Version: 2.0
Revision Date: 03/18/2020
SAFETY DATA SHEET
1.Identification | |
Product identifier | SPRAYWAY GLASS CLEANER |
Other means of identification | |
SDS number: | RE1000000075 |
Recommended restrictions | |
Product use | Cleaner |
Restrictions on use | Not known. |
Manufacturer/Importer/Distributor Information | |
Manufacturer | |
Company Name | Sprayway, Inc. |
Address | 1000 INTEGRAM DR. Pacific, MO 63069 |
Telephone | 1-630-628-3000 |
Fax | |
Emergency telephone number | 1-866-836-8855 |
2. Hazard(s) identification | |
Hazard Classification | |
Physical Hazards | Gases under pressure Compressed gas |
Label Elements | |
Hazard Symbol |  |
Signal Word | Warning |
Hazard Statement | Contains gas under pressure; may explode if heated. |
Precautionary Statements | |
Storage | Protect from sunlight. Store in a well-ventilated place. |
Hazard(s) not otherwise classified (HNOC) | None. |
3. Composition/information on ingredients | ||
Mixtures | ||
Chemical Identity | CAS number | Content in percent (%)* |
Ethanol | 64-17-5 | 1-<5% |
Ethanol, 2-butoxy- | 111-76-2 | 1-<5% |
Propane | 74-98-6 | 1-<5% |
Butane | 106-97-8 | 1-<5% |
*All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. | ||
4. First-aid measures | |
Ingestion | Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
Inhalation | Move to fresh air. |
Skin Contact | Wash skin thoroughly with soap and water. If skin irritation occurs: Get medical advice/attention. |
Eye contact | Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. |
Most important symptoms/effects, acute and delayed | |
Symptoms | No data available. |
Hazards | No data available. |
Indication of immediate medical attention and special treatment needed | |
Treatment | No data available. |
5. Fire-fighting measures | |
General Fire Hazards | Use water spray to keep fire-exposed containers cool. Fight fire from a protected location. Move containers from fire area if you can do so without risk. |
Suitable (and unsuitable) extinguishing media | |
Suitable extinguishing media | Use fire-extinguishing media appropriate for surrounding materials. |
Unsuitable extinguishing media | Do not use water jet as an extinguisher, as this will spread the fire. |
Specific hazards arising from the chemical | Pressurized container may explode when exposed to heat or flame. |
Special protective equipment and precautions for firefighters | |
Special fire fighting procedures | No data available. |
Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures:
No data available.
Methods and material for
containment and cleaning
up:
Stop the flow of material, if this is without risk. Absorb with sand or other inert absorbent.
Environmental Precautions:
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages.
7. Handling and storage
Precautions for safe handling: Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Protect from sunlight. Store in a cool place. Aerosol Level 1 including any
incompatibilities:
8. Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chemical Identity | Type | Exposure Limit Values | Source | |
Ethanol | REL | 1,000 ppm | 1,900 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
PEL | 1,000 ppm | 1,900 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 | |
CFR 1910.1000) (02 2006) | ||||
TWA | 1,000 ppm | 1,900 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
STEL | 1,000 ppm | US. ACGIH Threshold Limit Values (2009) | ||
Ethanol, 2-butoxy- | TWA | 20 ppm | US. ACGIH Threshold Limit Values (2008) | |
REL | 5 ppm | 24 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards | |
(2005) | ||||
PEL | 50 ppm | 240 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 | |
CFR 1910.1000) (02 2006) | ||||
TWA | 25 ppm | 120 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Propane | REL | 1,000 ppm | 1,800 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
PEL | 1,000 ppm | 1,800 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 | |
CFR 1910.1000) (02 2006) | ||||
TWA | 1,000 ppm | 1,800 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Butane | REL | 800 ppm | 1,900 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
STEL | 1,000 ppm | US. ACGIH Threshold Limit Values (03 2018) | ||
TWA | 800 ppm | 1,900 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Morpholine | REL | 20 ppm | 70 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
STEL | 30 ppm | 105 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards | |
(2005) | ||||
TWA | 20 ppm | US. ACGIH Threshold Limit Values (2008) | ||
TWA | 20 ppm | 70 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
STEL | 30 ppm | 105 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
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PEL | 20 ppm | 70 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 | |
CFR 1910.1000) (02 2006) | ||||
2-Propanol, 2-methyl- | STEL | 150 ppm | 450 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
TWA | 100 ppm | 300 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
PEL | 100 ppm | 300 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 | |
CFR 1910.1000) (02 2006) | ||||
TWA | 100 ppm | US. ACGIH Threshold Limit Values (2008) | ||
STEL | 150 ppm | 450 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
REL | 100 ppm | 300 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards | |
(2005) | ||||
Silica | REL | 6 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards | |
(2005) | ||||
TWA | 20 millions of | US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) | ||
particles per | ||||
cubic foot of | ||||
air | ||||
TWA | 6 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | ||
TWA | 0.8 mg/m3 | US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) | ||
2,6-Octadienal, 3,7-dimethyl- | TWA | 5 ppm | US. ACGIH Threshold Limit Values (01 2010) | |
- Inhalable fraction and | ||||
vapor. |
Biological Limit Values
Chemical Identity | Exposure Limit Values | Source | ||
Ethanol, 2-butoxy- (Butoxyacetic acid (BAA), with hydrolysis: | 200 mg/g (Creatinine in urine) | ACGIH BEL (03 2013) | ||
Sampling time: End of shift.) | ||||
Appropriate Engineering | No data available. | |||
Controls | ||||
Individual protection measures, such as personal protective equipment
General information: | Use personal protective equipment as required. Personal protection | |
equipment should be chosen according to the CEN standards and in | ||
discussion with the supplier of the personal protective equipment. | ||
Eye/face protection: | Wear goggles/face shield. | |
Skin Protection | ||
Hand Protection: | No data available. | |
Other: | No data available. | |
Respiratory Protection: | In case of inadequate ventilation use suitable respirator. Seek advice from | |
local supervisor. | ||
Hygiene measures: | Observe good industrial hygiene practices. | |
9. Physical and chemical properties | ||
Appearance | ||
Physical state: | liquid | |
Form: | Spray Aerosol | |
Color: | No data available. | |
Odor: | No data available. | |
Odor threshold: | No data available. | |
pH: | 8.7 - 9.7 | |
Melting point/freezing point: | No data available. | |
Initial boiling point and boiling range: | No data available. | |
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Version: 2.0
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Flash Point: Not applicable
Evaporation rate: No data available.
Flammability (solid, gas): Non-flammable Aerosol
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: 5,515 - 6,894 hPa (20 °C)
Vapor density: No data available.
Density: No data available.
Relative density: No data available.
Solubility(ies)
Solubility in water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.
10. Stability and reactivity
Reactivity: | No data available. |
Chemical Stability: | Material is stable under normal conditions. |
Possibility of hazardous | No data available. |
reactions: | |
Conditions to avoid: | Avoid heat or contamination. |
Incompatible Materials: | No data available. |
Hazardous Decomposition | No data available. |
Products: | |
11. Toxicological information | |
Information on likely routes of exposure
Inhalation: No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
Ingestion:
No data available.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation:
No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
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Ingestion:
No data available.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product:
ATEmix: 36,844.23 mg/kg
Dermal
Product:
ATEmix: 32,120.9 mg/kg
Inhalation
Product:
ATEmix: 690.87 mg/l
ATEmix : 172.72 mg/l
Repeated dose toxicity
Product:
No data available.
Specified substance(s):
Ethanol
Ethanol, 2-butoxy-
Propane
Butane
NOAEL (Rat(Male), Oral, 7 - 14 Weeks): 10 %(m) Oral Experimental result,
Key study
NOAEL (Rat(Female), Inhalation, 2 yr): < 31 ppm(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female), Oral, 90 d): < 82 mg/kg Oral Experimental result, Key
study
NOAEL (Rabbit(Female, Male), Dermal, 90 d): > 150 mg/kg Dermal
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
Skin Corrosion/Irritation
Product:
No data available.
Specified substance(s):
Ethanol
Ethanol, 2-butoxy-
in vivo (Rabbit): Not irritant Experimental result, Key study
in vivo (Rabbit): Irritating Experimental result, Key study
Serious Eye Damage/Eye Irritation
Product: No data available.
Specified substance(s):
Ethanol
Rabbit, 1 - 24 hrs: Not irritating
Ethanol, 2-butoxy-
Rabbit, 24 - 72 hrs: Irritating
Respiratory or Skin Sensitization
Product:
No data available.
Specified substance(s):
Ethanol
Ethanol, 2-butoxy-
Skin sensitization:, in vivo (Guinea pig): Non sensitising
Skin sensitization:, in vivo (Guinea pig): Non sensitising
Carcinogenicity
Product:
No data available.
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IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
No carcinogenic components identified
US. National Toxicology Program (NTP) Report on Carcinogens:
No carcinogenic components identified
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified
Germ Cell Mutagenicity
In vitro
Product:
No data available.
In vivo
Product:
No data available.
Reproductive toxicity
Product:
No data available.
Specific Target Organ Toxicity - Single Exposure
Product: No data available.
Specific Target Organ Toxicity - Repeated Exposure
Product: No data available.
Aspiration Hazard
Product:
Other effects:
No data available.
No data available.
12. Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product:
No data available.
Specified substance(s):
Ethanol
Ethanol, 2-butoxy-
Propane
Butane
LC 50 (Pimephales promelas, 96 h): 15.3 g/l Experimental result, Key study
LC 50 (Oncorhynchus mykiss, 96 h): 1,474 mg/l Experimental result, Key
study
LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
Aquatic Invertebrates
Product:
No data available.
Specified substance(s):
Ethanol
Ethanol, 2-butoxy-
Butane
LC 50 (Ceriodaphnia dubia, 48 h): 5,012 mg/l Experimental result, Key study
EC 50 (Daphnia magna, 48 h): 1,550 mg/l Experimental result, Key study
LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study
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Chronic hazards to the aquatic environment:
Fish
Product:
No data available.
Specified substance(s):
Ethanol
NOAEL (Oryzias latipes): 7,900 mg/l Read-across from supporting substance (structural analogue or surrogate), Supporting study
Ethanol, 2-butoxy-
NOAEL (Danio rerio): > 100 mg/l Experimental result, Key study
Aquatic Invertebrates
Product:
No data available.
Specified substance(s):
Ethanol
LC 50 (Daphnia magna): 454 mg/l Experimental result, Key study
NOAEL (Daphnia magna): 9.6 mg/l Experimental result, Key study
Ethanol, 2-butoxy-
EC 10 (Daphnia magna): 134 mg/l Experimental result, Key study
EC 50 (Daphnia magna): 297 mg/l Experimental result, Key study
Toxicity to Aquatic Plants
Product:
No data available.
Persistence and Degradability
Biodegradation
Product:
No data available.
Specified substance(s):
Ethanol
95 % Detected in water. Experimental result, Key study
Ethanol, 2-butoxy-
90.4 % Detected in water. Experimental result, Key study
Propane
100 % (385.5 h) Detected in water. Experimental result, Key study
50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study
Butane
100 % (385.5 h) Detected in water. Experimental result, Key study
BOD/COD Ratio
Product:
No data available.
Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: | No data available. |
Specified substance(s): | |
Ethanol | Cyprinus carpio, Bioconcentration Factor (BCF): 4.5 Aquatic sediment Read- |
across from supporting substance (structural analogue or surrogate), | |
Supporting study | |
Partition Coefficient n-octanol / water (log Kow) | |
Product: | No data available. |
Mobility in soil: | No data available. |
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Known or predicted distribution to environmental compartments | |||
Ethanol | No data available. | ||
Ethanol, 2-butoxy- | No data available. | ||
Propane | No data available. | ||
Butane | No data available. | ||
Other adverse effects: | No data available. | ||
13. Disposal considerations | |||
Disposal instructions: | Wash before disposal. Dispose to controlled facilities. | ||
Contaminated Packaging: | No data available. | ||
14. Transport information | |||
DOT | |||
UN Number: | UN 1950 | ||
UN Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es) | |||
Class: | 2.2 | ||
Label(s): | – | ||
Packing Group: | II | ||
Marine Pollutant: | No | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
IMDG | |||
UN Number: | UN 1950 | ||
UN Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es) | |||
Class: | 2 | ||
Label(s): | – | ||
EmS No.: | |||
Packing Group: | – | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
IATA | |||
UN Number: | UN 1950 | ||
Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es): | |||
Class: | 2.2 | ||
Label(s): | – | ||
Packing Group: | – | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
Cargo aircraft only: | Allowed. | ||
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15. Regulatory information
US Federal Regulations
Restrictions on use: Not known.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.
CERCLA Hazardous Substance List (40 CFR 302.4):
Chemical Identity | Reportable quantity | |
Ethanol | lbs. 100 | |
Propane | lbs. 100 | |
Butane | lbs. 100 | |
Morpholine | lbs. 100 | |
Nitrous acid, sodium salt (1:1) | lbs. 100 | |
2-Propanol, 2-methyl- | lbs. 100 | |
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Not listed.
SARA 302 Extremely Hazardous Substance
None present or none present in regulated quantities.
SARA 304 Emergency Release Notification | ||||
Chemical Identity | Reportable quantity | |||
Ethanol | lbs. 100 | |||
Ethanol, 2-butoxy- | ||||
Propane | lbs. 100 | |||
Butane | lbs. 100 | |||
Morpholine | lbs. 100 | |||
Nitrous acid, sodium salt (1:1) | lbs. 100 | |||
2-Propanol, 2-methyl- | lbs. 100 | |||
SARA 311/312 Hazardous Chemical | ||||
Chemical Identity | Threshold Planning Quantity | |||
Ethanol | 10000 lbs | |||
Ethanol, 2-butoxy- | 10000 lbs | |||
Propane | 10000 lbs | |||
Butane | 10000 lbs | |||
Morpholine | 10000 lbs | |||
Nitrous acid, sodium salt (1:1) | 10000 lbs | |||
2-Propanol, 2-methyl- | 10000 lbs | |||
Silica | 10000 lbs | |||
2,6-Octadienal, 3,7-dimethyl- | 10000 lbs | |||
SARA 313 (TRI Reporting) | |||||||||
Reporting | Reporting threshold for | ||||||||
threshold for | manufacturing and | ||||||||
Chemical Identity | other users | processing | |||||||
Ethanol, 2-butoxy- | N230 lbs | N230 lbs. | |||||||
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Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65
No ingredient requiring a warning under CA Prop 65.
US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
Ethanol
Ethanol, 2-butoxy-
Propane
Butane
US. Massachusetts RTK - Substance List
No ingredient regulated by MA Right-to-Know Law present.
US. Pennsylvania RTK - Hazardous Substances
Chemical Identity
Ethanol
Ethanol, 2-butoxy-
Propane
Butane
US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.
International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
Not applicable
Kyoto protocol
Not applicable
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Inventory Status:
Australia AICS:
On or in compliance with the inventory
Canada DSL Inventory List:
On or in compliance with the inventory
Canada NDSL Inventory:
Not in compliance with the inventory.
Ontario Inventory:
On or in compliance with the inventory
China Inv. Existing Chemical Substances:
On or in compliance with the inventory
Japan (ENCS) List:
On or in compliance with the inventory
Japan ISHL Listing:
Not in compliance with the inventory.
Japan Pharmacopoeia Listing:
Not in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI):
Not in compliance with the inventory.
Mexico INSQ:
Not in compliance with the inventory.
New Zealand Inventory of Chemicals:
Not in compliance with the inventory.
Philippines PICCS:
Not in compliance with the inventory.
Taiwan Chemical Substance Inventory:
On or in compliance with the inventory
US TSCA Inventory:
On or in compliance with the inventory
EINECS, ELINCS or NLP:
Not in compliance with the inventory.
16.Other information, including date of preparation or last revision
Issue Date:
Revision Information:
Version #:
Further Information:
Disclaimer:
03/18/2020
No data available.
2.0
No data available.
This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.
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