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5. Fire-fighting measures | |
General Fire Hazards | Use water spray to keep fire-exposed containers cool. Fight fire from a protected location. Move containers from fire area if you can do so without risk. |
Suitable (and unsuitable) extinguishing media | |
Suitable extinguishing media | Use fire-extinguishing media appropriate for surrounding materials. |
Unsuitable extinguishing media | Do not use water jet as an extinguisher, as this will spread the fire. |
Specific hazards arising from the chemical | Pressurized container may explode when exposed to heat or flame. |
Special protective equipment and precautions for firefighters | |
Special fire fighting procedures | No data available. |
Special protective equipment for fire-fighters | Firefighters must use standard protective equipment including flame |
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retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. |
6. Accidental release measures | |
Personal precautions, | |
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protective equipment and |
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emergency procedures |
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No data available. | |
Methods and material for |
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containment and cleaning |
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up |
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Stop the flow of material, if this is without risk. Absorb with sand or other inert absorbent. | |
Environmental Precautions |
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Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. |
7. Handling and storage | |
Precautions for safe handling | |
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Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. | |
Conditions for safe storage, including any incompatibilities | Protect from sunlight. Store in a cool place. Aerosol Level 1 |
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Version: 2.0
Revision Date: 03/18/2020
PEL
20 ppm
70 mg/m3
8. Exposure controls/personal protection | ||||
Control Parameters | ||||
Occupational Exposure Limits | ||||
Chemical Identity | Type | Exposure Limit Values | Source | |
Ethanol | REL | 1,000 ppm | 1,900 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) |
PEL | 1,000 ppm | 1,900 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) | |
TWA | 1,000 ppm | 1,900 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
STEL | 1,000 ppm | US. ACGIH Threshold Limit Values (2009) | ||
Ethanol, 2-butoxy- | TWA | 20 ppm | US. ACGIH Threshold Limit Values (2008) | |
REL | 5 ppm | 24 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) | |
PEL | 50 ppm | 240 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) | |
TWA | 25 ppm | 120 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Propane | REL | 1,000 ppm | 1,800 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) |
PEL | 1,000 ppm | 1,800 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) | |
TWA | 1,000 ppm | 1,800 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Butane | REL | 800 ppm | 1,900 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) |
STEL | 1,000 ppm | US. ACGIH Threshold Limit Values (03 2018) | ||
TWA | 800 ppm | 1,900 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
Morpholine | REL | 20 ppm | 70 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) |
STEL | 30 ppm | 105 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards (2005) | |
TWA | 20 ppm | US. ACGIH Threshold Limit Values (2008) | ||
TWA | 20 ppm | 70 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
STEL | 30 ppm | 105 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
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PEL | 20 ppm | 70 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 |
CFR 1910.1000) (02 2006) | ||||
2-Propanol, 2-methyl- | STEL | 150 ppm | 450 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
TWA | 100 ppm | 300 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
PEL | 100 ppm | 300 mg/m3 | US. OSHA Table Z-1 Limits for Air Contaminants (29 |
CFR 1910.1000) (02 2006) | ||||
TWA | 100 ppm | US. ACGIH Threshold Limit Values (2008) | ||
STEL | 150 ppm | 450 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | |
REL | 100 ppm | 300 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
Silica | REL | 6 mg/m3 | US. NIOSH: Pocket Guide to Chemical Hazards |
(2005) | ||||
TWA | 20 millions of particles per cubic foot of air | US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) |
particles per
cubic foot of
air
TWA | 6 mg/m3 | US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) | ||
TWA | 0.8 mg/m3 | US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) | ||
2,6-Octadienal, 3,7-dimethyl- -Inhalable fraction and vapor. | TWA | 5 ppm | US. ACGIH Threshold Limit Values (01 2010) |
vapor.
Biological Limit Values | |||
Chemical Identity | Exposure Limit Values | Source | |
Ethanol, 2-butoxy- (Butoxyacetic acid (BAA), with hydrolysis: Sampling time: End of shift.) | 200 mg/g (Creatinine in urine) | ACGIH BEL (03 2013) | Sampling time: End of shift.) | Appropriate Engineering
Appropriate Engineering Controls | No data available. |
Controls
Individual protection measures, such as personal protective equipment | |
General information | |
Use personal protective equipment as required. Personal protection |
equipment should be chosen according to the CEN standards and in |
discussion with the supplier of the personal protective equipment. |
Eye/face protection |
Wear goggles/face shield. | |
Skin Protection | |
Hand Protection | |
No data available. | |
Other |
No data available. | |
Respiratory Protection |
In case of inadequate ventilation use suitable respirator. Seek advice from |
local supervisor. |
Hygiene measures |
Observe good industrial hygiene practices. |
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Version: 2.0
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9. Physical and chemical properties | |||
Appearance | |||
Physical state: | liquid | ||
Form: | Spray Aerosol | ||
Color: | No data available. | ||
Odor: | No data available. | ||
Odor threshold: | No data available. | ||
pH: | 8.7 - 9.7 | ||
Melting point/freezing point: | No data available. | ||
Initial boiling point and boiling range: | No data available. | SDS_US - ??? | 4/12 |
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Flash Point | Not applicable |
Evaporation rate |
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No data available. | |
Flammability (solid, gas) |
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Non-flammable Aerosol | |
Upper/lower limit on flammability or explosive limits | |
Flammability limit - upper (%) | |
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No data available. | |
Flammability limit - lower (%) |
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No data available. | |
Explosive limit - upper (%) |
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No data available. | |
Explosive limit - lower (%) |
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No data available. | |
Vapor pressure |
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5,515 - 6,894 hPa (20 °C) | |
Vapor density |
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No data available. | |
Density |
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No data available. | |
Relative density |
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No data available. | |
Solubility(ies) | |
Solubility in water | |
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No data available. | |
Solubility (other) |
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No data available. | |
Partition coefficient (n-octanol/water) |
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No data available. | |
Auto-ignition temperature |
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No data available. | |
Decomposition temperature |
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No data available. | |
Viscosity |
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No data available. |
10. Stability and reactivity | |
Reactivity: | No data available. |
Chemical Stability: | Material is stable under normal conditions. |
Possibility of hazardous reactions | No data available.reactions: |
Conditions to avoid: | Avoid heat or contamination. |
Incompatible Materials: | No data available. |
Hazardous Decomposition Products | No data available.Products: |
11. Toxicological information | |
Information on likely routes of exposure | |
Inhalation | |
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No data available. | |
Skin Contact |
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No data available. | |
Eye contact |
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No data available. | |
Ingestion |
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No data available. | |
Symptoms related to the physical, chemical and toxicological characteristics | |
Inhalation | |
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No data available. | |
Skin Contact |
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No data available. | |
Eye contact |
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No data available. |
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Ingestion:
No data available.
Information on toxicological effects
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Ingestion | No data available. |
Information on toxicological effects | |
Acute toxicity (list all possible routes of exposure) | |
Oral Product | |
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ATEmix: 36,844.23 mg/kg | |
Dermal Product |
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ATEmix: 32,120.9 mg/kg | |
Inhalation Product |
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ATEmix: 690.87 mg/l ATEmix : 172.72 mg/l | |
Repeated dose toxicity | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | |
Ethanol, 2-butoxy-
Propane
Butane
NOAEL (Rat(Male), Oral, 7 - 14 Weeks): 10 %(m) Oral Experimental result, |
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Key study | |
Ethanol, 2-butoxy- | NOAEL (Rat(Female), Inhalation, 2 yr): < 31 ppm(m) Inhalation |
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Experimental result, Key study NOAEL (Rat(Female), Oral, 90 d): < 82 mg/kg Oral Experimental result, Key |
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study NOAEL (Rabbit(Female, Male), Dermal, 90 d): > 150 mg/kg Dermal |
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Experimental result, Key study | |
Propane | NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation |
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Experimental result, Key study LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation |
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Experimental result, Key study | |
Butane | LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation |
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Experimental result, Key study NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation |
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Experimental result, Key study | |
Skin Corrosion/Irritation | |
Product | |
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No data available |
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Specified substance(s) | |
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Ethanol | |
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in vivo (Rabbit): Not irritant Experimental result, Key study | |
Ethanol, 2-butoxy | in vivo (Rabbit): Irritating Experimental result, Key study |
Serious Eye Damage/Eye Irritation | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | Rabbit, 1 - 24 hrs: Not irritating |
Ethanol, 2-butoxy- | Rabbit, 24 - 72 hrs: Irritating |
Respiratory or Skin Sensitization | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | |
Ethanol, 2-butoxy-
Skin sensitization:, in vivo (Guinea pig): Non sensitising | |
Ethanol, 2-butoxy- | Skin sensitization:, in vivo (Guinea pig): Non sensitising |
Carcinogenicity | |
Product | |
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No data available |
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. |
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Revision Date: 03/18/2020
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans |
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No carcinogenic components identified | |
US. National Toxicology Program (NTP) Report on Carcinogens |
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No carcinogenic components identified | |
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) |
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No carcinogenic components identified | |
Germ Cell Mutagenicity | |
In vitro | |
Product | |
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No data available |
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In vivo | |
Product | |
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No data available |
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Reproductive toxicity | |
Product | |
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No data available |
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Specific Target Organ Toxicity - Single Exposure | |
Product | |
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No data available |
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Specific Target Organ Toxicity - Repeated Exposure | |
Product | |
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No data available |
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Aspiration Hazard | |
Product | |
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No data available |
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Other effects | No data available. |
12. Ecological information | |
Ecotoxicity |
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Acute hazards to the aquatic environment |
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Fish | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol
Ethanol, 2-butoxy-
Propane
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Ethanol | LC 50 (Pimephales promelas, 96 h): 15.3 g/l Experimental result, Key study |
Ethanol, 2-butoxy- | LC 50 (Oncorhynchus mykiss, 96 h): 1,474 mg/l Experimental result, Key study |
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Propane | LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study |
Butane | LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study |
Aquatic Invertebrates | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | |
Ethanol, 2-butoxy-
Butane
LC 50 (Ceriodaphnia dubia, 48 h): 5,012 mg/l Experimental result, Key study | |
Ethanol, 2-butoxy- | EC 50 (Daphnia magna, 48 h): 1,550 mg/l Experimental result, Key study |
Butane | LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key |
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study | |
Chronic hazards to the aquatic environment | |
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Fish | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | NOAEL (Oryzias latipes): 7,900 mg/l Read-across from supporting substance (structural analogue or surrogate), Supporting study |
Ethanol, 2-butoxy- | NOAEL (Danio rerio): > 100 mg/l Experimental result, Key study |
Aquatic Invertebrates | |
Product | |
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No data available. | |
Specified substance(s) | |
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Ethanol | LC 50 (Daphnia magna): 454 mg/l Experimental result, Key study NOAEL (Daphnia magna): 9.6 mg/l Experimental result, Key study |
Ethanol, 2-butoxy- | EC 10 (Daphnia magna): 134 mg/l Experimental result, Key study EC 50 (Daphnia magna): 297 mg/l Experimental result, Key study |
Toxicity to Aquatic Plants | |
Product | |
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No data available. | |
Persistence and Degradability | |
Biodegradation | |
Product | |
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No data available |
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Specified substance(s) | |
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Ethanol | 95 % Detected in water. Experimental result, Key study |
Ethanol, 2-butoxy- | 90.4 % Detected in water. Experimental result, Key study |
Propane | 100 % (385.5 h) Detected in water. Experimental result, Key study 50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study |
Butane | 100 % (385.5 h) Detected in water. Experimental result, Key study |
BOD/COD Ratio | |
Product | |
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No data available |
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Bioaccumulative potential | |
Bioconcentration Factor (BCF) | |
Product | |
No data available |
Specified substance(s) | |
Ethanol | Cyprinus carpio, Bioconcentration Factor (BCF): 4.5 Aquatic sediment Read- |
across from supporting substance (structural analogue or surrogate), |
Supporting study | |
Partition Coefficient n-octanol / water (log Kow) | |
Product | |
No data available. | |
Mobility in soil |
No data available. |
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Known or predicted distribution to environmental compartments | |
Ethanol | No data available. |
Ethanol, 2-butoxy- | No data available. |
Propane | No data available. |
Butane | No data available. |
Other adverse effects: | No data available. |
13. Disposal considerations | |
Disposal instructions | |
Wash before disposal. Dispose to controlled facilities. | |
Contaminated Packaging |
No data available. |
14. Transport information | |||
DOT | |||
UN Number: | UN 1950 | ||
UN Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es) | |||
Class: | 2.2 | ||
Label(s): | – | ||
Packing Group: | II | ||
Marine Pollutant: | No | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
IMDG | |||
UN Number: | UN 1950 | ||
UN Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es) | |||
Class: | 2 | ||
Label(s): | – | ||
EmS No.: | |||
Packing Group: | – | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
IATA | |||
UN Number: | UN 1950 | ||
Proper Shipping Name: | Aerosols, non-flammable | ||
Transport Hazard Class(es) | :|||
Class: | 2.2 | ||
Label(s): | – | ||
Packing Group: | – | ||
Environmental Hazards: | No | ||
Marine Pollutant | No | ||
Special precautions for user: | Not regulated. | ||
Cargo aircraft only: | Allowed. | SDS_US - ??? | 9/12 |
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Version: 2.0
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15. Regulatory information | |
US Federal Regulations | |
Restrictions on use | |
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Not known |
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TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) | |
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) | None present or none present in regulated quantities. |
CERCLA Hazardous Substance List (40 CFR 302.4) | |
...
Chemical Identity | Reportable quantity |
Ethanol | lbs. 100 |
Propane | lbs. 100 |
Butane | lbs. 100 |
Morpholine | lbs. 100 |
Nitrous acid, sodium salt (1:1) | lbs. 100 |
2-Propanol, 2-methyl- | lbs. 100 |
Superfund Amendments and Reauthorization Act of 1986 (SARA) | |
Hazard categories | Not listed. |
SARA 302 Extremely Hazardous Substance | None present or none present in regulated quantities. |
SARA 304 Emergency Release Notification | |
Chemical Identity | Reportable quantity |
Ethanol | lbs. 100 |
Ethanol, 2-butoxy- | |
Propane | lbs. 100 |
Butane | lbs. 100 |
Morpholine | lbs. 100 |
Nitrous acid, sodium salt (1:1) | lbs. 100 |
2-Propanol, 2-methyl- | lbs. 100 |
SARA 311/312 Hazardous Chemical | |
Chemical Identity | Threshold Planning Quantity |
Ethanol | 10000 lbs |
Ethanol, 2-butoxy- | 10000 lbs |
Propane | 10000 lbs |
Butane | 10000 lbs |
Morpholine | 10000 lbs |
Nitrous acid, sodium salt (1:1) | 10000 lbs |
2-Propanol, 2-methyl- | 10000 lbs |
Silica | 10000 lbs |
2,6-Octadienal, 3,7-dimethyl- | 10000 lbs |
SARA 313 (TRI Reporting) |
Chemical Identity | Reporting threshold for other users | Reporting threshold for |
manufacturing and | ||
Chemical Identity | other users | processing | ||||||||||||
Ethanol, 2-butoxy- | N230 lbs | N230 lbs. | ||||||||||||
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