1. Identification

Product identifier

Pro-Strength Liquid-Plumr® Clog Destroyer Gel with Pipeguard™

Other means of identification

Document Number: US001283

Recommended use

Clog remover

Recommended restrictions

None known.

Manufacturer

Company name

The Clorox Company

Address

1221 Broadway

Oakland, CA 94612 United States

Telephone

1-510-271-7000

E-mail

Not available.

Emergency phone number

Medical Emergency: 1-800-446-1014

Transportation Emergency: 1-800-424-9300 (Chemtrec)

2. Hazards Identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Not classified.

Skin corrosion/irritation

Serious eye damage/eye irritation

Not classified.

Not classified.

Open

Category 2

Category 1

Signal word

Danger

Hazard statement

Causes skin irritation. Causes serious eye damage.

Precautionary statement

Prevention

Wash thoroughly after handling. Wear protective gloves and eye protection.

Response

IF ON SKIN: Wash with plenty of water. Specific treatment (see information on this label). If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Storage

Store away from incompatible materials.

Disposal

Dispose of container in accordance with local, regional, national and international regulations.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information

This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations.

3. Composition/Information on Ingredients

Mixtures

Chemical name

Common name and synonyms

CAS number

%

Sodium hydroxide

1310-73-2

1-5*

Sodium hypochlorite

7681-52-9

5-10*

4. First Aid Measures

Inhalation

If breathed in, move person into fresh air.

Skin contact

Wash immediately with water.

Eye contact

Flush immediately with water for 15 minutes. if wearing contact lenses, remove after first 5 minutes

Ingestion

IF SWALLOWED - Drink a glassful of water. DO NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain.

Indication of immediate medical attention and special treatment needed

Provide general supportive measures and treat symptomatically. Symptoms may be delayed.

General information

If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. KEEP OUT OF REACH OF CHILDREN AND PETS.

IN ALL CASES, CALL A DOCTOR OR POISON CONTROL CENTER IMMEDIATELY.

5. Fire Fighting Measures

Suitable extinguishing media

Treat for surrounding material.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

No unusual fire or explosion hazards noted.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Methods and materials for containment and cleaning up

Prevent entry into basements or confined areas.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Do not discharge into lakes, streams, ponds or public waters.

7. Handling and Storage

Precautions for safe handling

Avoid contact with eyes and skin. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash thoroughly after handling. Use good industrial hygiene practices in handling this material. When using do not eat or drink. DO NOT USE WITH PLUNGER OR IN TOILETS.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a cool, dry and well-ventilated place. KEEP OUT OF REACH OF CHILDREN AND PETS.

8. Exposure Controls/Personal Protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components

Type

Value

Sodium hydroxide (CAS

1310-73-2)

PEL

2 mg/m3

US. ACGIH Threshold Limit Values

Components

Type

Value

Sodium hydroxide (CAS 1310-73-2)

Ceiling

2 mg/m3

US. NIOSH: Pocket Guide to Chemical Hazards

Components

Type

Value

Sodium hydroxide (CAS 1310-73-2)

Ceiling

2 mg/m3

US. Workplace Environmental Exposure Level (WEEL) Guides

Components

Type

Value

Sodium hypochlorite (CAS

7681-52-9)

STEL

2 mg/m3

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Eye/face protection

Wear safety glasses with side shields.

Skin protection

Hand protection

For prolonged use, wear rubber gloves.

Other

Wear appropriate chemical resistant clothing. As required by employer code.

Respiratory protection

Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Respirator should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1910.134), CAN/CSA-Z94.4 and ANSI's standard for respiratory protection (Z88.2).

Thermal hazards

Not applicable.

General hygiene considerations

Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Wash hands before breaks and immediately after handling the product. When using do not eat or drink.

9. Physical and Chemical Properties

Appearance

Clear, Viscous

Physical state

Liquid.

Form

Not available.

Color

Pale yellow

Odor

Bleach

Odor threshold

Not available.

pH

~13

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Pour point

Not available.

Specific gravity

Not available.

Partition coefficient (n-octanol/water)

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

Not available.

Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

Not available.

Vapor density

Not available.

Relative density

~1.1

Solubility(ies)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

10. Stability and Reactivity

Reactivity

This product may react with strong oxidizing agents.

Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

Chemical stability

Material is stable under normal conditions.

Conditions to avoid

Do not mix with other chemicals. Do not use with ammonia, toilet bowl cleaners or non-Liquid-Plumr® clog removers, as splashing or the release of hazardous gases may occur.

Incompatible materials

Oxidizers. Caustics. Acids.

Not corrosive to SAE 1020 Steel or non-clad Aluminum based on test data (UN Manual of Tests and Criteria, Part III, Section 37.1 -Corrosion to metals).

Hazardous decomposition products

May include and are not limited to: Oxides of carbon.

11. Toxicological Information

Inhalation

No adverse effects due to inhalation are expected.

Excessive intentional inhalation may cause respiratory tract irritation.

Skin contact

Causes skin irritation.

Eye contact

Causes serious eye damage.

Ingestion

May cause stomach distress, nausea or vomiting.

Symptoms related to the physical, chemical and toxicological characteristics

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain.

Information on toxicological effects

Acute toxicity

See below.

Components

Species

Test Results

Sodium hydroxide (CAS 1310-73-2)

Acute

Dermal

LD50

Not available

Inhalation

LC50

Not available

Oral

LD50

Not available

Sodium hypochlorite (CAS 7681-52-9)

Acute

Dermal

LD50

Rabbit

> 20000 mg/kg, ECHA

Inhalation

LC50

Rat

> 10.5 mg/L, 1 Hours, ECHA

Oral

LD50

Rat

8910 mg/kg, ECHA

Skin corrosion/irritation

Causes skin irritation.

Exposure minutes

Not available.

Erythema value

Not available.

Oedema value

Not available.

Serious eye damage/eye

irritation

Causes serious eye damage.

Corneal opacity value

Not available.

Iris lesion value

Not available.

Conjunctival reddening value

Not available.

Conjunctival oedema value

Not available.

Recover days

Not available.

Respiratory sensitization

Not a respiratory sensitizer.

Skin sensitization

This product is not expected to cause skin sensitization.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

See below.

IARC Monographs. Overall Evaluation of Carcinogenicity

Sodium hypochlorite (CAS 7681-52-9) Volume 52 - 3

Not classifiable as to carcinogenicity to humans

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed

Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - single exposure

Not classified.

Specific target organ toxicity - repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

Chronic effects

Not available.

Further information

Not available.

12. Ecological Information

Ecotoxicity: See below

Ecotoxicological data

Components

Species

Test Results

Sodium hydroxide (CAS 1310-73-2)

Aquatic

Crustacea EC50

Water flea (Ceriodaphnia dubia)

34.59 - 47.13 mg/L, 48 hours

Fish LC50

Western mosquitofish (Gambusia affinis)

125 mg/L, 96 hours

Sodium hypochlorite (CAS 7681-52-9)

Crustacea EC50

Daphnia

2.1 mg/L, 48 Hours

Aquatic

Fish LC50

Chinook salmon (Oncorhynchus tshawytscha)

Persistence and degradability

Not available.

Bioaccumulative potential

Not available.

Mobility in soil

Not available.

Mobility in general

Not available.

Other adverse effects

Not available.

13. Disposal Considerations

Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Waste from residues / unused products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport Information

General

Not corrosive to SAE 1020 Steel or non-clad Aluminum based on test data (UN Manual of Tests and Criteria, Part III, Section 37.1 -Corrosion to metals).

Canada:

TDG Proof of Classification:

Classification Method: Classified as per Part 2, Sections 2.1 – 2.8 of the Transportation of Dangerous Goods Regulations. If applicable, the technical name and the classification of the product will appear below.

Not regulated as dangerous goods.

Marine Pollutants Exemption. 1.45.1. : Part 3, Documentation, and Part 4, Dangerous Goods Safety Marks, do not apply to substances that are classified as marine pollutants in accordance with section 2.43 of Part 2, Classification, if they are in transport solely on land by road vehicle or railway vehicle. However, substances may be identified as marine pollutants on a shipping document and the required dangerous goods safety marks may be displayed when they are in transport by road or railway vehicle. (SOR/2008-34, s. 23)

US: DOT: Not regulated per 49 CFR 171.4(c)(1)

IMDG: Not restricted per IMDG Code 2.10.2.7 Marine Pollutant exemption

IATA: Not restricted per IATA Special Provision A197

15. Regulatory Information

US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

DANGER: CAN CAUSE BURNS ON CONTACT. HARMFUL IF SWALLOWED. KEEP OUT OF REACH OF CHILDREN AND PETS.

DANGER: KEEP OUT OF REACH OF CHILDREN AND PETS. INJURES EYES, SKIN AND MUCOUS MEMBRANES ON CONTACT. HARMFUL IF SWALLOWED.

FIRST AID: EYES – Flush immediately with water for 15 minutes. If wearing contact lenses, remove after first 5 minutes. SKIN – Wash immediately with water. IF SWALLOWED – Drink a glassful of water. DO NOT induce vomiting. IN ALL CASES, CALL A DOCTOR OR POISON CONTROL CENTER IMMEDIATELY. CONTAINS: Sodium hypochlorite, sodium hydroxide and biodegradable surfactants

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Sodium hydroxide (CAS 1310-73-2)

Listed.

Sodium hypochlorite (CAS 7681-52-9)

Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

SARA 302 Extremely hazardous substance

No

SARA 311/312 Hazardous chemical

Yes

Classified hazard categories

Skin corrosion or irritation Serious eye damage or eye irritation

SARA 313 (TRI reporting)

Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act (SDWA)

Not regulated.

Food and Drug Administration (FDA)

Not regulated.

US state regulations

US - Illinois Chemical Safety Act: Listed substance

Sodium hydroxide (CAS 1310-73-2)

Sodium hypochlorite (CAS 7681-52-9)

US - Louisiana Spill Reporting: Listed substance

Sodium hydroxide (CAS 1310-73-2)

Listed.

Sodium hypochlorite (CAS 7681-52-9)

Listed.

US - Minnesota Haz Subs: Listed substance

Sodium hydroxide (CAS 1310-73-2)

SODIUM HYDROXIDE

Sodium hypochlorite (CAS 7681-52-9)

SODIUM HYPOCHLORITE

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not Listed

US. Massachusetts RTK - Substance List

Sodium hydroxide (CAS 1310-73-2)

Sodium hypochlorite (CAS 7681-52-9)

US. New Jersey Worker and Community Right-to-Know Act

Sodium hydroxide (CAS 1310-73-2)

Sodium hypochlorite (CAS 7681-52-9)

US. Pennsylvania Worker and Community Right-to-Know Law

Sodium hydroxide (CAS 1310-73-2)

Sodium hypochlorite (CAS 7681-52-9)

US. Rhode Island RTK

Sodium hydroxide (CAS 1310-73-2)

California Proposition 65

This product is not subject to warning labeling under the California Proposition 65 regulation.

Country(s) or region

Inventory name

On inventory (yes/no)*

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)

16. Other Information

LEGEND

Severe

4

Serious

3

Moderate

2

Slight

1

Minimal

0

Health

/3

Flammability

0

Physical Hazard

0

Personal Protection

X

Disclaimer

The information in the safety data sheet was written by Dell Tech Laboratories Ltd.

(http://www.delltech.com ) based on the best knowledge and experience currently available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.

Issue date

28-May-2021

Version#

01

Further information

Not available.

other information

Item: 01811PK01

Reference Item: 055500002009

Prepared by: The Clorox Company, 4900 Johnson Drive, Pleasanton, CA 94588, 925-368-6000