Common Name: TOUGH GUY CONCENTRATED GLASS CLEANER

Manufacturer: W.W. GRAINGER

SDS Revision Date: 7/5/2011

SDS Format: No Format Specified

Item Number(s): 12M176

Manufacturer Model Number(s):

SDS Table of Contents

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SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SECTION 2. HAZARDS IDENTIFICATION

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS SECTION 4. FIRST AID MEASURES

SECTION 5. FIRE FIGHTING MEASURES SECTION 6. ACCIDENTAL RELEASE MEASURES SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION SECTION 12. ECOLOGICAL INFORMATION SECTION 13. DISPOSAL CONSIDERATIONS SECTION 14. TRANSPORT INFORMATION SECTION 15. REGULATORY INFORMATION SECTION 16. OTHER INFORMATION

SAFETY DATA SHEET

GRAINGER(R*) FOR THE ONES WHO GET IT DONE MANUFACTURED FOR:

W.W. GRAINGER, INC.

100 GRAINGER PKWY.

LAKE FOREST, IL 60045-5201 1-847-535-1000 WWW.GRAINGER.COM

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: TOUGH GUY CONCENTRATED GLASS CLEANER PRODUCT USE: CONCENTRATED GLASS CLEANER

PRODUCT CODE: 12M176 DATE OF ISSUE: 07/05/11 SUPERSEDES:

EMERGENCY TELEPHONE NUMBERS:

FOR MSDS INFORMATION:

TECHNICAL SERVICES: 1-847-535-5400

FOR MEDICAL EMERGENCY: (800) 983-4582 TOLL FREE FOR TRANSPORTATION EMERGENCY:

CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED IN THE DISTRICT OF COLUMBIA: (202) 483-7616

PREPARED BY:

COMPLIANCE SERVICES

1420 SEABOARD INDUSTRIAL BLVD. ATLANTA, GA 30318

SECTION 2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:

WARNING!

COMBUSTIBLE. CAUSES EYE AND SKIN IRRITATION. HARMFUL IF SWALLOWED.

NOTE:

MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL PROTECTIVE EQUIPMENT.

ACUTE EFFECTS:

ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION.

EYES:

CAUSES EYE IRRITATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS, WATERING AND ITCHING.

SKIN:

CAUSES SKIN IRRITATION. SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING, OR REDDENING. PRODUCT MAY BE DERMAL ABSORBED.

INHALATION:

AVOID BREATHING VAPORS, SPRAY OR MISTS. OVER-EXPOSURE BY INHALATION MAY CAUSE RESPIRATORY IRRITATION. CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.

INGESTION: INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION AND DIARRHEA. CHRONIC EFFECTS:

CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: BLOOD, KIDNEYS, THE REPRODUCTIVE SYSTEM, LIVER, UPPER RESPIRATORY TRACT, SKIN, EYES, CENTRAL NERVOUS SYSTEM (CNS).

CARCINOGENICITY:

INGREDIENTS: NOT LISTED AS CARCINOGEN BY OSHA, NTP OR IARC. PRODUCT/INGREDIENT NAME: NOT AVAILABLE.

ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)

*HAZARD DETERMINATION SYSTEM (HDS): HEALTH 1

FLAMMABILITY 2

REACTIVITY 0

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

AQUA AMMONIA 26 BE; AMMONIUM HYDROXIDE; 1336-21-6 <3 AMMONIA, AQUEOUS SOLUTION

SECTION 4. FIRST AID MEASURES

EYE CONTACT:

IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET MEDICAL ATTENTION IMMEDIATELY.

SKIN CONTACT:

FLUSH AFFECTED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.

INHALATION:

MOVE EXPOSED PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.

INGESTION:

DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY.

SECTION 5. FIRE FIGHTING MEASURES

FLASH POINT:

CLOSED CUP: 44.44 DEG. C (112 DEG. F) FLAMMABLE LIMITS: NOT AVAILABLE. FLAMMABILITY: COMBUSTIBLE.

FIRE HAZARD:

COMBUSTIBLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.

FIRE-FIGHTING PROCEDURES: USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM. NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):

1

2

0

SECTION 6. ACCIDENTAL RELEASE MEASURES

SPILL CLEAN UP:

ELIMINATE ALL IGNITION SOURCES. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH WATER AND MOP UP IF WATER-SOLUBLE OR ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER.

SECTION 7. HANDLING AND STORAGE

HANDLING:

PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. DO NOT REUSE CONTAINER. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE.

STORAGE:

STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.

STORE BETWEEN THE FOLLOWING TEMPERATURES:

40 DEG. F - 120 DEG. F (4.4 DEG. C - 49 DEG. C). KEEP OUT OF THE REACH OF CHILDREN.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

PRODUCT NAME EXPOSURE LIMITS

ETHANOL; ETHYL ALCOHOL; GRAIN NIOSH REL (UNITED STATES, 6/2009). ALCOHOL TWA: 1000 PPM 10 HOUR(S).

TWA: 1900 MG/M3 10 HOUR(S).

OSHA PEL (UNITED STATES, 11/2006). TWA: 1000 PPM 8 HOUR(S).

TWA: 1900 MG/M3 8 HOUR(S).

ACGIH TLV (UNITED STATES, 1/2009). STEL: 1000 PPM 15 MINUTE(S).

OSHA PEL 1989 (UNITED STATES, 3/1989). TWA: 1000 PPM 8 HOUR(S).

TWA: 1900 MG/M3 8 HOUR(S).

AQUA AMMONIA 26 BE; AMMONIUM ACGIH TLV (UNITED STATES). HYDROXIDE; AMMONIA, AQUEOUS TWA: 25 PPM 8 HOUR(S).

SOLUTION

PERSONAL PROTECTIVE EQUIPMENT (PPE): SAFETY GLASSES

GLOVES

EYES: SAFETY GLASSES.

ACGIH TLV / OSHA PEL (UNITED STATES). STEL: 35 PPM 15 MINUTE(S).

BODY: RECOMMENDED: NEOPRENE GLOVES. RUBBER GLOVES. NITRILE GLOVES.

RESPIRATORY:

USE WITH ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS BELOW THEIR RESPECTIVE OCCUPATIONAL EXPOSURE LIMITS.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: LIQUID. pH: 10.5 TO 11.5

BOILING POINT: 104.44 DEG. C (220 DEG. F) SPECIFIC GRAVITY: 0.99

SOLUBILITY:

EASILY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER. COLOR: CLEAR. BLUE.

ODOR: AMMONIACAL.

VAPOR PRESSURE: NOT DETERMINED. VAPOR DENSITY: NOT DETERMINED. EVAPORATION RATE: 1 (WATER = 1)

VOC (CONSUMER): 10%

SECTION 10. STABILITY AND REACTIVITY

STABILITY AND REACTIVITY: THE PRODUCT IS STABLE. INCOMPATIBILITY:

KEEP AWAY FROM HEAT, SPARKS AND FLAME. REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:

OXIDIZING MATERIALS.

HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.

HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES (CO, CO2)

SECTION 11. TOXICOLOGICAL INFORMATION

VAPOR

LC50 INHALATION GUINEA PIG >633 PPM 1 HOURS VAPOR

LC50 INHALATION RAT 450 PPM 4 HOURS GAS.

SECTION 12. ECOLOGICAL INFORMATION

ENVIRONMENTAL EFFECTS: NOT AVAILABLE. AQUATIC ECOTOXICITY:

PRODUCT/INGREDIENT TEST RESULT SPECIES EXPOSURE NAME

ETHANOL ACUTE EC50 >100 PPM DAPHNIA - WATER 48 HOURS FRESH WATER FLEA - DAPHNIA

MAGNA - <24 HOURS

(MICRO)G/L MARINE BRINE SHRIMP - WATER ARTEMIA

FRANCHISCANA - LARVAE

CHRONIC NOEC DAPHNIA - WATER 48 HOURS

<6.3 G/L FLEA - DAPHNIA

FRESH WATER MAGNA

SECTION 13. DISPOSAL CONSIDERATIONS

WASTE INFORMATION:

WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES FOR ADDITIONAL INFORMATION.

WASTE STREAM:

CODE: D001

CLASSIFICATION: (HAZARDOUS WASTE) ORIGIN: (RCRA WASTE.)

SECTION 14. TRANSPORT INFORMATION

REGULATORY UN NUMBER PROPER SHIPPING NAME CLASSES PG* LABEL INFORMATION

DOT NOT REGULATED. NOT A DOT CONTROLLED CLASSIFICATION MATERIAL

(UNITED STATES).

NOTE:

DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING WITH YOUR SHIPMENT.

PG*: PACKING GROUP

SECTION 15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS:

SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:

PRODUCT NAME: AQUA AMMONIA

CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND. CLEAN WATER ACT (CWA) 311: AQUA AMMONIA

CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES: NO PRODUCTS WERE FOUND.

ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA INVENTORY.

UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED. STATE REGULATIONS:

CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.

SECTION 16. OTHER INFORMATION

TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE. HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.

FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

*NOTE:

HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE MEANINGS OF THIS SCALE.