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Section 8. Exposure controls/personal protection | |
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Control parameters | |
Occupational exposure limits | |
Ingredient name | Exposure limits |
Acetone | ACGIH TLV (United States, 4/2014). TWA: 1000 ppm 8 hours. |
Propane | NIOSH REL (United States, 10/2013). |
Butane | NIOSH REL (United States, 10/2013). |
Titanium Dioxide | ACGIH TLV (United States, 4/2014). |
Appropriate engineering controls |
Environmental exposure controls
Individual protection measures
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Body protection
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Other skin protection
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Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. | |
Environmental exposure controls | Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. |
Individual protection measures | |
Hygiene measures | Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. |
Eye/face protection | Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. |
Hand protection | Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. |
Body protection | Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. |
Other skin protection | Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
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Respiratory protection |
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Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. |
Section 9. Physical and chemical properties | ||
Appearance | ||
Physical state | Liquid. | |
Color | Not available. | |
Odor | Not available. | |
Odor threshold | Not available. | |
pH | 7 | |
Melting point | Not available. | |
Boiling point | Not available. | |
Flash point | Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] | |
Evaporation rate | 5.6 (butyl acetate = 1) | |
Flammability (solid, gas) | Not available. | |
Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Viscosity | : : : : : : : : : : : : : : : : : : : | Liquid. Not available. Not available. Not available. 7 Not available. Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] 5.6 (butyl acetate = 1) Not available. Lower: 0.9% Upper: 12.8% Lower: 0.9% Upper: 12.8% |
Vapor pressure | 13.5 kPa (101.325 mm Hg) [at 20°C] | |
Vapor density | 1.55 [Air = 1] | |
Relative density | 0.79 | |
Solubility | Not available. | |
Partition coefficient: noctanol/water | Not available. | |
Auto-ignition temperature | Not available. | |
Decomposition temperature | Not available. | |
Viscosity | Kinematic (room temperature): <0.07 cm2/s (<7 cSt) Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt) | |
Aerosol product | ||
Type of aerosol | Spray | |
Heat of combustion | : : | Spray 0.00002993 kJ/g |
Section 10. Stability and reactivity | ||
Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products | : : : : : : | 0.00002993 kJ/g |
Section 10. Stability and reactivity | |
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Reactivity | No specific test data related to reactivity available for this product or its ingredients. |
Chemical stability | The product is stable. |
Possibility of hazardous reactions | Under normal conditions of storage and use, hazardous reactions will not occur. |
Conditions to avoid | Avoid all possible sources of ignition (spark or flame). |
Incompatible materials | No specific data. |
Hazardous decomposition products | Under normal conditions of storage and use, hazardous decomposition products should not be produced |
Date of issue/Date of revision
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Section 11. Toxicological information |
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Information on toxicological effects | |||||
Acute toxicity | |||||
Product/ingredient name | Result | Species | Dose | Exposure | |
Acetone | LD50 Oral | Rat | 5800 mg/kg | - | |
Butane | LC50 Inhalation Vapor | Rat | 658000 mg/m³ | 4 hours | |
p-Chlorobenzotrifluoride | LD50 Oral | Rat | 13 g/kg | - | |
Irritation/Corrosion | |||||
Product/ingredient name | Result | Species | Score | Exposure | Observation |
Acetone | Eyes - Mild irritant | Human | - | 186300 parts per million | - |
Eyes - Mild irritant | Rabbit | - | 10 microliters | - | |
Eyes - Moderate irritant | Rabbit | - | 24 hours 20 milligrams | - | |
Eyes - Severe irritant | Rabbit | - | 20 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 24 hours 500 milligrams | - | |
Skin - Mild irritant | Rabbit | - | 395 milligrams | - | |
Titanium Dioxide | Skin - Mild irritant | Human | - | 72 hours 300 Micrograms Intermittent | - |
Sensitization | Not available. | ||||
Mutagenicity | Not available. | ||||
Carcinogenicity | Not available. |
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Product/ingredient name | OSHA | IARC | NTP | ||
Titanium Dioxide | - | 2B | - | ||
Reproductive toxicity | Not available. | ||||
Teratogenicity | Not available. | ||||
Specific target organ toxicity (single exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Propane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Butane | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
p-Chlorobenzotrifluoride | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects |
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Lt. Aliphatic Hydrocarbon Solvent | Category 3 | Not applicable. | Respiratory tract irritation and Narcotic effects | ||
Specific target organ toxicity (repeated exposure) | |||||
Name | Category | Route of exposure | Target organs | ||
Acetone |
Propane Butane
p-Chlorobenzotrifluoride
Lt. Aliphatic Hydrocarbon SolventCategory 2 |
Category 2
Category 2
Category 2Not determined | Not determined | ||||
Propane Butane | Category 2 | Not determined | Not determined |
Not determined
Not determinedp-Chlorobenzotrifluoride | Category 2 | Not determined | Not determined |
Not determined
Not determinedLt. Aliphatic Hydrocarbon Solvent | Category 2 | Not determined | Not determined | ||
Aspiration hazard | |||||
Name | Result | ||||
Propane | ASPIRATION HAZARD - Category 1 | ||||
Butane | ASPIRATION HAZARD - Category 1 | ||||
Lt. Aliphatic Hydrocarbon Solvent | ASPIRATION HAZARD - Category 1 |
Information on the likely : Not available. routes of exposure
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It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision : 4/8/2015. Date of previous issue : 4/7/2015. Version : 1.03 13/13