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Section 11. Toxicological information | |||||
Information on toxicological effects | |||||
Acute toxicity | |||||
Product/ingredient name | Result | Species | Dose | Exposure | |
Acetone | LD50 Oral | Rat | 5800 mg/kg | - | |
Butane | LC50 Inhalation Vapor | Rat | 658000 mg/m³ | 4 hours | |
p-Chlorobenzotrifluoride | LD50 Oral | Rat | 13 g/kg | - | |
Irritation/Corrosion | |||||
Product/ingredient name | Result | Species | Score | Exposure | Observation |
Acetone | Eyes - Mild irritant | Human | - | 186300 parts per million | - |
Eyes - Mild irritant | Rabbit | - | 10 microliters | - | |
Eyes - Moderate irritant | Rabbit | - | 24 hours 20 milligrams | - | |
Eyes - Severe irritant | Rabbit | - | 20 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 24 hours 500 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 395 milligrams | - | |
Titanium Dioxide | Skin - Mild irritant | Human | - | 72 hours 300 Micrograms Intermittent | - |
Sensitization | Not available. | ||||
Mutagenicity | Not available. | ||||
Carcinogenicity | Not available. | ||||
Product/ingredient name | OSHA | IARC | NTP | ||
Titanium Dioxide | - | 2B | - | ||
Reproductive toxicity | Not available. | ||||
Teratogenicity | Not available. | ||||
Specific target organ toxicity (single exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Propane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Butane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
p-Chlorobenzotrifluoride | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Lt. Aliphatic Hydrocarbon Solvent | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Specific target organ toxicity (repeated exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone | Category 2 | Not determined | Not determined | ||
Propane Butane | Category 2 | Not determined | Not determined | ||
p-Chlorobenzotrifluoride | Category 2 | Not determined | Not determined | ||
Lt. Aliphatic Hydrocarbon Solvent | Category 2 | Not determined | Not determined | ||
Aspiration hazard | |||||
Name | Result | ||||
Propane | ASPIRATION HAZARD - Category 1 | ||||
Butane | ASPIRATION HAZARD - Category 1 | ||||
Lt. Aliphatic Hydrocarbon Solvent | ASPIRATION HAZARD - Category 1 | ||||
Information on the likely | |||||
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routes of exposure | Not available. | ||||
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Potential acute health effects | |||||
Eye contact | |||||
Causes serious eye irritation. | |||
Inhalation | |||
Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. | |||
Skin contact | |||
Causes skin irritation. | |||
Ingestion | |||
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. | |||||
Symptoms related to the physical, chemical and toxicological characteristics | |||||
Eye contact | |||||
Adverse symptoms may include the following: pain or irritation watering redness | |||
Inhalation | |||
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue |
dizziness/vertigo unconsciousness |
Skin contact | Adverse symptoms may include the following: irritation redness | ||||
Ingestion | Adverse symptoms may include the following: | ||||
nausea or vomiting | |||||
Delayed and immediate effects and also chronic effects from short and long term exposure | |||||
Short term exposure | |||||
Potential immediate | |||||
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effects | Not available. | ||||
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Potential delayed effects | |||
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Not available. | |||||
Long term exposure | |||||
Potential immediate | |||||
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effects | Not available. | ||||
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Potential delayed effects | |||
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Not available. | |||||
Potential chronic health effects | Not available. | ||||
General | |||||
May cause damage to organs through prolonged or repeated exposure. | |||
Carcinogenicity | |||
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. | |||
Mutagenicity | |||
No known significant effects or critical hazards. | |||
Teratogenicity | |||
No known significant effects or critical hazards. | |||
Developmental effects | |||
No known significant effects or critical hazards. | |||
Fertility effects | |||
No known significant effects or critical hazards. | |||||
Numerical measures of toxicity Acute toxicity estimates | Not available. | ||||
Section 12. Ecological information | |||
Toxicity | |||
Product/ingredient name | Result | Species | Exposure |
Acetone | Acute EC50 20.565 mg/l Marine water | Algae - Ulva pertusa | 96 hours |
Acute LC50 6000000 µg/l Fresh water | Crustaceans - Gammarus pulex | 48 hours | |
Acute LC50 10000 µg/l Fresh water | Daphnia - Daphnia magna | 48 hours | |
Acute LC50 5600 ppm Fresh water | Fish - Poecilia reticulata | 96 hours | |
Chronic NOEC 4.95 mg/l Marine water | Algae - Ulva pertusa | 96 hours | |
Chronic NOEC 0.016 ml/L Fresh water | Crustaceans - Daphniidae | 21 days | |
Chronic NOEC 0.1 ml/L Fresh water | Daphnia - Daphnia magna Neonate | 21 days | |
Chronic NOEC 5 µg/l Marine water | Fish - Gasterosteus aculeatus Larvae | 42 days | |
Titanium Dioxide | Acute LC50 >1000000 µg/l Marine water | Fish - Fundulus heteroclitus | 96 hours |
Lt. Aliphatic Hydrocarbon Solvent | Acute LC50 >100000 ppm Fresh water | Fish - Oncorhynchus mykiss | 96 hours |
Persistence and degradability | |||
Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability |
Acetone | - | - | Readily |
Bioaccumulative potential | |||
Product/ingredient name | LogPow | BCF | Potential |
Titanium Dioxide | - | 352 | low |
Lt. Aliphatic Hydrocarbon Solvent | - | 10 to 2500 | high |
Mobility in soil | |||
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Soil/water partition | |||
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coefficient (KOC) | Not available. | ||
Other adverse effects |
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No known significant effects or critical hazards. |
Section 13. Disposal considerations | |
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Disposal methods | |
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The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. |
Section 14. Transport information | |
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Special precautions for user | |
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73/78 and the IBC Code
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Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. |
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Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code | Not available. |
Section 15. Regulatory information | |
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U.S. Federal regulations | |
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State regulations | |
California Prop. 65 | WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. |
Section 16. Other information | ||
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Hazardous Material Information System (U.S.A.) | ||
Health | * | 2 |
Flammability | 3 | |
Physical hazards | 0 | |
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. | ||
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision : 4/8/2015. Date of previous issue : 4/7/2015. Version : 1.03 13/13