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Manufacturer: W.W. GRAINGER
SDS Revision Date: 7/5/2011
SDS Format: No Format Specified
Item Number(s): 12M176
Manufacturer Model Number(s):
SDS Table of Contents
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SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SECTION 2. HAZARDS IDENTIFICATION
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS SECTION 4. FIRST AID MEASURES
SECTION 5. FIRE FIGHTING MEASURES SECTION 6. ACCIDENTAL RELEASE MEASURES SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION SECTION 12. ECOLOGICAL INFORMATION SECTION 13. DISPOSAL CONSIDERATIONS SECTION 14. TRANSPORT INFORMATION SECTION 15. REGULATORY INFORMATION SECTION 16. OTHER INFORMATION
SAFETY DATA SHEET
GRAINGER(R*) FOR THE ONES WHO GET IT DONE
MANUFACTURED FOR:
W.W. GRAINGER, INC.
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LAKE FOREST, IL 60045-5201
1-847-535-1000
SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: TOUGH GUY CONCENTRATED GLASS CLEANER
PRODUCT USE: CONCENTRATED GLASS CLEANER
PRODUCT CODE: 12M176
DATE OF ISSUE: 07/05/11
SUPERSEDES:
EMERGENCY TELEPHONE NUMBERS:
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TECHNICAL SERVICES: 1-847-535-5400
FOR MEDICAL EMERGENCY:
(800) 983-4582 TOLL FREE
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
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INGESTION: INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION AND DIARRHEA.
CHRONIC EFFECTS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: BLOOD, KIDNEYS, THE REPRODUCTIVE SYSTEM, LIVER, UPPER RESPIRATORY TRACT, SKIN, EYES, CENTRAL NERVOUS SYSTEM (CNS).
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INGREDIENTS: NOT LISTED AS CARCINOGEN BY OSHA, NTP OR IARC.
PRODUCT/INGREDIENT NAME: NOT AVAILABLE.
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*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 1
FLAMMABILITY 2
REACTIVITY 0
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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
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NAME OF HAZARDOUS INGREDIENTS | CAS NUMBER | % BY WEIGHT | |||
ETHANOL; ETHYL ALCOHOL; GRAIN ALCOHOLCAS NUMBER | 64-17-5 | % 5 BY WEIGHT - 15 | |||
DETERGENT SURFACTANT BLEND | 65143-89-7 | 1 | - 5 | 70191-76-3 | 1 - 5 |
AQUA AMMONIA 26 BE; AMMONIUM HYDROXIDE; AMMONIA, AQUEOUS SOLUTION | 1336-21-6 |
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< 3 |
SECTION 4. FIRST AID MEASURES
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SECTION 5. FIRE FIGHTING MEASURES
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FLASH POINT:
CLOSED CUP: 44.44 DEG. C (112 DEG. F) FLAMMABLE LIMITS: NOT AVAILABLE. FLAMMABILITY: COMBUSTIBLE.
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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PRODUCT NAME | EXPOSURE LIMITS |
ETHANOL; ETHYL ALCOHOL; GRAIN ALCOHOL | NIOSH REL (UNITED STATES, 6/2009). |
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TWA: 1000 PPM 10 HOUR(S). TWA: 1900 MG/M3 10 HOUR(S). OSHA PEL (UNITED STATES, 11/2006). TWA: 1000 PPM 8 HOUR(S). TWA: 1900 MG/M3 8 HOUR(S). ACGIH TLV (UNITED STATES, 1/2009). STEL: 1000 PPM 15 MINUTE(S). OSHA PEL 1989 (UNITED STATES, 3/1989). TWA: 1000 PPM 8 HOUR(S). TWA: 1900 MG/M3 8 HOUR(S). | |
AQUA AMMONIA 26 BE; AMMONIUM HYDROXIDE; AMMONIA, AQUEOUS SOLUTION | ACGIH TLV (UNITED STATES). |
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TWA: 25 PPM 8 HOUR(S |
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SOLUTION
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) |
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GLOVES
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. ACGIH TLV / OSHA PEL (UNITED STATES). STEL: 35 PPM 15 MINUTE(S). |
PERSONAL PROTECTIVE EQUIPMENT (PPE):
SAFETY GLASSES
GLOVES
EYES: SAFETY GLASSES.
BODY: RECOMMENDED: NEOPRENE GLOVES. RUBBER GLOVES. NITRILE GLOVES.
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL STATE: LIQUID.
pH: 10.5 TO 11.5
BOILING POINT: 104.44 DEG. C (220 DEG. F)
SPECIFIC GRAVITY: 0.99
SOLUBILITY:
EASILY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
COLOR: CLEAR. BLUE.
ODOR: AMMONIACAL.
VAPOR PRESSURE: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: 1 (WATER = 1)
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STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
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SECTION 11. TOXICOLOGICAL INFORMATION
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ACUTE TOXICITY: | ||||
PRODUCT/INGREDIENT NAME | RESULT | SPECIES | DOSE | EXPOSURE |
ETHYLENE GLYCOL MONOBUTYL ETHER | LD50 DERMAL LD50 DERMAL LD50 INTRAPERITONEAL LD50 INTRAVENOUS LD50 ORAL LD50 ORAL LD50 ORAL LD50 UNREPORTED LDLO ORAL TDLO ORAL TDLO UNREPORTED LC50 INHALATION VAPOR LC50 INHALATION VAPOR LC50 INHALATION GAS | GUINEA PIG RABBIT RAT RAT GUINEA PIG RAT RAT RAT RAT RAT RAT RAT GUINEA PIGPIG RAT | >2000 MG/KG 220 MG/KG 220 MG/KG 307 MG/KG 1200 MG/KG 917 MG/KG 250 MG/KG 917 MG/KG 1500 MG/KG 500 MG/KG 250 MG/KG 2900 MG/M3 >633 PPM 450 PPM | 7 HOURS |
VAPOR
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1 HOURS |
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4 HOURS |
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DETERGENT SURFACTANT BLEND | LD50 DERMAL | RAT | >2000 MG/KG | |
AQUA AMMONIA | LD50 ORAL LC50 INHALATION VAPOR | RAT MOUSE | 350 MG/KG |
LC50 INHALATION
VAPOR
2500 PPM | 1 HOURS |
SECTION 12. ECOLOGICAL INFORMATION
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ENVIRONMENTAL EFFECTS: NOT AVAILABLE.
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT NAME | TEST RESULT | SPECIES | EXPOSURE |
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ETHANOL | ACUTE EC50 >100 PPM FRESH WATER | DAPHNIA - WATER |
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FLEA - DAPHNIA MAGNA - <24 HOURS | 48 HOURS | ||||||
ACUTE EC50 2000 (MICRO)G/L FRESH WATER2000 FRESH | DAPHNIA - WATER FLEA - DAPHNIA MAGNA | 48 HOURS | |||||
ACUTE LC50 5680 MG/L FRESH 5680 WATER | DAPHNIA - WATER FLEA - DAPHNIA MAGNA - NEONATE - <24 HOURS | 48 HOURS | |||||
ACUTE LC50 FRESH WATER 13 MLM/L FRESH WATER | FISH - RAINBOW TROUT, DONALDSON TROUT - ONCORHYNCHUS MYKISS - 0.8 G | 96 HOURS | |||||
ACUTE LC50 13480000 (MICRO)G/L FRESH WATER 13480000 FRESH | FISH - FATHEAD MINNOW - PIMEPHALES PROMELAS - JUVENILE (FLEDGLING, HATCHLING, WEANLING) - 4 TO 8 WEEKS - 1.1 TO 3.1 CM | 96 HOURS | |||||
ACUTE LC50 10000000 | FISH - BLEAK - | 96 | HOURS | TO 11500000 (MICRO)G/L MARINE WATER | FISH - BLEAK - ALBURNUS ALBURNUS - 8 CM | 96 HOURS | |
ACUTE LC50 5577000 (MICRO)G/L FRESH WATER | DAPHNIA - WATER FLEA - CERIODAPHNIA DUBIA - NEONATE | 48 HOURS | |||||
ACUTE LC50 3715000 (MICRO)G/L FRESH WATER | DAPHNIA - WATER FLEA - CERIODAPHNIA DUBIA - NEONATE | 48 HOURS | |||||
ACUTE LC50 42000 (MICRO)G/L FRESH WATER 42000 FRESH | FISH - RAINBOW TROUT, DONALDSON TROUT - ONCORHYNCHUS MYKISS | 4 DAYS | |||||
ACUTE LC50 25500 | CRUSTACEANS - | 48 HOURS | (MICRO)G/L MARINE WATER | CRUSTACEANS - BRINE SHRIMP - | |||
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ARTEMIA |
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FRANCHISCANA - LARVAE |
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48 HOURS | ||
CHRONIC NOEC <6.3 G/L FRESH WATER | DAPHNIA - WATER FLEA - DAPHNIA |
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MAGNA | 48 HOURS |
SECTION 13. DISPOSAL CONSIDERATIONS
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CLASSIFICATION: (HAZARDOUS WASTE)
ORIGIN: (RCRA WASTE.)
SECTION 14. TRANSPORT INFORMATION
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REGULATORY INFORMATION UN NUMBER PROPER SHIPPING NAME CLASSES PG* LABEL INFORMATION
DOT CLASSIFICATION NOT REGULATED. NOT A DOT CONTROLLED CLASSIFICATION MATERIAL (UNITED STATES).
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING WITH YOUR SHIPMENT.
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CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: AQUA AMMONIA
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UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
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