Tough Guy Concentrated Glass Cleaner
Common Name: TOUGH GUY CONCENTRATED GLASS CLEANER
Manufacturer: W.W. GRAINGER
SDS Revision Date: 7/5/2011
SDS Format: No Format Specified
Item Number(s): 12M176
Manufacturer Model Number(s):
SAFETY DATA SHEET
GRAINGER(R*) FOR THE ONES WHO GET IT DONE
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINGER PKWY.
LAKE FOREST, IL 60045-5201
1-847-535-1000
SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TOUGH GUY CONCENTRATED GLASS CLEANER
PRODUCT USE: CONCENTRATED GLASS CLEANER
PRODUCT CODE: 12M176
DATE OF ISSUE: 07/05/11
SUPERSEDES:
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
TECHNICAL SERVICES: 1-847-535-5400
FOR MEDICAL EMERGENCY:
(800) 983-4582 TOLL FREE
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD. ATLANTA, GA 30318
SECTION 2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING!
COMBUSTIBLE. CAUSES EYE AND SKIN IRRITATION. HARMFUL IF SWALLOWED.
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL PROTECTIVE EQUIPMENT.
ACUTE EFFECTS:
ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION.
EYES:
CAUSES EYE IRRITATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS, WATERING AND ITCHING.
SKIN:
CAUSES SKIN IRRITATION. SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING, OR REDDENING. PRODUCT MAY BE DERMAL ABSORBED.
INHALATION:
AVOID BREATHING VAPORS, SPRAY OR MISTS. OVER-EXPOSURE BY INHALATION MAY CAUSE RESPIRATORY IRRITATION. CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
INGESTION: INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION AND DIARRHEA.
CHRONIC EFFECTS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: BLOOD, KIDNEYS, THE REPRODUCTIVE SYSTEM, LIVER, UPPER RESPIRATORY TRACT, SKIN, EYES, CENTRAL NERVOUS SYSTEM (CNS).
CARCINOGENICITY:
INGREDIENTS: NOT LISTED AS CARCINOGEN BY OSHA, NTP OR IARC.
PRODUCT/INGREDIENT NAME: NOT AVAILABLE.
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 1
FLAMMABILITY 2
REACTIVITY 0
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
NAME OF HAZARDOUS INGREDIENTS | CAS NUMBER | % BY WEIGHT |
ETHANOL; ETHYL ALCOHOL; GRAIN ALCOHOL | 64-17-5 | 5 - 15 |
DETERGENT SURFACTANT BLEND | 65143-89-7 70191-76-3 | 1 - 5 |
AQUA AMMONIA 26 BE; AMMONIUM HYDROXIDE; AMMONIA, AQUEOUS SOLUTION | 1336-21-6 | < 3 |
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH AFFECTED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT:
CLOSED CUP: 44.44 DEG. C (112 DEG. F) FLAMMABLE LIMITS: NOT AVAILABLE. FLAMMABILITY: COMBUSTIBLE.
FIRE HAZARD:
COMBUSTIBLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
FIRE-FIGHTING PROCEDURES: USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM. NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
1
2
0
SECTION 6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN UP:
ELIMINATE ALL IGNITION SOURCES. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH WATER AND MOP UP IF WATER-SOLUBLE OR ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER.
SECTION 7. HANDLING AND STORAGE
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. DO NOT REUSE CONTAINER. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE.
STORAGE:
STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
STORE BETWEEN THE FOLLOWING TEMPERATURES:
40 DEG. F - 120 DEG. F (4.4 DEG. C - 49 DEG. C). KEEP OUT OF THE REACH OF CHILDREN.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
PRODUCT NAME | EXPOSURE LIMITS |
ETHANOL; ETHYL ALCOHOL; GRAIN ALCOHOL | NIOSH REL (UNITED STATES, 6/2009). TWA: 1000 PPM 10 HOUR(S). TWA: 1900 MG/M3 10 HOUR(S). OSHA PEL (UNITED STATES, 11/2006). TWA: 1000 PPM 8 HOUR(S). TWA: 1900 MG/M3 8 HOUR(S).
ACGIH TLV (UNITED STATES, 1/2009). STEL: 1000 PPM 15 MINUTE(S).
OSHA PEL 1989 (UNITED STATES, 3/1989). TWA: 1000 PPM 8 HOUR(S). TWA: 1900 MG/M3 8 HOUR(S). |
AQUA AMMONIA 26 BE; AMMONIUM HYDROXIDE; AMMONIA, AQUEOUS SOLUTION | ACGIH TLV (UNITED STATES). TWA: 25 PPM 8 HOUR(S).
ACGIH TLV / OSHA PEL (UNITED STATES). STEL: 35 PPM 15 MINUTE(S). |
PERSONAL PROTECTIVE EQUIPMENT (PPE):
SAFETY GLASSES
GLOVES
EYES: SAFETY GLASSES.
BODY: RECOMMENDED: NEOPRENE GLOVES. RUBBER GLOVES. NITRILE GLOVES.
RESPIRATORY:
USE WITH ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS BELOW THEIR RESPECTIVE OCCUPATIONAL EXPOSURE LIMITS.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: LIQUID.
pH: 10.5 TO 11.5
BOILING POINT: 104.44 DEG. C (220 DEG. F)
SPECIFIC GRAVITY: 0.99
SOLUBILITY:
EASILY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
COLOR: CLEAR. BLUE.
ODOR: AMMONIACAL.
VAPOR PRESSURE: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: 1 (WATER = 1)
VOC (CONSUMER): 10%
SECTION 10. STABILITY AND REACTIVITY
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES (CO, CO2)
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY: | ||||
PRODUCT/INGREDIENT NAME | RESULT | SPECIES | DOSE | EXPOSURE |
ETHYLENE GLYCOL MONOBUTYL ETHER | LD50 DERMAL LD50 DERMAL LD50 INTRAPERITONEAL LD50 INTRAVENOUS LD50 ORAL LD50 ORAL LD50 ORAL LD50 UNREPORTED LDLO ORAL TDLO ORAL TDLO UNREPORTED LC50 INHALATION VAPOR LC50 INHALATION VAPOR LC50 INHALATION GAS | GUINEA PIG RABBIT RAT
RAT GUINEA PIG RAT RAT RAT RAT RAT RAT RAT
GUINEA PIG
RAT | >2000 MG/KG 220 MG/KG 220 MG/KG
307 MG/KG 1200 MG/KG 917 MG/KG 250 MG/KG 917 MG/KG 1500 MG/KG 500 MG/KG 250 MG/KG 2900 MG/M3
>633 PPM
450 PPM |
7 HOURS
1 HOURS
4 HOURS |
DETERGENT SURFACTANT BLEND | LD50 DERMAL | RAT | >2000 MG/KG |
|
AQUA AMMONIA | LD50 ORAL LC50 INHALATION VAPOR | RAT MOUSE | 350 MG/KG 2500 PPM |
1 HOURS |
SECTION 12. ECOLOGICAL INFORMATION
ENVIRONMENTAL EFFECTS: NOT AVAILABLE.
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT NAME | TEST RESULT | SPECIES | EXPOSURE |
ETHANOL | ACUTE EC50 >100 PPM FRESH WATER | DAPHNIA - WATER FLEA - DAPHNIA MAGNA - <24 HOURS | 48 HOURS |
| ACUTE EC50 2000 (MICRO)G/L FRESH WATER | DAPHNIA - WATER FLEA - DAPHNIA MAGNA | 48 HOURS |
| ACUTE LC50 5680 MG/L FRESH WATER | DAPHNIA - WATER FLEA - DAPHNIA MAGNA - NEONATE - <24 HOURS | 48 HOURS |
| ACUTE LC50 13 M/L FRESH WATER | FISH - RAINBOW TROUT, DONALDSON TROUT - ONCORHYNCHUS MYKISS - 0.8 G | 96 HOURS |
| ACUTE LC50 13480000 (MICRO)G/L FRESH WATER | FISH - FATHEAD MINNOW - PIMEPHALES PROMELAS - JUVENILE (FLEDGLING, HATCHLING, WEANLING) - 4 TO 8 WEEKS - 1.1 TO 3.1 CM | 96 HOURS |
| ACUTE LC50 10000000 TO 11500000 (MICRO)G/L MARINE WATER | FISH - BLEAK - ALBURNUS ALBURNUS - 8 CM | 96 HOURS |
| ACUTE LC50 5577000 (MICRO)G/L FRESH WATER | DAPHNIA - WATER FLEA - CERIODAPHNIA DUBIA - NEONATE | 48 HOURS |
| ACUTE LC50 3715000 (MICRO)G/L FRESH WATER | DAPHNIA - WATER FLEA - CERIODAPHNIA DUBIA - NEONATE | 48 HOURS |
| ACUTE LC50 42000 (MICRO)G/L FRESH WATER | FISH - RAINBOW TROUT, DONALDSON TROUT - ONCORHYNCHUS MYKISS | 4 DAYS |
| ACUTE LC50 25500 (MICRO)G/L MARINE WATER | CRUSTACEANS - BRINE SHRIMP - ARTEMIA FRANCHISCANA - LARVAE | 48 HOURS |
| CHRONIC NOEC <6.3 G/L FRESH WATER | DAPHNIA - WATER FLEA - DAPHNIA MAGNA | 48 HOURS |
SECTION 13. DISPOSAL CONSIDERATIONS
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CODE: D001
CLASSIFICATION: (HAZARDOUS WASTE)
ORIGIN: (RCRA WASTE.)
SECTION 14. TRANSPORT INFORMATION
REGULATORY INFORMATION UN NUMBER PROPER SHIPPING NAME CLASSES PG* LABEL
DOT CLASSIFICATION NOT REGULATED. NOT A DOT CONTROLLED MATERIAL (UNITED STATES).
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING WITH YOUR SHIPMENT.
PG*: PACKING GROUP
SECTION 15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
PRODUCT NAME: AQUA AMMONIA
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: AQUA AMMONIA
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES: NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA INVENTORY.
UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
SECTION 16. OTHER INFORMATION
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE. HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE MEANINGS OF THIS SCALE.