Section 1. Identification

Product name

KRYLON® PRO PROFESSIONAL All Surface Enamel Flat White

Product code

5810

Other means of identification

Not available.

Product type

Aerosol.

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

Manufacturer

Krylon Products Group

101 W. Prospect Avenue Cleveland, OH 44115

Emergency telephone number of the company

US / Canada: (216) 566-2917

Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Product Information Telephone Number

US / Canada: (800) 457-9566 Mexico: Not Available

Regulatory Information Telephone Number

US / Canada: (216) 566-2902 Mexico: Not Available

Transportation Emergency Telephone Number

US / Canada: (216) 566-2917

Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

FLAMMABLE AEROSOLS - Category 1

GASES UNDER PRESSURE - Compressed gas

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

SKIN SENSITIZATION - Category 1

CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract

irritation) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -

Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1

ASPIRATION HAZARD - Category 1

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 30.4%

(oral), 32.1% (dermal), 32.1% (inhalation)

GHS label elements

Hazard pictograms

Signal word

Danger

Hazard statements

Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

Causes serious eye irritation.

May cause respiratory irritation.

May cause drowsiness or dizziness.

Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure. (lungs)

Precautionary statements

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use.

Response

IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place. Keep container tightly closed.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Hazards not otherwise classified

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations.

Section 3. Composition/information on ingredients

Substance/mixture

Mixture

Other means of identification

Not available.

CAS number/other identifiers

Ingredient name

% by weight

CAS number

Propane

≥10 - ≤25

74-98-6

Talc

≥10 - ≤25

14807-96-6

Acetone

≥10 - ≤25

67-64-1

Lt. Aliphatic Hydrocarbon Solvent

≥10 - ≤25

64742-89-8

Butane

≤10

106-97-8

Titanium Dioxide

≤10

13463-67-7

n-Butyl Acetate

≤7.7

123-86-4

Xylene, mixed isomers

≤2.2

1330-20-7

Ethyl 3-Ethoxypropionate

≤3

763-69-9

Ethylbenzene

<1

100-41-4

Unsaturated Fatty Acids

<1

85711-46-2

Light Aliphatic Hydrocarbon

≤0.3

64742-47-8

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects

Eye contact

Causes serious eye irritation.

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Skin contact

May cause an allergic skin reaction.

Ingestion

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following:

pain or irritation

watering

redness

Inhalation

Adverse symptoms may include the following:

respiratory tract irritation

coughing

nausea or vomiting

headache

drowsiness/fatigue

dizziness/vertigo

unconsciousness

Skin contact

Adverse symptoms may include the following:

irritation

redness

Ingestion

Adverse symptoms may include the following:

nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments

No specific treatment.

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media

None known.

Specific hazards arising from the chemical

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.

Hazardous thermal decomposition products

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

phosphorus oxides

metal oxide/oxides

Special protective actions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools.

Empty containers retain product residue and can be hazardous.

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Product/ingredient name

Result

Species

Exposure

Acetone

Acute EC50 7200000 µg/l Fresh water

Algae - Selenastrum sp.

96 hours

Image Removed

Image Added

Acute LC50 4.42589 ml/L Marine water

Crustaceans - Acartia tonsa Copepodid

48 hours

Acute LC50 7460000 µg/l Fresh water

Daphnia - Daphnia cucullata

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

n-Butyl Acetate

Acute LC50 32 mg/l Marine water

Crustaceans - Artemia salina

48 hours

Acute LC50 18000 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Xylene, mixed isomers

Acute LC50 8500 µg/l Marine water

Crustaceans - Palaemonetes pugio

48 hours

Acute LC50 13400 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Ethylbenzene

Acute EC50 4900 µg/l Marine water

Algae - Skeletonema costatum

72 hours

Acute EC50 7700 µg/l Marine water

Algae - Skeletonema costatum

96 hours

Acute EC50 6.53 mg/l Marine water

Crustaceans - Artemia sp. Nauplii

48 hours

Acute EC50 2.93 mg/l Fresh water

Daphnia - Daphnia magna -

48 hours

Section 12. Ecological information

Neonate

Acute LC50 4200 µg/l Fresh water

Fish - Oncorhynchus mykiss

96 hours

Light Aliphatic Hydrocarbon

Acute LC50 2200 µg/l Fresh water

Fish - Lepomis macrochirus

4 days

Product/ingredient name

LogP_ow

BCF

Potential

Lt. Aliphatic Hydrocarbon Solvent

-

10 to 2500

high

Image Removed

Image Added

Xylene, mixed isomers

-

8.1 to 25.9

low

Mobility in soil

Soil/water partition coefficient (K_OC)

: Not available.

Other adverse effects

: No known significant effects or critical hazards.

DOT

Classification

TDG

Classification

Mexico Classification

IATA

IMDG

UN number

UN1950

UN1950

UN1950

UN1950

UN1950

UN proper shipping name

AEROSOLS

AEROSOLS

AEROSOLS

AEROSOLS, flammable

AEROSOLS

Transport hazard class(es)

2.1

Image Removed

Image Added

2.1

Image Removed

Image Added

2.1

Image Removed

Image Added

2.1

Image Removed

Image Added

2.1

Image Removed

Image Added

Packing group

-

-

-

-

-