2. Hazard(s) identification

Physical hazards

Flammable gases - Category 1

Gases under pressure - Liquefied gas

Health hazards

Not classified.

OSHA defined hazards Label elements

Simple asphyxiant

Label elements

Signal word

Danger

Hazard statement

Extremely flammable gas. Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statement

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Use only with adequate ventilation.

Response

Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so.

Storage

Protect from sunlight. Store in a well-ventilated place.

Disposal

Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise classified (HNOC)

Contact with liquefied gas may cause frostbite.

Supplemental information

None.

Chemical name Common name and synonyms CAS number %

Propylene 115-07-1 99.5 - 100

Substances

Chemical name

Common name and synonyms

CAS number

%

Propylene

115-07-1

99.5 - 100

Impurities

Chemical name

Common name and synonyms

CAS number

%

Propane

74-98-6

0 - 0.5

Composition comments

Gas concentrations are in percent by volume.

4. First-aid measures

Inhalation

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory tract irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

Skin contact

Not likely, due to the form of the product. If frostbite occurs, immerse affected area in warm water

(not exceeding 105°F/41°C). Keep immersed for 20 to 40 minutes. Get medical attention immediately.

Eye contact

Not likely, due to the form of the product. If frostbite occurs, immediately flush eyes with plenty of warm water (not exceeding 105°F/41°C) for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention promptly if symptoms persist or occur after washing.

Ingestion

This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Most important symptoms/effects, acute and delayed

Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high exposure can cause suffocation from lack of oxygen. Symptoms may include loss of

mobility/consciousness. Victim may not be aware of asphyxiation. Asphyxiation may bring about unconsciousness without warning and so rapidly that victim may be unable to protect themself.

Indication of immediate medical attention and special treatment needed

Exposure may aggravate pre-existing respiratory disorders. Provide general supportive measures and treat symptomatically.

General information

Fire-fighting measures

First aid personnel must be aware of own risk during rescue. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

Suitable extinguishing media

Dry chemical powder. Carbon dioxide (CO2). Water fog. Foam.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

Extremely flammable gas. May form explosive mixtures with air. Gas may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur. Promptly isolate the scene by removing all persons from the vicinity of the incident. No action shall be taken involving any personal risk or without suitable training. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Stop flow of material. Use water to keep fire exposed containers cool and to protect personnel effecting shutoff. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak. Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials. Cool containers exposed to flames with water until well after the fire is out.

General fire hazards

Extremely flammable gas. Contents under pressure. Pressurized container may explode when exposed to heat or flame.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Evacuate the area promptly. No action shall be taken involving any personal risk or without suitable training. In the event of a leak evacuate all personnel until ventilation can restore oxygen concentrations to safe levels. Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Wear appropriate personal protective equipment (See Section 8).

Methods and materials for containment and cleaning up

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. For waste disposal, see section 13 of the SDS.

Environmental precautions

Should not be released into the environment. Prevent further leakage or spillage if safe to do so.

7. Handling and storage

Precautions for safe handling

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not smoke. All equipment used when handling the product must be grounded. Do not breathe gas. Avoid prolonged exposure. Do not enter storage areas or confined spaces unless adequately ventilated. Use only outdoors or in a well-ventilated area. Oxygen concentration should not fall below 19.5 % at sea level (pO2 = 135 mmHg). Mechanical ventilation or local exhaust ventilation may be required. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

Conditions for safe storage, including any incompatibilities

Do not store, incinerate, or heat this material above 120 degrees Fahrenheit. Keep away from heat, sparks and open flame. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Protect cylinders from damage. Stored containers should be periodically checked for general condition and leakage. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Impurities

Type

Value

Propane (CAS 74-98-6)

PEL

1800 mg/m3

1000 ppm

US. ACGIH Threshold Limit Values

Material

Type

Value

Propylene (CAS 115-07-1)

TWA

500 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Impurities

Type

Value

Propane (CAS 74-98-6)

TWA

1800 mg/m3

1000 ppm

Biological limit values

No biological exposure limits noted for the ingredient(s).

Exposure guidelines

Follow standard monitoring procedures.

Appropriate engineering controls

Provide adequate ventilation and minimize the risk of inhalation of gas. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.

Individual protection measures, such as personal protective equipment

Eye/face protection

Wear approved safety glasses or goggles. Face shield is recommended.

9. Physical and chemical properties

Appearance

Physical state

Gas.

Form

Compressed liquefied gas.

Color

Colorless.

Odor

Hydrocarbon or mercaptan if odorized.

Odor threshold

Not determined.

pH

Not applicable.

Melting point/freezing point

-301 °F (-185 °C)

Initial boiling point and boiling range

-54.4 °F (-48 °C)

Boiling point pressure

101.33 kPa

Flash point

-162.0 °F (-107.8 °C)

Evaporation rate

Not determined.

Flammability (solid, gas)

Extremely flammable gas.

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

2 % v/v

Flammability limit - upper (%)

11 % v/v

Vapor pressure

109.73 PSIG

Vapor pressure temp.

69.8 °F (21 °C)

Vapor density

1.5 (gas) (Air=1) (32 °F (0 °C))

Relative density

0.52 (liquid) (Water=1) (68 °F (20 °C))

Solubility(ies)

Solubility (water)

384 mg/l - Slightly soluble in water.

Partition coefficient (n-octanol/water)

1.77

Auto-ignition temperature

927 °F (497.22 °C)

Decomposition temperature

Not determined.

Viscosity

10. Stability and reactivity

Reactivity

Reacts violently with strong oxidants, nitrites, inorganic chlorides, chlorites and perchlorates causing fire and explosion hazard.

Chemical stability

Stable under normal temperature conditions and recommended use.

Possibility of hazardous reactions

Polymerization will not occur. May form explosive mixture with air. This product may react with oxidizing agents.

Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents. Strong acids. Halogens. Nitrates.

Hazardous decomposition products

Thermal decomposition of this product can generate carbon monoxide and carbon dioxide. Hydrocarbons.

11. Toxicological information

Information on likely routes of exposure

Inhalation

High concentrations: Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Breathing of high concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness.

Skin contact

Contact with liquefied gas may cause frostbite.

Eye contact

Contact with liquefied gas may cause frostbite.

Ingestion

This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Symptoms related to the physical, chemical and toxicological characteristics

Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high exposure can cause suffocation from lack of oxygen. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. Asphyxiation may bring about unconsciousness without warning and so rapidly that victim may be unable to protect themself.

Acute toxicity

Not expected to be acutely toxic.

Toxicological data

Impurities

Species

Test Results

Propane (CAS 74-98-6)

Acute

Inhalation

Species

Test Results

Gas

LC50

Rat

> 80000 ppm, 15 Minutes

Serious eye damage/eye

irritation

Not classified.

Respiratory or skin sensitization

Respiratory sensitization

Not a respiratory sensitizer.

Skin sensitization

This product is not expected to cause skin sensitization.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

Not classifiable as to carcinogenicity to humans.

IARC Monographs. Overall Evaluation of Carcinogenicity

Propylene (CAS 115-07-1)

3 Not classifiable as to carcinogenicity to humans.

NTP Report on Carcinogens

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Not listed.

Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - single exposure

Not classified.

Specific target organ toxicity - repeated exposure

Not classified.

Aspiration hazard

Not relevant, due to the form of the product.

Chronic effects

Exposure over a long period of time may cause central nervous system effects.

Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability

Not relevant, due to the form of the product.

Bioaccumulative potential

Not relevant, due to the form of the product.

Partition coefficient n-octanol / water (log Kow)

Propylene (CAS 115-07-1)

1.77

Mobility in soil

Not relevant, due to the form of the product.

Other adverse effects

The product contains volatile organic compounds which have a photochemical ozone creation potential.

Disposal instructions

Use the container until empty. Do not dispose of any non-empty container. Empty containers have residual vapor that is flammable and explosive. Cylinders should be emptied and returned to a hazardous waste collection point. Do not puncture or incinerate even when empty. Dispose in accordance with all applicable regulations.

Local disposal regulations

Dispose of in accordance with local regulations.

Hazardous waste code

D001: Waste Flammable material with a flash point <140 °F

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Waste from residues / unused products

Dispose in accordance with all applicable regulations.

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information

DOT

UN number

UN1077

UN proper shipping name

Propylene

Transport hazard class(es)

Class2.1

Subsidiary risk

-

Label(s)

2.1

-

2.1

Packing group

-

Environmental hazards

Marine pollutant

No

Special precautions for user

Read safety instructions, SDS and emergency procedures before handling.

Special provisions

19, T50

Packaging exceptions

306

Packaging non bulk

304

Packaging bulk

314, 315

IATA

UN number

UN1077

UN proper shipping name

Propylene

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

2.1

-

2.1

Packing group

-

Environmental hazards

No

ERG Code

10L

Special precautions for user

Read safety instructions, SDS and emergency procedures before handling.

IMDG

UN number

UN1077

UN proper shipping name

PROPYLENE

Transport hazard class(es)

Class

Subsidiary risk

2.1

-

Packing group

-

Environmental hazards

Marine pollutant

No

EmS

F-D, S-U

Special precautions for user

Read safety instructions, SDS and emergency procedures before handling.

Transport in bulk according to

Annex II of MARPOL 73/78 and the IBC Code

Not applicable.

US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1

)

Listed.

Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Not listed.

Toxic Substances Control Act (TSCA)

This substance is on the TSCA 8(b) inventory and is designated “active”.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous chemical

Yes

Classified hazard categories

Flammable (gases, aerosols, liquids, or solids)

Gas under pressure

Simple asphyxiant

Hazard not otherwise classified (HNOC)

SARA 313 (TRI reporting)

Chemical

Name

CAS

Number

% by wt.

PropylenePropylene

115-07-1

99.5 -

100

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1)

Safe Drinking Water Act (SDWA)

Not regulated.

US state regulations

US. Massachusetts RTK - Substance List

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1)

US. New Jersey Worker and Community Right-to-Know Act

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1)

US. Pennsylvania Worker and Community Right-to-Know Law

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1)

US. Rhode Island RTK

Propane (CAS 74-98-6)

Propylene (CAS 115-07-1)

California Proposition 65

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))

Propylene (CAS 115-07-1)

International Inventories

Country(s) or region

Inventory name

On inventory (yes/no)*

Australia

Australian Inventory of Industrial Chemicals (AICIS)

Yes

Canada

Domestic Substances List (DSL)

Yes

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

Taiwan

Taiwan Chemical Substance Inventory (TCSI)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date

07-December-2012

Revision date

10-March-2021

Version #

04

HMIS® ratings

Health: 2

Flammability: 4

Physical hazard: 3

NFPA ratings

Disclaimer

All information in this Safety Data Sheet is believed to be accurate and reliable. However, no guarantee or warranty of any kind is made with regard to the accuracy of information or the suitability of the recommendations contained herein. It is the user’s responsibility to assess the safety and toxicity of this product under their own conditions of use and to comply with all applicable laws and regulations.