Product name:

LOCTITE NS 5109 HIGH TEMP GASKET known as LOCTITE® GASKET MAKER HIGH TEM

IDH number:

226654

Product type:

Sealant

Item number:

30558

Restriction of Use:

None identified

Region:

United States

Company address:

Henkel Corporation

One Henkel Way

Rocky Hill, Connecticut 06067

Contact information:

Telephone: +1 (860) 571-5100

MEDICAL EMERGENCY Phone: Poison Control Center

1-877-671-4608 (toll free) or 1-303-592-1711

TRANSPORT EMERGENCY Phone: CHEMTREC

1-800-424-9300 (toll free) or 1-703-527-3887

Internet: www.henkelna.com

WARNING:

FLAMMABLE LIQUID AND VAPOR.

CAUSES SKIN IRRITATION.

CAUSES SERIOUS EYE IRRITATION.

MAY CAUSE RESPIRATORY IRRITATION.

MAY CAUSE DROWSINESS OR DIZZINESS.

FLAMMABLE LIQUID

SKIN IRRITATION

EYE IRRITATION

SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE

Prevention:

Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a well-ventilated area.

Wear protective gloves, eye protection, and face protection.

Response:

If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get

medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.

Storage:

Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

Disposal:

Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

Hazardous Component(s)

CAS Number

Percentage*

Methyl acetate

79-20-9

30 - 40

Talc

14807-96-6

20 - 30

Polyvinyl butyral - polyvinyl alcohol -

polyvinyl acetate terpolymer

27360-07-2

10 - 20

Graphite

7782-42-5

5 - 10

Quartz (SiO2)

14808-60-7

0.1 - 1

Inhalation:

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Skin contact:

Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). Wash clothing before reuse.

Thoroughly clean shoes before reuse. If skin irritation persists, call a physician.

Eye contact:

Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion:

DO NOT induce vomiting unless directed to do so by medical personnel.

Immediately give large quantities of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.

Symptoms:

See Section 11.

Extinguishing media:

Foam, dry chemical or carbon dioxide.

Special firefighting procedures:

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards:

None

Hazardous combustion products:

Oxides of carbon. Butyraldehyde. Butyric acid. Irritating organic vapours.

Environmental precautions:

Do not allow product to enter sewer or waterways.

Clean-up methods:

Remove all sources of ignition. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid

binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal.

Handling:

Use only with adequate ventilation. Prevent contact with eyes, skin and

clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed.

Storage:

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

Hazardous Component(s)

Methyl acetate

200 ppm TWA

250 ppm STEL

200 ppm (610 mg/m3) PEL

Talc

2 mg/m3 TWA Respirable fraction.

0.1 mg/m3 TWA Respirable.

0.3 mg/m3 TWA Total dust.

2.4 MPPCF TWA

Polyvinyl butyral - polyvinyl alcohol -

polyvinyl acetate terpolymer

Graphite

2 mg/m3 TWA Respirable fraction.

Quartz (SiO2)

0.025 mg/m3 TWA Respirable fraction.

2.4 MPPCF TWA

Respirable.

0.1 mg/m3 TWA Respirable.

0.05 mg/m3 PEL

Engineering controls:

Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination.

Respiratory protection:

Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists.

Eye/face protection:

Safety goggles or safety glasses with side shields. Full face protection should

be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.

Skin protection:

Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. Nitrile gloves.

Physical state:

Liquid

Color:

Gray

Odor:

Ester-like

Odor threshold:

Not available.

pH:

Not applicable

Vapor pressure:

33 mm hg

Boiling point/range:

82.2 °C (180°F)

Melting point/ range:

Not applicable

Specific gravity:

1.17

Vapor density:

2.07

Flash point:

30 °C (86°F)

Flammable/Explosive limits - lower:

2.3 %

Flammable/Explosive limits - upper:

12.7 %

Autoignition temperature:

Not available.

Flammability:

Not applicable

Evaporation rate:

7.7 (Ether = 1)

Solubility in water:

Slightly soluble

Partition coefficient (n-octanol/water):

Not available.

VOC content:

0 %; 0 g/l

Viscosity:

Not available.

Decomposition temperature:

Not available.

Stability:

Stable under recommended storage conditions.

Hazardous reactions:

Will not occur.

Hazardous decomposition products:

Oxides of carbon. Acrid smoke and fumes. Acrolein.

Incompatible materials:

Strong oxidizing agents.

Reactivity:

Not available.

Conditions to avoid:

Heat, flames, sparks and other sources of ignition. Store away from incompatible materials.

Relevant routes of exposure:

Skin, Inhalation, Eyes, Ingestion

Inhalation:

Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. May cause respiratory tract irritation. Contains crystalline silica (quartz), which is classified as a possible carcinogen. However, the crystalline silica present in this product is encapsulated in the liquid and will only be liberated if the product is sanded or abraded, and even then what is liberated will not be pure crystalline silica. Appropriate precautions, however, should be taken if the product is sanded or abraded to prevent personnel

from breathing the dust.

Skin contact:

Causes skin irritation.

Eye contact:

Causes serious eye damage. Causes eye irritation.

Ingestion:

Not expected under normal conditions of use.

Hazardous Component(s)

LD50s and LC50s

Methyl acetate

Oral LD50 (Rabbit) = 3.7 g/kg

Talc

Irritant, Lung, Some evidence of carcinogenicity

Polyvinyl butyral - polyvinyl alcohol -

polyvinyl acetate terpolymer

Graphite

Quartz (SiO2)

Hazardous Component(s)

Methyl acetate

Talc

Polyvinyl butyral - polyvinyl alcohol - polyvinyl acetate terpolymer

Graphite

Quartz (SiO2)

Known To Be Human Carcinogen.

Ecological information:

Not available.

Recommended method of disposal:

Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number:

D001: Ignitable.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name:

Resin solution

Hazard class or division:

3

Identification number:

UN 1866

Packing group:

III

International Air Transportation (ICAO/IATA)

Proper shipping name:

Resin solution

Hazard class or division:

3

Identification number:

UN 1866

Packing group:

III

Exceptions:

Consumer Commodity ORM-D, ID8000, (Not more than 500 ml)

Water Transportation (IMO/IMDG)

Proper shipping name:

RESIN SOLUTION

Hazard class or division:

3

Identification number:

UN 1866

Packing group:

III

Exceptions:

Limited quantity (Not more than 500 ml)

TSCA 8 (b) Inventory Status:

All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12 (b) Export Notification:

None above reporting de minimis

CERCLA/SARA Section 302 EHS:

None above reporting de minimis.

CERCLA/SARA Section 311/312:

Immediate Health, Delayed Health, Fire

CERCLA/SARA Section 313:

None above reporting de minimis.

CERCLA Reportable quantity:

Methyl acetate (CAS# 79-20-9) 100 lbs. (45.4 kg)

California Proposition 65:

This product contains a chemical known in the State of California to cause cancer. This

product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

CEPA DSL/NDSL Status:

All components are listed on or are exempt from listing on the Canadian Domestic Substances List.

Prepared by:

Timothy Pratt, Regulatory Affairs Specialist

Issue date:

11/28/2016