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11. Toxicological information | ||
Information on likely routes of exposure | ||
Inhalation | High concentrations: Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Breathing of high concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. | |
Skin contact | Contact with liquefied gas may cause frostbite. | |
Eye contact | Contact with liquefied gas may cause frostbite. | |
Ingestion | This material is a gas under normal atmospheric conditions and ingestion is unlikely. | |
Symptoms related to the physical, chemical and toxicological characteristics | Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high exposure can cause suffocation from lack of oxygen. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. Asphyxiation may bring about unconsciousness without warning and so rapidly that victim may be unable to protect themself. | |
Information on toxicological effects | ||
Acute toxicity | Not expected to be acutely toxic. | |
Components | Species | Test Results |
Propane (CAS 74-98-6) Acute Inhalation Gas LC50 | Rat | > 80000 ppm, 15 Minutes |
Propylene (CAS 115-07-1) Acute Inhalation Gas LC50 | Rat | > 65000 ppm, 4 Hours |
Skin corrosion/irritation | Not classified. | |
Serious eye damage/eye irritation | Not classified. | |
Respiratory or skin sensitization | ||
Respiratory sensitization | Not a respiratory sensitizer. | |
Skin sensitization | This product is not expected to cause skin sensitization. | |
Germ cell mutagenicity | No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. | |
Carcinogenicity | Not classifiable as to carcinogenicity to humans. | |
Information on toxicological effects
IARC Monographs. Overall Evaluation of Carcinogenicity | ||
Propylene (CAS 115-07-1) | 3 Not classifiable as to carcinogenicity to humans. | |
NTP Report on Carcinogens | ||
Not listed. | ||
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) | ||
Not listed. | ||
Reproductive toxicity | This product is not expected to cause reproductive or developmental effects. | |
Specific target organ toxicity - single exposure | Not classified. | |
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Specific target organ toxicity - repeated exposure | Not classified. | |
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Aspiration hazard | Not relevant, due to the form of the product. | |
Chronic effects | Exposure over a long period of time may cause central nervous system effects. | |
12. Ecological information | |
|---|---|
Ecotoxicity | The product is not expected to be hazardous to the environment. |
Persistence and degradability | Not relevant, due to the form of the product. |
Bioaccumulative potential | Not relevant, due to the form of the product. |
Partition coefficient n-octanol / water (log Kow) | |
Propane (CAS 74-98-6) | 2.36 |
Propylene (CAS 115-07-1) | 1.77 |
Mobility in soil | Not relevant, due to the form of the product. |
Other adverse effects | The product contains volatile organic compounds which have a photochemical ozone creation potential. |
13. Disposal considerations | |
|---|---|
Disposal instructions | Use the container until empty. Do not dispose of any non-empty container. Empty containers have residual vapor that is flammable and explosive. Cylinders should be emptied and returned to a hazardous waste collection point. Do not puncture or incinerate even when empty. Dispose in accordance with all applicable regulations. |
Local disposal regulations | Dispose of in accordance with local regulations. |
Hazardous waste code | D001: Waste Flammable material with a flash point <140 °F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. |
Waste from residues / unused products | Dispose in accordance with all applicable regulations. |
Contaminated packaging | |
14. Transport information
DOTEmpty containers should be taken to an approved waste handling site for recycling or disposal. |
14. Transport information | |
DOT | |
UN number | UN1075 |
UN proper shipping name | Petroleum gases, liquefied |
Transport hazard class(es) Class | 2.1 |
Subsidiary risk | - |
Label(s) | 2.1 |
Packing group | - |
Environmental hazards | |
Marine pollutant | No |
Special precautions for user | Read safety instructions, SDS and emergency procedures before handling. |
Special provisions | T50 |
Packaging exceptions | 306 |
Packaging non bulk | 304 |
Packaging bulk | 314, 315 |
IATA | |
UN number | UN1075 |
UN proper shipping name | Petroleum gases, liquefied |
Transport hazard class(es) | |
Class | 2.1 |
Subsidiary risk | - |
Packing group | - |
Environmental hazards | No |
ERG Code | 10L |
Special precautions for user | Read safety instructions, SDS and emergency procedures before handling. |
IMDG | |
UN number | UN1075 |
UN proper shipping name | PETROLEUM GASES, LIQUEFIED |
Transport hazard class(es) | |
Class | 2.1 |
Subsidiary risk | - |
Packing group | - |
Environmental hazards | |
Marine pollutant | No |
EmS | F̲-D̲ , S-U |
Special precautions for user | Read safety instructions, SDS and emergency procedures before handling. |
Transport in bulk according to | |
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Annex II of MARPOL 73/78 and the IBC Code | Not applicable. |
15. Regulatory information | ||
|---|---|---|
US federal regulations | This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. | |
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) | Not regulated. | |
CERCLA Hazardous Substance List (40 CFR 302.4) | ||
Butane (CAS 106-97-8) | Listed. | |
Ethyl mercaptan (CAS 75-08-1) | Listed. | |
Propane (CAS 74-98-6) | Listed. | |
Propylene (CAS 115-07-1) | Listed. | |
SARA 304 Emergency release notification | Not regulated. | |
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) | Not listed. | |
Toxic Substances Control Act (TSCA) | All components of the mixture on the TSCA 8(b) inventory are designated | |
...
“active”. | ||
Superfund Amendments and Reauthorization Act of 1986 (SARA) | ||
SARA 302 Extremely hazardous substance | Not listed. | |
SARA 311/312 Hazardous chemical | Yes | |
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Classified hazard categories | Flammable (gases, aerosols, liquids, or solids) | |
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Gas under pressure Simple asphyxiant Hazard not otherwise classified (HNOC) | ||
SARA 313 (TRI reporting) | ||
Chemical name | CAS number | |
% by wt. | ||
Propylene | 115-07-1 | 0 - 10 |
Other federal regulations | ||
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List | ||
Not regulated. | ||
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) | Butane (CAS 106-97-8) Ethyl mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) | |
Safe Drinking Water Act (SDWA) | Not regulated. | |
(SDWA)
US state regulations | ||
US. Massachusetts RTK - Substance List | Butane (CAS 106-97-8) Ethyl mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) | |
US. New Jersey Worker and Community Right-to-Know Act | Butane (CAS 106-97-8) Ethyl mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) | |
US. Pennsylvania Worker and Community Right-to-Know Law | Butane (CAS 106-97-8) Ethyl mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) | |
US. Rhode Island RTK | Butane (CAS 106-97-8) Ethyl mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) | |
California Proposition 65 | California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. | |
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) | Butane (CAS 106-97-8) Propylene (CAS 115-07-1) | |
International Inventories | ||
Country(s) or region | Inventory name | On inventory (yes/no)* |
Australia | Australian Inventory of Industrial Chemicals (AICIS) | Yes |
Canada | Domestic Substances List (DSL) | Yes |
Canada | Non-Domestic Substances List (NDSL) | No |
China | Inventory of Existing Chemical Substances in China (IECSC) | Yes |
Europe | European Inventory of Existing Commercial Chemical Substances (EINECS) | Yes |
Europe | European List of Notified Chemical Substances (ELINCS) | No |
Japan | Inventory of Existing and New Chemical Substances (ENCS) | Yes |
Korea | Existing Chemicals List (ECL) | Yes |
New Zealand | New Zealand Inventory | Yes |
Philippines | Philippine Inventory of Chemicals and Chemical Substances (PICCS) | Yes |
Taiwan | Taiwan Chemical Substance Inventory (TCSI) | Yes |
United States & Puerto Rico | Toxic Substances Control Act (TSCA) Inventory | Yes |
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) | ||
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). | ||
16. Other information, including date of preparation or last revision | |
Issue date | 05-May-2014 |
Revision date | 21-March-2021 |
Version # | 03 |
HMIS® ratings | Health: 2 Flammability: 4 Physical hazard: 3 |
NFPA ratings | |
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Disclaimer |
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All information in this Safety Data Sheet is believed to be accurate and reliable. However, no guarantee or warranty of any kind is made with regard to the accuracy of information or the suitability of the recommendations contained herein. It is the user’s responsibility to assess the safety and toxicity of this product under their own conditions of use and to comply with all applicable laws and regulations. |