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ZEP ANTIBACTERIAL HAND SOAP

Version: 1.2

Revision Date: 04/24/2020

Print Date: 07/15/2020

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name

ZEP ANTIBACTERIAL HAND SOAP

Material number

R46101

Manufacturer or supplier's details

Company

Zep Inc.

Address

350 Joe Frank Harris Parkway, SE

Emerson, GA 30137

Telephone

404-352-1680

Emergency telephone numbers

For SDS Information

Compliance Services 1-877-428-9937

For a Medical Emergency

877-541-2016 Toll Free - All Calls Recorded

For a Transportation

CHEMTREC: 800-424-9300 - All Calls Recorded.

Emergency

In the District of Columbia 202-483-7616

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance

viscous liquid

Colour

clear, red, orange

Odour

No data available

GHS Classification

Eye irritation

Category 2A

GHS label elements

Hazard pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

Precautionary statements

Prevention:

P264 Wash skin thoroughly after handling.

P280 Wear eye protection/ face protection.

Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/attention

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

Mixture

Hazardous components

Chemical name

CAS-No.

Concentration [%]

glycerol

56-81-5

>= 1 - < 3

cetrimonium chloride

112-02-7

>= 1 - < 3

Fatty acids, C8-18 and C18-unsatd., compds. with diisopropanolamine

68855-69-6

>= 1 - < 3

N-[3-(dimethylamino)propyl]dodecanamide Noxide

61792-31-2

>= 1 - < 3

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

General advice

Move out of dangerous area.

Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.

If inhaled

If unconscious, place in recovery position and seek medical advice.

If symptoms persist, call a physician.

In case of skin contact

This product is formulated for use on skin but should always be immediately washed off with plenty of water. Discontinue use if irritation and redness develop. If conditions persist for more than 72 hours, consult a physician.

In case of eye contact

Remove contact lenses.

Protect unharmed eye.

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes.

If swallowed

Keep respiratory tract clear.

Never give anything by mouth to an unconscious person. DO NOT induce vomiting unless directed to do so by a physician or poison control center. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

Effects are immediate and delayed.

Symptoms may include irritation, redness, pain, and rash.

Causes serious eye irritation.

Review section 2 of SDS to see all potential hazards.

Notes to physician

Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

Dry chemical

Foam

Alcohol-resistant foam

Carbon dioxide (CO2)

Unsuitable extinguishing

media

High volume water jet

Specific hazards during firefighting

Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products

Carbon dioxide (CO2)

Carbon monoxide

Smoke

Nitrogen oxides (NOx)

Specific extinguishing methods

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Further information

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Material can create slippery conditions.

Use non-slip safety shoes in areas where spills or leaks can occur.

Refer to protective measures listed in sections 7 and 8.

Environmental precautions

Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains, inform respective authorities.

Methods and materials for containment and cleaning up

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling

For personal protection see section 8.

Avoid contact with eyes.

Smoking, eating and drinking should be prohibited in the application area.

Dispose of rinse water in accordance with local and national regulations.

Conditions for safe storage

Keep container tightly closed in a dry and well-ventilated place.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Materials to avoid

No materials to be especially mentioned.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components

CAS-No.

Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

glycerol

56-81-5

TWA (mist, respirable fraction)

5 mg/m3

OSHA Z-1

TWA (mist, total dust)

15 mg/m3

OSHA Z-1

PEL (Mist - total fraction)

10 mg/m3

CAL PEL

PEL (Mist - respirable fraction)

5 mg/m3

CAL PEL

TWA (Mist - total dust)

10 mg/m3

OSHA P0

TWA (Mist - respirable fraction)

5 mg/m3

OSHA P0

Engineering measures

effective ventilation in all processing areas

Personal protective equipment

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

Hand protection Remarks

No special protection is required.

Eye protection

Eye protection is not required while washing with this product. In the workplace, the use of safety glasses is recommended to avoid eye exposure during the handling of containers or during spill clean-up.

Remove respiratory and skin/eye protection only after vapours have been cleared from the area.

Skin and body protection

No special protection is required.

Hygiene measures

When using do not eat or drink.

When using do not smoke.

Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

viscous liquid

Colour

clear, red, orange

Odour

No data available

Odour Threshold

No data available

pH

5 - 6

Melting point/freezing point

No data available

Boiling point

100 °C

Flash point

does not flash

Evaporation rate

No data available

Upper explosion limit

No data available

Lower explosion limit

No data available

Vapour pressure

No data available

Density

1.015 g/cm3

Solubility(ies)

Water solubility

completely soluble

Partition coefficient: noctanol/water

No data available

Auto-ignition temperature

No data available

Viscosity, kinematic

No data available

:

SECTION 10. STABILITY AND REACTIVITY

Reactivity

Stable

Chemical stability

Stable under normal conditions

Possibility of hazardous reactions

No decomposition if stored and applied as directed

Conditions to avoid

No data available

Incompatible materials

No data available

Hazardous decomposition products

No decomposition if stored normally.

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Aggravated Medical Condition

:None known.

Symptoms of Overexposure

Effects are immediate and delayed.

Symptoms may include irritation, redness, pain, and rash.

Causes serious eye irritation.

Review section 2 of SDS to see all potential hazards. Treat symptomatically. Symptoms may be delayed.

Carcinogenicity

IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA

No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Acute oral toxicity

Acute toxicity estimate : 3,549 mg/kg

Method: Calculation method

Acute inhalation toxicity

Acute toxicity estimate : > 200 mg/l

Exposure time: 4 h

Test atmosphere: vapour

Method: Calculation method

Skin corrosion/irritation

Result: No skin irritation

Serious eye damage/eye irritation

Remarks: Irritating to eyes.

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

No data available

SECTION 12. ECOLOGICAL INFORM

Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

Partition coefficient: noctanol/water

No data available

glycerol : Partition coefficient: noctanol/water

log Pow: -1.76

Mobility in soil

No data available

Other adverse effects

No data available

Regulation

40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

Remarks

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological information

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues

The product should not be allowed to enter drains, water courses or the soil.

Do not contaminate ponds, waterways or ditches with chemical or used container.

Dispose of in accordance with local regulations.

Contaminated packaging

Empty remaining contents.

Dispose of as unused product.

Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

Transportation Regulation: 49 CFR (USA):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IMDG (Vessel):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Cargo Air):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Passenger Air):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: TDG (Canada):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.

SECTION 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification

requirements.

EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Serious eye damage or eye irritation

SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop. 65

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other reproductive harm.

The components of this product are reported in the following inventories:

DSL All components of this product are on the Canadian DSL

TSCA On TSCA Inventory

For information on the country notification status for other regions please contact the manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

Further information

NFPA:

HEALTH

2

FLAMMABILITY

0

INSTABILITY

0

SPECIAL HAZARD.

0 = not significant, 1 =Slight,

24 = Extreme = Moderate , 3 = High

HMIS III:

HEALTH

2

FLAMMABILITY

0

PHYSICAL HAZARD

0

0 = not significant, 1 =Slight,

2 = Moderate, 3 = High

4 = Extreme, * = Chronic

OSHA - GHS Label Information:

Hazard pictograms :

Exclamation mark

Signal word

:

Warning:

Hazard statements

:

Causes serious eye irritation.

Precautionary statements

:

Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.

Version:

1.2

Revision Date:

04/24/2020

Print Date:

07/15/2020

We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.

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