SAFETY DATA SHEET
Issuing Date 27-May-2016 Revision Date 11-Dec-20 Revision Number 2
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING | |
Product identifier | |
Product Name | Clorox® Clean-Up® Cleaner + Bleach1 |
Other means of identification | |
Synonyms | None |
EPA Pesticide registration number | 5813-21 |
Document number | US001273 |
Recommended use of the chemical and restrictions on use | |
Recommended Use | Disinfectant - Non-Aerosol |
Uses advised against | No information available |
Details of the supplier of the safety data sheet | |
Supplier Name | The Clorox Company |
Supplier Address | 1221 Broadway Oakland CA 94612 US |
Supplier Phone Number | 1-510-271-7000 |
Emergency telephone number | For Medical Emergencies Call: 1-800-446-1014 For Transportation Emergencies, Call Chemtrec: 1-800-424-9300 |
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Category 2A
Serious eye damage/eye irritation
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Hazard Statements Causes serious eye irritati | Warning on |
Appearance Clear, pale yellow
Physical state Liquid
Odor Fragranced
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection
Precautionary Statements - Response Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
Skin
If skin irritation occurs: Get medical advice/attention
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
0.12 % of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life with long lasting effects
Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name | CAS-No | Percent | Trade Secret |
Sodium hypochlorite | 7681-52-9 | 1-5 | * |
Sodium hydroxide | 1310-73-2 | 0.1-1 | * |
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing.
Skin contact Take off contaminated clothing and wash before reuse. Wash off immediately with plenty of
water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation | Move victim to fresh air. If symptoms persist, call a physician. |
Ingestion | Call a physician or Poison Control Center immediately. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. |
Self-protection of the first aider | Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8). |
Most important symptoms and effects, both acute and delayed | |
Most Important Symptoms and Effects | May cause redness and tearing of the eyes. |
Indication of any immediate medical attention and special treatment needed | |
Notes to Physician | Treat symptomatically. |
5. FIRE-FIGHTING MEASURES | |
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. | |
Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. | |
Specific hazards arising from the chemical No information available. | |
Hazardous Combustion Products Carbon oxides. | |
Explosion Data | |
Sensitivity to Mechanical Impact | No. |
Sensitivity to Static Discharge | No. |
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. | |
6. ACCIDENTAL RELEASE MEASURES | |
Personal precautions, protective equipment and emergency procedures | |
Personal precautions | Use personal protective equipment as required. Avoid contact with skin and eyes. |
Other Information | Refer to protective measures listed in Sections 7 and 8. |
Environmental precautions | |
Environmental precautions | See Section 12 for additional Ecological Information. |
Methods and material for containment and cleaning up | |
Methods for containment | Prevent further leakage or spillage if safe to do so. |
Methods for cleaning up | Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. After cleaning, flush away traces with water. Prevent product from entering drains. Dam up. |
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep container tightly closed. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers.
Incompatible Products Ammonia. Acids.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name | ACGIH TLV | OSHA PEL | NIOSH IDLH |
Sodium hydroxide 1310-73-2 | Ceiling: 2 mg/m3 | TWA: 2 mg/m3 | IDLH: 10 mg/m3Ceiling: 2 mg/m3 |
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992)
Appropriate engineering controls
Engineering Measures Showers Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). If splashes are likely to occur:. None
required for consumer use.
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Hygiene Measures Take off contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing. When using do not eat, drink or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties | |||
Physical state Appearance | Liquid Clear, pale yellow | Odor | Fragranced |
Color | No information available | Odor Threshold | No information available |
Property | Values | Remarks Method | |
pH Melting / freezing point Boiling point / boiling range | 12.4-12.8 No data available No data available | None known None known None known | |
Flash Point | 5001 C / 9034 | F | None known |
Evaporation Rate | No data available | None known | |
Flammability (solid, gas) | No data available | None known | |
Flammability Limit in Air | |||
Upper flammability limit | No data available | ||
Lower flammability limit | No data available | ||
Vapor pressure | No data available | None known | |
Vapor density | No data available | None known | |
Specific Gravity | 1.03 | None known | |
Water Solubility | Soluble in water | None known | |
Solubility in other solvents | No data available | None known | |
Partition coefficient: n-octanol/waterNo data available | None known | ||
Autoignition temperature | No data available | None known | |
Decomposition temperature | No data available | None known | |
Kinematic viscosity | No data available | None known | |
Dynamic viscosity | No data available | None known | |
Explosive properties | No data available | ||
Oxidizing properties | No data available | ||
Other Information | |||
Softening Point | No data available | ||
Particle Size | No data available | ||
Particle Size Distribution | |||
10. STABILITY AND REACTIVITY | |||
Reactivity | |||
No data available. | |||
Chemical stability Stable under recommended storage conditions. | |||
Possibility of Hazardous Reactions None under normal processing. | |||
Hazardous Polymerization Hazardous polymerization does not occur. | |||
Conditions to avoid None known. | |||
Incompatible materials Ammonia. Acids. | |||
Hazardous Decomposition Products Carbon oxides. | |||
11. TOXICOLOGICAL INFORMATION | |||
Information on likely routes of exposure | |||
Product Information | . | ||
Inhalation | May cause irritation of respiratory tract. | ||
Eye contact | Irritating to eyes. | ||
Skin contact | Prolonged contact may cause redness and irritation. | ||
Ingestion | Specific test data for the substance or mixture is not available. | ||
Component Information
_
_
1350 mg/kg (Rabbit)
_
Sodium hydroxide 1310-73-2
>10000 mg/kg (Rabbit)
8200 mg/kg (Rat)
Sodium hypochlorite 7681-52-9
Inhalation LC50
Dermal LD50
Oral LD50
Chemical Name
Information on toxicological effects
Symptoms May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name | ACGIH | IARC | NTP | OSHA |
Sodium hypochlorite 7681-52-9 | - | Group 3 | - | - |
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity Carcinogenic potential is unknown.
Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI).
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Not applicable
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Persistence and Degradability
No information available.
Bioaccumulation
No information available
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS | ||
Waste treatment methods | ||
Disposal methods | Dispose of in accordance with federal, state and local regulations. | |
Contaminated Packaging | Dispose of contents/containers in accordance with local regulations. | |
US EPA Waste Number | D002 | |
California Hazardous Waste Codes | 122 | |
This product contains one or more substances that are listed with the State of California as a hazardous waste. | ||
14. TRANSPORT INFORMATION | ||
For shipments less than 5 liters: DOT - Not Regulated per 49 CFR 171.4(c)(1) IMDG - Not Restricted per IMDG Code 2.10.2.7 Marine Pollutant exemption IATA - Not Restricted per IATA Special Provision A197 Environmentally Hazardous Substance exemption For shipments 5 liters or more: DOT - Not Regulated per 49 CFR 171.4(c)(1) IMDG - UN 3082 Environmentally Hazardous Substance, Liquid, N.O.S. (Sodium Hypochlorite), 9, III, Marine Pollutant IATA - UN 3082 Environmentally Hazardous Substance, Liquid, N.O.S. (Sodium Hypochlorite), 9, III, Marine Pollutant | ||
15. REGULATORY INFORMATION | ||
International Inventories | ||
TSCA | All components are listed on the TSCA Inventory | |
DSL | All components are listed either on the DSL or NDSL. | |
IECSC | - | |
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory | ||
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List | ||
US Federal Regulations | ||
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 | ||
SARA 311/312 Hazard Categories | ||
Acute Health Hazard | Yes | |
Chronic Health Hazard | No | |
Fire Hazard | No | |
Sudden release of pressure hazard | No | |
Reactive Hazard | No | |
CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and | ||
40 CFR 122.42)
X
1000 lb
Sodium hydroxide 1310-73-2
X
100 lb
Sodium hypochlorite 7681-52-9
CWA - Hazardous Substances
CWA - Priority Pollutants
CWA - Toxic Pollutants
CWA - Reportable Quantities
Chemical Name
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
RQ 1000 lb final RQRQ 454 kg final RQ
-
1000 lb
Sodium hydroxide 1310-73-2
RQ 100 lb final RQRQ 45.4 kg final RQ
-
100 lb
Sodium hypochlorite 7681-52-9
RQ
Extremely Hazardous Substances RQs
Hazardous Substances RQs
Chemical Name
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name | New Jersey | Massachusetts | Pennsylvania | Rhode Island | Illinois |
Sodium hypochlorite 7681-52-9 | X | X | X | X | |
Sodium hydroxide 1310-73-2 | X | X | X | X |
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
EPA Pesticide label
WARNING: EYE AND SKIN IRRITANT. Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Avoid contact with skin. Wear protective eyewear. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. Harmful if swallowed. For sensitive skin or prolonged use, wear gloves. Vapors may irritate. Avoid prolonged breathing of vapors. Use only in well ventilated areas. Not recommended for use by persons with heart conditions or chronic respiratory problems such as asthma, emphysema or obstructive lung disease.
16. OTHER INFORMATION
Prepared By Product Stewardship
23 British American Blvd. Latham, NY 12110
1-800-572-6501
Issuing Date 27-May-2016
Revision Date | 11-Dec-20 |
Revision Note | No information available |
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text | |
End of Safety Data Sheet | |