68424-85-1

= 426 mg/kg (Rat)

-

-

Ethyl Alcohol

64-17-5

= 7060 mg/kg (Rat)

-

= 124.7 mg/L ( Rat ) 4 h

Information on physical, chemical and toxicological effects

Symptoms

Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity

The ingredient in this product is only classified as a carcinogen when consumed as an alcoholic beverage in long-term studies.

Chemical Name

ACGIH

IARC

NTP

OSHA

Ethyl Alcohol

64-17-5

A3

Group 1

Known

X

Legend

ACGIH (American Conference of Governmental Industrial Hygienists)

A3

Animal Carcinogen

IARC (International Agency for Research on Cancer)

Group 1

Carcinogenic to Humans

NTP (National Toxicology Program)

Known

Known Carcinogen

OSHA (Occupational Safety and Health Administration of the US Department of Labor)

X

Present

Numerical measures of toxicity

Not determined

12. ECOLOGICAL INFORMATION

Ecotoxicity

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Component Information

Chemical Name

Algae/aquatic plants

Fish

Crustacea

Ethyl Alcohol

64-17-5

 

12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static

10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static 9268 - 14221: 48 h Daphnia magna mg/L LC50

Persistence/Degradability

Not determined.

Bioaccumulation

Not determined.

Mobility

Chemical Name

Partition Coefficient

Ethyl Alcohol

64-17-5

0.32

Other Adverse Effects

Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging

Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Status

Chemical Name

California Hazardous Waste Status

Ethyl Alcohol

64-17-5

Toxic

Ignitable

14. TRANSPORT INFORMATION

Note

Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.

DOT

UN/ID No

UN1760

Proper Shipping Name

Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride)

Hazard Class

8

Packing Group

II

IATA

UN/ID No

UN1760

Proper Shipping Name

Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride)

Hazard Class

8

Packing Group

II

IMDG - Not regulated

UN/ID No

UN1760

Proper Shipping Name

Corrosive liquid, n.o.s. (Dialkyldimethylammonium chloride)

Hazard Class

8

Packing Group

II

Marine Pollutant

Not a marine pollutant

15. REGULATORY INFORMATION

International Inventories

Chemical Name

TSCA

DSL/NDSL

EINECS/E LINCS

ENCS

IECSC

KECL

PICCS

AICS

Nonylphenol Ethoxylate

X

X

X

Present

X

Present

X

X

Di-n-alkyl Dimethyl Ammonium Chloride

X

X

X

Present

X

Present

X

X

Alkyl dimethyl benzyl ammonium chloride (C12-16)

X

X

X

Present

X

Present

X

X

Ethyl Alcohol

X

X

X

Present

X

Present

X

X

Legend:

TSCA

United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL

Canadian Domestic Substances List/Non-Domestic Substances List

EINECS/ELINCS

European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances

ENCS

Japan Existing and New Chemical Substances

IECSC

China Inventory of Existing Chemical Substances

KECL

Korean Existing and Evaluated Chemical Substances

PICCS

Philippines Inventory of Chemicals and Chemical Substances

AICS

Australian Inventory of Chemical Substances

US Federal Regulations

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).

SARA 313

Not determined

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

US State Regulations

California Proposition 65

This product contains the following Proposition 65 chemicals.

Chemical Name

California Proposition 65

Ethyl Alcohol - 64-17-5

Carcinogen

Developmental

U.S. State Right-to-Know Regulations

Chemical Name

New Jersey

Massachusetts

Pennsylvania

Water

 

 

X

7732-18-5

 

 

 

Ethyl Alcohol

X

X

X

64-17-5

 

 

 

EPA Pesticide Registration Number

EPA Reg. No 6836-75-559

EPA Statement

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

EPA Pesticide Label

Signal Word: Danger

Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin or on clothing. Wear protective eyewear (goggles, face shield or safety glasses), protective (rubber or chemical resistant) gloves and protective clothing. Harmful if swallowed or absorbed through the skin. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse

Difference between SDS and EPA pesticide label

 

EPA

OSHA

Signal Word

Danger

Danger

Skin corrosion/irritation

Causes skin burns

Causes severe skin burns

Serious eye damage/eye irritation

Causes irreversible eye damage

Causes serious eye damage

16. OTHER INFORMATION

NFPA

Health Hazards

Flammability

Instability

Special Hazards

 

3

1

0

Not determined

HMIS

Health Hazards

Flammability

Physical hazards

Personal Protection

 

Not determined

Not determined

Not determined

Not determined

Issue Date:

01-Apr-2014

Revision Date:

14-Sep-2017

Revision Note:

Regulatory Update

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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