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Section 8. Exposure controls/personal protection | ||
Control parameters | ||
Occupational exposure limits (OSHA United States) | ||
Ingredient name | CAS # | Exposure limits |
Propane | 74-98-6 | NIOSH REL (United States, 10/2020). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). Oxygen Depletion [Asphyxiant]. Explosive potential. |
Talc | 14807-96-6 | NIOSH REL (United States, 10/2020). TWA: 2 mg/m³ 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction |
Acetone | 67-64-1 | ACGIH TLV (United States, 1/2021). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m³ 8 hours. |
Lt. Aliphatic Hydrocarbon Solvent | 64742-89-8 | None. |
Butane | 106-97-8 | NIOSH REL (United States, 10/2020). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 1/2021). Explosive potential. STEL: 1000 ppm 15 minutes. |
Titanium Dioxide | 13463-67-7 | ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust |
n-Butyl Acetate | 123-86-4 | NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. |
Xylene, mixed isomers | 1330-20-7 | ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. |
Ethyl 3-Ethoxypropionate | 763-69-9 | None. |
Ethylbenzene | 100-41-4 | ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. |
Unsaturated Fatty Acids | 85711-46-2 | None. |
Light Aliphatic Hydrocarbon | 64742-47-8 | ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. |
Occupational exposure limits (Canada) | ||
Ingredient name | CAS # | Exposure limits |
Normal propane | 74-98-6 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Oxygen Depletion [Asphyxiant]. Explosive potential. CA Ontario Provincial (Canada, 6/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. |
talc (none asbestiform) | 14807-96-6 | CA British Columbia Provincial (Canada, 6/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). |
Occupational exposure limits (Canada)
Ingredient name | CAS # | Exposure limits |
Normal propane | 74-98-6 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Oxygen Depletion [Asphyxiant]. Explosive potential. CA Ontario Provincial (Canada, 6/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. |
talc (none asbestiform) | 14807-96-6 | CA British Columbia Provincial (Canada, 6/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). |
Occupational exposure limits (Canada)
8 hrs OEL: 2 mg/m³ 8 hours. Form: |
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Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m³ 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). TWA: 2 mg/m³ 8 hours. Form: respirable fraction |
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acetone |
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67-64-1 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 1200 mg/m³ 8 hours. 15 min OEL: 1800 mg/m³ 15 minutes. 8 hrs OEL: 500 ppm 8 hours. 15 min OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 500 ppm 8 hours. TWAEV: 1190 mg/m³ 8 hours. STEV: 1000 ppm 15 minutes. |
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STEV: 2380 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours. |
Butane |
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106-97-8 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 800 ppm 8 hours. TWAEV: 1900 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Explosive potential. STEL: 1000 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). Explosive potential. STEL: 1000 ppm 15 minutes. |
Titanium |
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dioxide | 13463-67-7 | CA British Columbia Provincial (Canada, |
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6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. |
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n-butyl |
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acetate | 123-86-4 | CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. |
Xylene |
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1330-20-7 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. |
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CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. |
Ethylbenzene |
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100-41-4 | CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m³ 8 hours. 15 min OEL: 543 mg/m³ 15 minutes. 15 min OEL: 125 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. CA Saskatchewan Provincial (Canada, |
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7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. | ||
Petroleum refining, hydrotreated light distillate | 64742-47-8 | CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 6/2018). Absorbed through skin. 8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. |
Occupational exposure limits (Mexico)
CAS # | Exposure limits | |
Propane | 74-98-6 | NOM-010-STPS-2014 (Mexico, 4/2016).  TWA: 1000 ppm 8 hours. |
Acetone | 67-64-1 | NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. |
Butane | 106-97-8 | NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours. |
n-Butyl Acetate | 123-86-4 | NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. |
Xylene, mixed isomers | 1330-20-7 | NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. |
Appropriate engineering |
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controls | Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or |
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other engineering controls to keep worker exposure to airborne contaminants below any |
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recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. |
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Environmental exposure |
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controls | Emissions from ventilation or work process equipment should be checked to ensure |
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they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. | |
Individual protection measures | |
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Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
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Product/ingredient name | Result | Species | Dose | Exposure |
Acetone | LD50 Oral | Rat | 5800 mg/kg | -   |
Butane | LC50 Inhalation Vapor | Rat | 658000 mg/m³ | 4 hours |
n-Butyl Acetate | LD50 Dermal | Rabbit | >17600 mg/kg | - |
LD50 Oral | Rat | 10768 mg/kg | - | |
Xylene, mixed isomers | LC50 Inhalation Gas. | Rat | 6700 ppm | 4 hours |
LD50 Oral | Rat | 4300 mg/kg | - | |
Ethyl 3-Ethoxypropionate | LD50 Oral | Rat | 3200 mg/kg | - |
Ethylbenzene | LD50 Dermal | Rabbit | >5000 mg/kg | - |
LD50 Oral | Rat | 3500 mg/kg | - |
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Product/ingredient name | Result | Species | Score | Exposure | Observation |
Talc | Skin - Mild irritant | Human | - | 72 hours 300 ug I | -   |
Acetone | Eyes - Mild irritant | Human | - | 186300 ppm | - |
Eyes - Mild irritant | Rabbit | - | 10 uL | - | |
Eyes - Moderate irritant | Rabbit | - | 24 hours 20 mg | - | |
Eyes - Severe irritant | Rabbit | - | 20 mg | - | |
Skin - Mild irritant | Rabbit | - | 24 hours 500 mg | - | |
Skin - Mild irritant | Rabbit | - | 395 mg | - | |
Titanium Dioxide | Skin - Mild irritant | Human | - | 72 hours 300 ug I | - |
n-Butyl Acetate | Eyes - Moderate irritant | Rabbit | - | 100 mg | - |
Skin - Moderate irritant | Rabbit | - | 24 hours 500 mg | - | |
Xylene, mixed isomers | Eyes - Mild irritant | Rabbit | - | 87 mg | - |
Eyes - Severe irritant | Rabbit | - | 24 hours 5 mg | - | |
Skin - Mild irritant | Rat | - | 8 hours 60 uL | - | |
Skin - Moderate irritant | Rabbit | - | 24 hours 500 mg | - | |
Skin - Moderate irritant | Rabbit | - | 100 % | - | |
Ethyl 3-Ethoxypropionate | Skin - Mild irritant | Rabbit | - | 24 hours 500 | - |
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Product/ingredient name | OSHA | IARC | NTP |
Talc | - | 3 | -   |
Titanium Dioxide | - | 2B | - |
Xylene, mixed isomers | - | 3 | - |
Ethylbenzene | - | 2B | - |
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Product/ingredient name | Result | Species | Exposure | ||||
Acetone | Acute EC50 7200000 µg/l Fresh water | Algae - Selenastrum sp. | 96 hours   | ||||
Acute LC50 4.42589 ml/L Marine water | Crustaceans - Acartia tonsa Copepodid | 48 hours | |||||
Acute LC50 7460000 µg/l Fresh water | Daphnia - Daphnia cucullata | 48 hours | |||||
Acute LC50 5600 ppm Fresh water | Fish - Poecilia reticulata | 96 hours | |||||
Chronic NOEC 4.95 mg/l Marine water | Algae - Ulva pertusa | 96 hours | |||||
Chronic NOEC 0.016 ml/L Fresh water | Crustaceans - Daphniidae | 21 days | |||||
Chronic NOEC 0.1 ml/L Fresh water | Daphnia - Daphnia magna Neonate | 21 days | |||||
Chronic NOEC 5 µg/l Marine water | Fish - Gasterosteus aculeatus Larvae | 42 days | |||||
Lt. Aliphatic Hydrocarbon Solvent | Acute LC50 >100000 ppm Fresh water | Fish - Oncorhynchus mykiss | 96 hours | ||||
Titanium Dioxide | Acute LC50 >1000000 µg/l Marine water | Fish - Fundulus heteroclitus | 96 hours | ||||
n-Butyl Acetate | Acute LC50 32 mg/l Marine water | Crustaceans - Artemia salina | 48 hours | ||||
Acute LC50 18000 µg/l Fresh water | Fish - Pimephales promelas | 96 hours | |||||
Xylene, mixed isomers | Acute LC50 8500 µg/l Marine water | Crustaceans - Palaemonetes pugio | 48 hours | ||||
Acute LC50 13400 µg/l Fresh water | Fish - Pimephales promelas | 96 hours | |||||
Ethylbenzene | Acute EC50 4900 µg/l Marine water | Algae - Skeletonema costatum | 72 hours | ||||
Acute EC50 7700 µg/l Marine water | Algae - Skeletonema costatum | 96 hours | |||||
Acute EC50 6.53 mg/l Marine water | Crustaceans - Artemia sp. Nauplii | 48 hours | |||||
Acute EC50 2.93 mg/l Fresh water | Daphnia - Daphnia magna - | 48 hours | |||||
Section 12. Ecological information | |||||||
Neonate | |||||||
Acute LC50 4200 µg/l Fresh water | Fish - Oncorhynchus mykiss | 96 hours | |||||
Light Aliphatic Hydrocarbon | Acute LC50 2200 µg/l Fresh water | Fish - Lepomis macrochirus | 4 days | ||||
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Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability |
Acetone | - | - | Readily   |
n-Butyl Acetate | - | - | Readily |
Xylene, mixed isomers | - | - | Readily |
Ethylbenzene | - | - | Readily |
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Product/ingredient name | LogPow | BCF | Potential | ||
Lt. Aliphatic Hydrocarbon Solvent | - | 10 to 2500 | high   | ||
Xylene, mixed isomers | - | 8.1 to 25.9 | low | ||
Mobility in soil | |||||
Soil/water partition coefficient (KOC) | : Not available. | ||||
Other adverse effects | : No known significant effects or critical hazards. | ||||
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DOT Classification | TDG Classification | Mexico Classification | IATA | IMDG | |
UN number | UN1950 | UN1950 | UN1950 | UN1950 | UN1950 |
UN proper shipping name | AEROSOLS | AEROSOLS | AEROSOLS | AEROSOLS, flammable | AEROSOLS |
Transport hazard class(es) | 2.1   | 2.1   | 2.1   | 2.1   | 2.1   |
Packing group | - | - | - | - | - |
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Section 14. Transport information | |||||
Environmental hazards | No. | No. | No. | No. | No. |
Additional information | - | Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). | - | - | -   |
Dependent upon container size, this product may ship under the Limited Quantity shipping exception. | Dependent upon container size, this product may ship under the Limited Quantity shipping exception. | Dependent upon container size, this product may ship under the Limited Quantity shipping exception. | Dependent upon container size, this product may ship under the Limited Quantity shipping exception. | Dependent upon container size, this product may ship under the Limited Quantity shipping exception. | |
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