Section 1. Identification

Product name

Product code

Other means of identification

Product type

Relevant identified uses of the substance or mixture and uses advised against

Manufacturer

Emergency telephone number of the company

SP™3105 Carton Stencil Ink Aerosol White

S03105

Not available.

Aerosol.

Not applicable.

Sprayon Products, Cleveland, OH 44115

(216) 566-2917

Product Information Telephone Number

(800)247-3266

Regulatory Information Telephone Number

(216)566-2902

Transportation Emergency Telephone Number

(800)424-9300

Section 2. Hazards identification

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

FLAMMABLE AEROSOLS - Category 1

GASES UNDER PRESSURE - Compressed gas

SKIN CORROSION/IRRITATION - Category 2

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 33.6%

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

Causes serious eye irritation.

Causes skin irritation.

Suspected of causing cancer.

May be fatal if swallowed and enters airways.

May cause respiratory irritation.

May cause drowsiness and dizziness.

May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED

EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Hazards not otherwise classified

None known.

Section 3. Composition/information on ingredients

Substance/mixture

Mixture

Other means of identification

Not available.

CAS number/other identifiers

Ingredient name

% by weight

CAS number

Acetone

41.3

67-64-1

Propane

12.8

74-98-6

Butane

12.3

106-97-8

p-Chlorobenzotrifluoride

11.5

98-56-6

Titanium Dioxide

5.8

13463-67-7

Lt. Aliphatic Hydrocarbon Solvent

5.3

64742-89-8

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

Causes skin irritation.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Adverse symptoms may include the following: irritation, redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

No specific treatment.

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Extinguishing media

Suitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media

None known.

Specific hazards arising from the chemical

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Hazardous thermal decomposition products

Decomposition products may include the following materials: carbon dioxide, carbon monoxide, halogenated compounds, carbonyl halides, metal oxide/oxides

Special protective actions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

Control parameters

Occupational exposure limits

Ingredient name

Exposure limits

Acetone

ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours

Propane

NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.

Butane

NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes

Titanium Dioxide

ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust

Appropriate engineering controls

Environmental exposure controls

Hygiene measures

Eye/face protection

Skin protection

Hand protection

Body protection

:

:

:

:

Other skin protection

:

Section 9. Physical and chemical properties

Appearance

Physical state

Color

Odor

Odor threshold pH

Melting point

Boiling point

Flash point

Evaporation rate

Flammability (solid, gas)

Lower and upper explosive

(flammable) limits

Vapor pressure

Vapor density

Relative density

Solubility

Partition coefficient: noctanol/water

Auto-ignition temperature

Decomposition temperature

Viscosity

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Liquid.

Not available.

Not available.

Not available.

7

Not available.

Not available.

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] 5.6 (butyl acetate = 1) Not available.

Lower: 0.9%

Upper: 12.8%

13.5 kPa (101.325 mm Hg) [at 20°C]

1.55 [Air = 1]

0.79

Not available.

Not available.

Not available.

Not available.

Kinematic (room temperature): <0.07 cm²/s (<7 cSt)

Kinematic (40°C (104°F)): <0.07 cm²/s (<7 cSt)

Aerosol product

Type of aerosol

Heat of combustion

: :

Spray

0.00002993 kJ/g

Section 10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

:

:

:

:

:

:

No specific test data related to reactivity available for this product or its ingredients.

The product is stable.

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid all possible sources of ignition (spark or flame).

No specific data.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Date of issue/Date of revision

: 4/8/2015. Date of previous issue : 4/7/2015. Version : 1.03 7/13

Product/ingredient name

Result

Species

Dose

Exposure

Acetone

LD50 Oral

Rat

5800 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

p-Chlorobenzotrifluoride

LD50 Oral

Rat

13 g/kg

-

Product/ingredient name

Result

Species

Score

Exposure

Observation

Acetone

Eyes - Mild irritant

Human

-

186300 parts per million

-

Eyes - Mild irritant

Rabbit

-

10 microliters

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20 milligrams

-

Eyes - Severe irritant

Rabbit

-

20 milligrams

-

Skin - Mild irritant

Rabbit

-

24 hours 500 milligrams

-

Skin - Mild irritant

Rabbit

-

395 milligrams

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300

Micrograms

Intermittent

-

Product/ingredient name

OSHA

IARC

NTP

Titanium Dioxide

-

2B

-

Name

Category

Route of exposure

Target organs

Acetone

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

p-Chlorobenzotrifluoride

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Name

Category

Route of exposure

Target organs

Acetone

Propane Butane

p-Chlorobenzotrifluoride

Lt. Aliphatic Hydrocarbon Solvent

Category 2

Category 2

Category 2

Category 2

Category 2

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Eye contact

: Causes serious eye irritation.

Inhalation

: Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

: Causes skin irritation.

Ingestion

: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Eye contact

: Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Skin contact

Ingestion

: Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue

dizziness/vertigo unconsciousness

: Adverse symptoms may include the following: irritation redness

: Adverse symptoms may include the following:

nausea or vomiting

General

: May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity

: Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

: No known significant effects or critical hazards.

Teratogenicity

: No known significant effects or critical hazards.

Developmental effects

: No known significant effects or critical hazards.

Fertility effects

: No known significant effects or critical hazards.

Product/ingredient name

Result

Species

Exposure

Acetone

Acute EC50 20.565 mg/l Marine water

Algae - Ulva pertusa

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 10000 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

-

-

Readily

Product/ingredient name

LogP_ow

BCF

Potential

Titanium Dioxide

-

352

low

Lt. Aliphatic Hydrocarbon Solvent

-

10 to 2500

high

Health

*

2

Flammability

3

Physical hazards

0