Control parameters

Occupational exposure limits

Ingredient name

Exposure limits

Acetone

ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours

Propane

NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.

Butane

NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes

Titanium Dioxide

ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance

Physical state

Color

Odor

Odor threshold pH

Melting point

Boiling point

Flash point

Evaporation rate

Flammability (solid, gas)

Lower and upper explosive

(flammable) limits

Vapor pressure

Vapor density

Relative density

Solubility

Partition coefficient: noctanol/water

Auto-ignition temperature

Decomposition temperature

Viscosity

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

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:

:

:

Liquid.

Color

Not available.

Odor

Not available.

Odor threshold

Not available.

pH

7

Melting point

Not available.

Boiling point

Not available.

Flash point

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Evaporation rate

5.6 (butyl acetate = 1) Not available.1)

Flammability (solid, gas)

Not available.

Lower and upper explosive (flammable) limits

Lower: 0.9%

Upper: 12.8%

Vapor pressure

13.5 kPa (101.325 mm Hg) [at 20°C]

Vapor density

1.55 [Air = 1]

Relative density

0.79

Solubility

Not available.

Partition coefficient: noctanol/water

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Kinematic (room temperature): <0.07 cm²/s (<7 cSt)

Kinematic (40°C (104°F)): <0.07 cm²/s (<7 cSt)

Aerosol product

Type of aerosol

Spray

Heat of combustion

: :

Spray

0.00002993 kJ/g

Section 10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

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/g

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

The product is stable.

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible materials

No specific data.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced

.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name

Result

Species

Dose

Exposure

Acetone

LD50 Oral

Rat

5800 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

p-Chlorobenzotrifluoride

LD50 Oral

Rat

13 g/kg

-

Irritation/Corrosion

Product/ingredient name

Result

Species

Score

Exposure

Observation

Acetone

Eyes - Mild irritant

Human

-

186300 parts per million

-

Eyes - Mild irritant

Rabbit

-

10 microliters

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20 milligrams

-

Eyes - Severe irritant

Rabbit

-

20 milligrams

-

Skin - Mild irritant

Rabbit

-

24 hours 500 milligrams

-

Skin - Mild irritant

Rabbit

-

395 milligrams

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300

Micrograms

Intermittent

-

Sensitization

Not available.

Mutagenicity

Not available.

Carcinogenicity

Not available.

Product/ingredient name

OSHA

IARC

NTP

Titanium Dioxide

-

2B

-

Reproductive toxicity

Not available.

Teratogenicity

Not available.

Specific target organ toxicity (single exposure)

Name

Category

Route of exposure

Target organs

Acetone

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

p-Chlorobenzotrifluoride

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Lt. Aliphatic Hydrocarbon Solvent

Category 3

Not applicable.

Respiratory tract irritation and

Narcotic effects

Specific target organ toxicity (repeated exposure)

Name

Category

Route of exposure

Target organs

Acetone

Category 2

Not determined

Not determined

Propane Butane

Category 2

Not determined

Not determined

p-Chlorobenzotrifluoride

Category 2

Not determined

Not determined

Lt. Aliphatic Hydrocarbon Solvent

Category 2

Not determined

Not determined

Aspiration hazard

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Information on the likely

routes of exposure

Not available.

Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

Causes skin irritation.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue

dizziness/vertigo unconsciousness

Skin contact

Adverse symptoms may include the following: irritation redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate

effects

Not available.

Potential delayed effects

Not available.

Long term exposure

Potential immediate

effects

Not available.

Potential delayed effects

Not available.

Potential chronic health effects

Not available.

General

May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates

Not available.

Section 12. Ecological information

Toxicity

Product/ingredient name

Result

Species

Exposure

Acetone

Acute EC50 20.565 mg/l Marine water

Algae - Ulva pertusa

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 10000 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Persistence and degradability

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

-

-

Readily

Bioaccumulative potential

Product/ingredient name

LogP_ow

BCF

Potential

Titanium Dioxide

-

352

low

Lt. Aliphatic Hydrocarbon Solvent

-

10 to 2500

high

Mobility in soil

Soil/water partition

coefficient (K_OC)

Not available.

Other adverse effects

No known significant effects or critical hazards.

Disposal methods

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

Section 14. Transport

information

Special precautions for user

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

Transport in bulk according to Annex II of MARPOL

73/78 and the IBC Code

Not available.

U.S. Federal regulations

State regulations

California Prop. 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

Hazardous Material Information System (U.S.A.)

Health

*

2

Flammability

3

Physical hazards

0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.