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Section 8. Exposure controls/personal protection | |
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Control parameters | |
Occupational exposure limits | |
Ingredient name | Exposure limits |
Acetone | ACGIH TLV (United States, 4/2014). TWA: 1000 ppm 8 hours. |
Propane | NIOSH REL (United States, 10/2013). |
Butane | NIOSH REL (United States, 10/2013). |
Titanium Dioxide | ACGIH TLV (United States, 4/2014). |
Appropriate engineering controls |
Environmental exposure controls
Individual protection measures
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Body protection
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Other skin protection
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Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. | |
Environmental exposure controls | Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. |
Individual protection measures | |
Hygiene measures | Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. |
Eye/face protection | Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. |
Hand protection | Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. |
Body protection | Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. |
Other skin protection | Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
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Respiratory protection |
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Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. |
Section 9. Physical and chemical properties | |||
Appearance | |||
Physical state Color Odor Odor threshold pH Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Viscosity | : : : : : : : : : : : : : : : : : : : | Liquid. | |
Color | Not available. | ||
Odor | Not available. | ||
Odor threshold | Not available. | ||
pH | 7 | ||
Melting point | Not available. | ||
Boiling point | Not available. | ||
Flash point | Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] | ||
Evaporation rate | 5.6 (butyl acetate = 1) Not available.1) | ||
Flammability (solid, gas) | Not available. | ||
Lower and upper explosive (flammable) limits | Lower: 0.9% Upper: 12.8% | ||
Vapor pressure | 13.5 kPa (101.325 mm Hg) [at 20°C] | ||
Vapor density | 1.55 [Air = 1] | ||
Relative density | 0.79 | ||
Solubility | Not available. | ||
Partition coefficient: noctanol/water | Not available. | ||
Auto-ignition temperature | Not available. | ||
Decomposition temperature | Not available. | ||
Viscosity | Kinematic (room temperature): <0.07 cm2/s (<7 cSt) Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt) | ||
Aerosol product | |||
Type of aerosol | Spray | ||
Heat of combustion | : : | Spray | 0.00002993 kJ/g |
Section 10. Stability and reactivity | |||
Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products | : : : : : : | /g |
Section 10. Stability and reactivity | |
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Reactivity | No specific test data related to reactivity available for this product or its ingredients. |
Chemical stability | The product is stable. |
Possibility of hazardous reactions | Under normal conditions of storage and use, hazardous reactions will not occur. |
Conditions to avoid | Avoid all possible sources of ignition (spark or flame). |
Incompatible materials | No specific data. |
Hazardous decomposition products | Under normal conditions of storage and use, hazardous decomposition products should not be produced |
Date of issue/Date of revision
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Section 11. Toxicological information |
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Information on toxicological effects | |||||
Acute toxicity | |||||
Product/ingredient name | Result | Species | Dose | Exposure | |
Acetone | LD50 Oral | Rat | 5800 mg/kg | - | |
Butane | LC50 Inhalation Vapor | Rat | 658000 mg/m³ | 4 hours | |
p-Chlorobenzotrifluoride | LD50 Oral | Rat | 13 g/kg | - | |
Irritation/Corrosion | |||||
Product/ingredient name | Result | Species | Score | Exposure | Observation |
Acetone | Eyes - Mild irritant | Human | - | 186300 parts per million | - |
Eyes - Mild irritant | Rabbit | - | 10 microliters | - | |
Eyes - Moderate irritant | Rabbit | - | 24 hours 20 milligrams | - | |
Eyes - Severe irritant | Rabbit | - | 20 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 24 hours 500 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 395 milligrams | - | |
Titanium Dioxide | Skin - Mild irritant | Human | - | 72 hours 300 Micrograms Intermittent | - |
Sensitization | Not available. | ||||
Mutagenicity | Not available. | ||||
Carcinogenicity | Not available. |
Classification
Product/ingredient name | OSHA | IARC | NTP | ||
Titanium Dioxide | - | 2B | - | ||
Reproductive toxicity | Not available. | ||||
Teratogenicity | Not available. | ||||
Specific target organ toxicity (single exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Propane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Butane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
p-Chlorobenzotrifluoride | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects |
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Lt. Aliphatic Hydrocarbon Solvent | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Specific target organ toxicity (repeated exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone |
p-Chlorobenzotrifluoride
Lt. Aliphatic Hydrocarbon Solvent
Category 2Category 2 |
Category 2
Category 2
Not determined | Not determined | ||||
Propane Butane | Category 2 | Not determined | Not determined |
Not determined
Not determinedp-Chlorobenzotrifluoride | Category 2 | Not determined | Not determined |
Not determined
Not determinedLt. Aliphatic Hydrocarbon Solvent | Category 2 | Not determined | Not determined | ||
Aspiration hazard | |||||
Name | Result | ||||
Propane | ASPIRATION HAZARD - Category 1 | ||||
Butane | ASPIRATION HAZARD - Category 1 | ||||
Lt. Aliphatic Hydrocarbon Solvent | ASPIRATION HAZARD - Category 1 | ||||
Information on the likely |
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routes of exposure | Not available. |
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Potential acute health effects | |||||
Eye contact |
Causes serious eye irritation. | |||
Inhalation |
Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. | |||
Skin contact |
Causes skin irritation. | |||
Ingestion |
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. | |||||
Symptoms related to the physical, chemical and toxicological characteristics | |||||
Eye contact |
Adverse symptoms may include the following: pain or irritation watering redness | |||
Inhalation |
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue |
dizziness/vertigo unconsciousness |
Skin contact | Adverse symptoms may include the following: irritation redness | ||||
Ingestion |
Adverse symptoms may include the following: |
nausea or vomiting | |||||
Delayed and immediate effects and also chronic effects from short and long term exposure | |||||
Short term exposure | |||||
Potential immediate |
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effects | Not available. |
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Potential delayed effects |
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Not available. | |||||
Long term exposure | |||||
Potential immediate |
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effects | Not available. |
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Potential delayed effects |
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Not available. | |||||
Potential chronic health effects | Not available. | ||||
General |
May cause damage to organs through prolonged or repeated exposure. | |||
Carcinogenicity |
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. | |||
Mutagenicity |
No known significant effects or critical hazards. | |||
Teratogenicity |
No known significant effects or critical hazards. | |||
Developmental effects |
No known significant effects or critical hazards. | |||
Fertility effects |
No known significant effects or critical hazards. | |||||
Numerical measures of toxicity Acute toxicity estimates | Not available. |
Section 12. Ecological information | |||
Toxicity | |||
Product/ingredient name | Result | Species | Exposure |
Acetone | Acute EC50 20.565 mg/l Marine water | Algae - Ulva pertusa | 96 hours |
Acute LC50 6000000 µg/l Fresh water | Crustaceans - Gammarus pulex | 48 hours | |
Acute LC50 10000 µg/l Fresh water | Daphnia - Daphnia magna | 48 hours | |
Acute LC50 5600 ppm Fresh water | Fish - Poecilia reticulata | 96 hours | |
Chronic NOEC 4.95 mg/l Marine water | Algae - Ulva pertusa | 96 hours | |
Chronic NOEC 0.016 ml/L Fresh water | Crustaceans - Daphniidae | 21 days | |
Chronic NOEC 0.1 ml/L Fresh water | Daphnia - Daphnia magna Neonate | 21 days | |
Chronic NOEC 5 µg/l Marine water | Fish - Gasterosteus aculeatus Larvae | 42 days | |
Titanium Dioxide | Acute LC50 >1000000 µg/l Marine water | Fish - Fundulus heteroclitus | 96 hours |
Lt. Aliphatic Hydrocarbon Solvent | Acute LC50 >100000 ppm Fresh water | Fish - Oncorhynchus mykiss | 96 hours |
Persistence and degradability | |||
Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability |
Acetone | - | - | Readily |
Bioaccumulative potential | |||
Product/ingredient name | LogPow | BCF | Potential |
Titanium Dioxide | - | 352 | low |
Lt. Aliphatic Hydrocarbon Solvent | - | 10 to 2500 | high |
Mobility in soil |
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Soil/water partition |
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coefficient (KOC) | Not available. | ||
Other adverse effects |
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No known significant effects or critical hazards. |
Section 13. Disposal considerations | |
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Disposal methods |
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The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. |
Section 14. Transport |
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Special precautions for user
Transport in bulk according to Annex II of MARPOL
73/78 and the IBC Code
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information | |
Special precautions for user | Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. |
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Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code | Not available. |
Section 15. Regulatory information | |
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U.S. Federal regulations |
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State regulations | |
California Prop. 65 | WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. |
Section 16. Other information | ||
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Hazardous Material Information System (U.S.A.) | ||
Health | * | 2 |
Flammability | 3 | |
Physical hazards | 0 | |
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. |
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision : 4/8/2015. Date of previous issue : 4/7/2015. Version : 1.03 13/13